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(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

CAS号：261158-29-6

英文名：(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

分子式：C28H36O9Si

分子量：544.666

合成路线

(1R,2S,3R,4R)-6,7-methylenedioxy-2-(N-oxazolidinoyl)carbonyl-3-triisopropylsilyloxymethyl-1-(3',4',5'-trimethoxy)phenyl-4-(2''-trimethylsilylethoxy)methoxy-1,2,3,4-tetrahydronaphthalene

(1R,2S,3R,4R)-6,7-methylenedioxy-2-(N-oxazolidinoyl)carbonyl-3-triisopropylsilyloxymethyl-1-(3',4',5'-trimethoxy)phenyl-4-(2''-trimethylsilylethoxy)methoxy-1,2,3,4-tetrahydronaphthalene

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

4-(dimethoxy)methyl-5-formyl(1,2-methylenedioxy)benzene

4-(dimethoxy)methyl-5-formyl(1,2-methylenedioxy)benzene

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

4-(dimethoxy)methyl-5-hydroxymethyl(1,2-methylenedioxy)benzene

4-(dimethoxy)methyl-5-hydroxymethyl(1,2-methylenedioxy)benzene

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

dimethyl 1,4-dihydro-1,4-epoxy-6,7-methylenedioxy-2,3-naphthalene-dicarboxylate

dimethyl 1,4-dihydro-1,4-epoxy-6,7-methylenedioxy-2,3-naphthalene-dicarboxylate

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

meso-(1R*,2R*,3S*,4S*)-2,3-bis(hydroxymethyl)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydronaphthalene

meso-(1R*,2R*,3S*,4S*)-2,3-bis(hydroxymethyl)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydronaphthalene

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

dimethyl meso-(1R*,2S*,3R*,4S*)-(endo)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydro-2,3-naphthalenedicarboxylate

dimethyl meso-(1R*,2S*,3R*,4S*)-(endo)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydro-2,3-naphthalenedicarboxylate

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

meso-(1R*,2R*,3S*,4S*)-2,3-bis(acetoxymethyl)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydronaphthalene

meso-(1R*,2R*,3S*,4S*)-2,3-bis(acetoxymethyl)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydronaphthalene

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

(1R,2S,3R,4R)-4-O-(2-trimethylsilylethoxy)methylpicropodophyllin

上游原料

dimethyl meso-(1R*,2S*,3R*,4S*)-(endo)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydro-2,3-naphthalenedicarboxylate (1R,2S,3R,4R)-6,7-methylenedioxy-2-(N-oxazolidinoyl)carbonyl-3-triisopropylsilyloxymethyl-1-(3',4',5'-trimethoxy)phenyl-4-(2''-trimethylsilylethoxy)methoxy-1,2,3,4-tetrahydronaphthalene meso-(1R*,2R*,3S*,4S*)-2,3-bis(hydroxymethyl)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydronaphthalene meso-(1R*,2R*,3S*,4S*)-2,3-bis(acetoxymethyl)-1,4-epoxy-6,7-methylenedioxy-1,2,3,4-tetrahydronaphthalene dimethyl 1,4-dihydro-1,4-epoxy-6,7-methylenedioxy-2,3-naphthalene-dicarboxylate 4-(dimethoxy)methyl-5-formyl(1,2-methylenedioxy)benzene 4-(dimethoxy)methyl-5-hydroxymethyl(1,2-methylenedioxy)benzene

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