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(R)-6-((1E,3Z,5R,7E,9E,11R,12R,13S,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-one

(R)-6-((1E,3Z,5R,7E,9E,11R,12R,13S,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-one

CAS号：206651-96-9

英文名：(R)-6-((1E,3Z,5R,7E,9E,11R,12R,13S,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-one

分子式

C35H58O4Si

熔点

密度

分子量

570.918

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(R)-6-((1E,3Z,5R,7E,9E,11R,12R,13S,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-one

英文名称

(R)-6-((1E,3Z,5R,7E,9E,11R,12R,13S,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-one

中文别名

英文别名

(R)-6-[(1E,3Z,7E,9E)-(5R,11R,13S,14R,15S)-14-(tert-Butyl-dimethyl-silanyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl]-5,6-dihydro-pyran-2-one、C19-tert-butyldimethylsilyl callystatin A

CAS号

206651-96-9

分子式

C35H58O4Si

分子量

570.918

精确质量

570.41

PSA

52.6

LOGP

9.5572

合成路线

(2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one

(2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one

(R)-6-((1E,3Z,5R,7E,9E,11R,12R,13S,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-one

(R)-6-((1E,3Z,5R,7E,9E,11R,12R,13S,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-5,9,11,13,15-pentamethyl-12-oxo-heptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-one

上游原料

共找到12个上游原料 >

[3S,4R,5R,5(2R),5(4R),5(5R)]-5-{2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl}-3-methylhexan-4-ol

[3S,4R,5R,5(2R),5(4R),5(5R)]-5-{2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl}-3-methylhexan-4-ol

(2R,6R)-6-((1E,3Z,5R,7E,9E,11R,12S,13R,14R,15S)-14-((tert-butyldimethylsilyl)oxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethylheptadeca-1,3,7,9-tetraen-1-yl)-5,6-dihydro-2H-pyran-2-ol

(2R,6R)-6-((1E,3Z,5R,7E,9E,11R,12S,13R,14R,15S)-14-((tert-butyldimethylsilyl)oxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethylheptadeca-1,3,7,9-tetraen-1-yl)-5,6-dihydro-2H-pyran-2-ol

(R)-6-chloromethyl-5,6-dihydropyran-2-one

(R)-6-chloromethyl-5,6-dihydropyran-2-one

(4R,5R,6S,7R,8S,E)-7-(tert-butyl(dimethyl)silyloxy)-2,4,6,8-tetramethyl-5-(trimethylsilyloxy)dec-2-enal

(4R,5R,6S,7R,8S,E)-7-(tert-butyl(dimethyl)silyloxy)-2,4,6,8-tetramethyl-5-(trimethylsilyloxy)dec-2-enal

(2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one

(2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one

(2R,6R)-6-((1E,3Z,5R,7E,9E,11R,12R,13R,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethylheptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-ol

(2R,6R)-6-((1E,3Z,5R,7E,9E,11R,12R,13R,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethylheptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-ol

上游原料

[3S,4R,5R,5(2R),5(4R),5(5R)]-5-{2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl}-3-methylhexan-4-ol (2R,6R)-6-((1E,3Z,5R,7E,9E,11R,12S,13R,14R,15S)-14-((tert-butyldimethylsilyl)oxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethylheptadeca-1,3,7,9-tetraen-1-yl)-5,6-dihydro-2H-pyran-2-ol (R)-6-chloromethyl-5,6-dihydropyran-2-one (4R,5R,6S,7R,8S,E)-7-(tert-butyl(dimethyl)silyloxy)-2,4,6,8-tetramethyl-5-(trimethylsilyloxy)dec-2-enal (2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one (2R,6R)-6-((1E,3Z,5R,7E,9E,11R,12R,13R,14R,15S)-14-(tert-butyl(dimethyl)silyloxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethylheptadeca-1,3,7,9-tetraenyl)-5,6-dihydro-2H-pyran-2-ol tert-Butyl-[(R)-2-(1-isopropoxy-allyloxy)-pent-4-enyloxy]-diphenyl-silane (2R,4S,5R,6S)-(-)-1-benzyloxy-5-hydroxy-2,4,6-trimethyloctan-3-one (8E,10E,14Z,16E)-[3S,4R,5R,7R,13R,17(2R)]-4-(tert-butyldimethylsilanyloxy)-15-ethyl-17-(6-hydroxy-3,6-dihydro-2H-pyran-2-yl)-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraen-6-ol (R)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-5,6-dihydro-2H-pyran-2-one (E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-hex-2-enal (R)-6-[(1E,3Z,7E,9E)-(5R,11R,12S,13R,14R,15S)-14-(tert-Butyl-dimethyl-silanyloxy)-3-ethyl-12-hydroxy-5,9,11,13,15-pentamethyl-heptadeca-1,3,7,9-tetraenyl]-5,6-dihydro-2H-pyran-2-ol