4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

CAS号：250355-97-6

英文名：4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

分子式

C48H67NO7Si2

熔点

密度

分子量

826.219

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

英文名称

4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

中文别名

英文别名

CAS号

250355-97-6

分子式

C48H67NO7Si2

分子量

826.219

精确质量

825.446

PSA

81.41

LOGP

10.4711

合成路线

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(2R,6R)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-2-(2-(((4-methoxybenzyl)oxy)methyl)oxazol-4-yl)-1,3-dioxan-4-one

(2R,6R)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-2-(2-(((4-methoxybenzyl)oxy)methyl)oxazol-4-yl)-1,3-dioxan-4-one

4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

上游原料

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2-(4-Methoxy-benzyloxymethyl)-oxazole-4-carbaldehyde

2-(4-Methoxy-benzyloxymethyl)-oxazole-4-carbaldehyde

4-((2R,4R)-4-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-6-methylene-1,3-dioxan-2-yl)-2-(((4-methoxybenzyl)oxy)methyl)oxazole

4-((2R,4R)-4-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-6-methylene-1,3-dioxan-2-yl)-2-(((4-methoxybenzyl)oxy)methyl)oxazole

(2R,6R)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-2-(2-(((4-methoxybenzyl)oxy)methyl)oxazol-4-yl)-1,3-dioxan-4-one

(2R,6R)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-2-(2-(((4-methoxybenzyl)oxy)methyl)oxazol-4-yl)-1,3-dioxan-4-one

下游产品

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{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-ethynyl-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-acetaldehyde

{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-ethynyl-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-acetaldehyde

4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-chloromethyl-oxazole

4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-chloromethyl-oxazole

2-{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-(2-iodo-1-methyl-vinyl)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-ethanol

2-{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-(2-iodo-1-methyl-vinyl)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-ethanol

{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-(2-iodo-1-methyl-vinyl)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-acetaldehyde

{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-(2-iodo-1-methyl-vinyl)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-acetaldehyde

4-((2R,4R,6R)-4-((tert-butyldimethylsilyl)oxy)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)tetrahydro-2H-pyran-2-yl)-2-(iodomethyl)oxazole

4-((2R,4R,6R)-4-((tert-butyldimethylsilyl)oxy)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)tetrahydro-2H-pyran-2-yl)-2-(iodomethyl)oxazole

Methanesulfonic acid 4-((2R,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-oxazol-2-ylmethyl ester

Methanesulfonic acid 4-((2R,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-oxazol-2-ylmethyl ester

上游原料

2-(4-Methoxy-benzyloxymethyl)-oxazole-4-carbaldehyde 4-((2R,4R)-4-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-6-methylene-1,3-dioxan-2-yl)-2-(((4-methoxybenzyl)oxy)methyl)oxazole (2R,6R)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)-2-(2-(((4-methoxybenzyl)oxy)methyl)oxazol-4-yl)-1,3-dioxan-4-one

下游产品

{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-ethynyl-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-acetaldehyde 4-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-chloromethyl-oxazole 2-{6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-(2-iodo-1-methyl-vinyl)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-ethanol {6-[4-(tert-butyl-dimethyl-silanyloxy)-6-(2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-(2-iodo-1-methyl-vinyl)-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazol-4-yl)-tetrahydro-pyran-2-ylmethyl]-4-methylene-tetrahydro-pyran-2-yl}-acetaldehyde 4-((2R,4R,6R)-4-((tert-butyldimethylsilyl)oxy)-6-(((2R,6R)-6-(2-((tert-butyldiphenylsilyl)oxy)ethyl)-4-methylenetetrahydro-2H-pyran-2-yl)methyl)tetrahydro-2H-pyran-2-yl)-2-(iodomethyl)oxazole Methanesulfonic acid 4-((2R,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-{(2R,6R)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-oxazol-2-ylmethyl ester [(2R,6R)-6-((2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-{2-[(E)-3-((2R,3R,4S,5R,6R)-6-ethynyl-4-hydroxy-3,5-dimethyl-tetrahydro-pyran-2-yl)-propenyl]-oxazol-4-yl}-tetrahydro-pyran-2-ylmethyl)-4-methylene-tetrahydro-pyran-2-yl]-acetaldehyde 4-(4-(tert-butyl-dimethyl-silanyloxy)-6-{6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-tetrahydro-pyran-2-yl)-2-{3-[4-(3,4-dimethoxy-benzyloxy)-6-ethynyl-3,5-dimethyl-tetrahydro-pyran-2-yl]-propenyl}-oxazole