百科

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

CAS号：214198-34-2

英文名：[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

分子式：C33H62O6Si2

分子量：611.013

合成路线

[2R,3R]-3-[(3,4-dimethoxybenzyl)oxy]-2-methylbutan-1-al

[2R,3R]-3-[(3,4-dimethoxybenzyl)oxy]-2-methylbutan-1-al

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

[2S,3S,4R,5R]-3-[(tert-butyldimethylsilyl)oxy]-5-[(3,4-dimethoxybenzyl)oxy]-2,4-dimethylhexan-1-al

[2S,3S,4R,5R]-3-[(tert-butyldimethylsilyl)oxy]-5-[(3,4-dimethoxybenzyl)oxy]-2,4-dimethylhexan-1-al

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

[3R,4R,5R,6R]-4-[(tert-butyldimethylsilyl)oxy]-6-[(3,4-dimethoxybenzyl)oxy]-3,5-dimethylhept-1-ene

[3R,4R,5R,6R]-4-[(tert-butyldimethylsilyl)oxy]-6-[(3,4-dimethoxybenzyl)oxy]-3,5-dimethylhept-1-ene

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

3-hydroxy-2-methylbutanoic acid

3-hydroxy-2-methylbutanoic acid

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

[3S,4R,5R,6S,7R,8R]-6-[(tert-butyldimethylsilyl)oxy]-8-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-3-methoxy-4-[(triethylsilyl)oxy]non-1-ene

上游原料

[2R,3R]-3-[(3,4-dimethoxybenzyl)oxy]-2-methylbutan-1-al [2S,3S,4R,5R]-3-[(tert-butyldimethylsilyl)oxy]-5-[(3,4-dimethoxybenzyl)oxy]-2,4-dimethylhexan-1-al [3R,4R,5R,6R]-4-[(tert-butyldimethylsilyl)oxy]-6-[(3,4-dimethoxybenzyl)oxy]-3,5-dimethylhept-1-ene

下游产品

[2R,3R,4S,5R,6R,7S]-4-[(tert-butyldimethylsilyl)oxy]-3,5-dimethyl-7-methoxy-6-[(triethylsilyl)oxy]-8-nonen-2-ol 巴佛洛霉素A1 [3R,4S,5S,8S,9R,10R,11R,12S]-9-[(tert-butyldimethylsilyl)oxy]-12-methoxy-3-[(4-methoxybenzyl)oxy]-2,4,8,10-tetramethyl-11-[(triethylsilyl)oxy]tetradec-13-en-5-ol-7-one