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(+)-amphidinolide T1

(+)-amphidinolide T1

CAS号：262597-82-0

英文名：(+)-amphidinolide T1

分子式

C25H42O5

熔点

密度

分子量

422.598

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(+)-amphidinolide T1

英文名称

(+)-amphidinolide T1

中文别名

英文别名

(1S,6S,9R,13R,14S,17R,19S)-14-Hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxa-bicyclo[15.2.1]icosane-7,15-dione、amphidinolide T1、amphidinolide T、amphidinolide-T1

CAS号

262597-82-0

分子式

C25H42O5

分子量

422.598

精确质量

422.303

PSA

72.83

LOGP

4.9946

合成路线

(1S,6S,9R,13R,14S,17R,19S)-(+)-14-methoxymethoxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosane-7,15-dione

(1S,6S,9R,13R,14S,17R,19S)-(+)-14-methoxymethoxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosane-7,15-dione

(+)-amphidinolide T1

(+)-amphidinolide T1

上游原料

共找到30个上游原料 >

{5-[2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-3-methyl-2-triisopropylsilanyloxy-hex-5-enyloxymethyl}-benzene

{5-[2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-3-methyl-2-triisopropylsilanyloxy-hex-5-enyloxymethyl}-benzene

(+)-11,15-dibenzylidene-(14S)-(tert-butyldimethylsilanyloxy)-(6S,13R,19R)-trimethyl-(9R)-propyl-8,20-dioxaicyclo[15.2.1]icosane-7-one

(+)-11,15-dibenzylidene-(14S)-(tert-butyldimethylsilanyloxy)-(6S,13R,19R)-trimethyl-(9R)-propyl-8,20-dioxaicyclo[15.2.1]icosane-7-one

((1S,2S)-1-Benzyloxymethyl-3-iodo-2-methyl-propoxy)-triisopropyl-silane

((1S,2S)-1-Benzyloxymethyl-3-iodo-2-methyl-propoxy)-triisopropyl-silane

(3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal

(3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal

(-)-4-[(3S)-methyl-(5R)-(prop-2-ynyl)tetrahydrofuran-(2S)-yl]butan-1-ol

(-)-4-[(3S)-methyl-(5R)-(prop-2-ynyl)tetrahydrofuran-(2S)-yl]butan-1-ol

2-methyl-6-[3-methyl-5-(2-trimethylsilanyl-ethoxy)-tetrahydro-furan-2-yl]-hexanoic acid benzyl ester

2-methyl-6-[3-methyl-5-(2-trimethylsilanyl-ethoxy)-tetrahydro-furan-2-yl]-hexanoic acid benzyl ester

上游原料

{5-[2-(tert-butyl-dimethyl-silanyloxy)-pentyl]-3-methyl-2-triisopropylsilanyloxy-hex-5-enyloxymethyl}-benzene (+)-11,15-dibenzylidene-(14S)-(tert-butyldimethylsilanyloxy)-(6S,13R,19R)-trimethyl-(9R)-propyl-8,20-dioxaicyclo[15.2.1]icosane-7-one ((1S,2S)-1-Benzyloxymethyl-3-iodo-2-methyl-propoxy)-triisopropyl-silane (3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal (-)-4-[(3S)-methyl-(5R)-(prop-2-ynyl)tetrahydrofuran-(2S)-yl]butan-1-ol 2-methyl-6-[3-methyl-5-(2-trimethylsilanyl-ethoxy)-tetrahydro-furan-2-yl]-hexanoic acid benzyl ester (2S,3R,7R)-7-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-5-methylene-decane-1,2-diol 4-benzyloxy-2-methyl-3-triisopropylsilanyloxy-butan-1-ol (+)-(2S)-methyl-6-[(3S)-methyl-(5R)-(3-phenylprop-2-ynyl)tetrahydrofuran-(2S)-yl]hexanoic acid 3-benzylidene-6-(tert-butyldimethylsilanyloxy)-(5R)-methyl-(1R)-propylhexyl ester (1S,6S,9R,13R,14S,17R,19S)-(+)-14-methoxymethoxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosane-7,15-dione (-)-(14S)-(tert-butyldimethylsilanyloxy)-(6S,13R,19R)-trimethyl-(9R)-propyl-8,20-dioxaicyclo[15.2.1]icosane-7,11,15-trione (1S,6S,9R,13R,14S,15S,17R,19S)-14-hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-15-((triethylsilyl)oxy)-8,20-dioxabicyclo[15.2.1]icosan-7-one 2-[(2S,3S,5R)-3-Methyl-5-(2-trimethylsilanyl-ethoxy)-tetrahydro-furan-2-yl]-ethanol (R)-4-Benzyl-3-{(S)-2-methyl-6-[(2S,3S,5R)-3-methyl-5-(2-trimethylsilanyl-ethoxy)-tetrahydro-furan-2-yl]-hexanoyl}-oxazolidin-2-one (2S,3S)-4-Benzyloxy-2-methyl-3-triisopropylsilanyloxy-butyric acid (1S,2R)-1-(toluene-4-sulfonylamino)-indan-2-yl ester 6-(5-benzenesulfonyl-3-methyl-tetrahydro-furan-2-yl)-2-methyl-hexanoic acid benzyl ester 5-(2-benzyloxy-ethyl)-4-methyl-dihydro-furan-2-one (+)-(2S)-methyl-6-[(3S)-methyl-(5R)-(3-phenylprop-2-ynyl)tetrahydrofuran-(2S)-yl]hexanoic acid 3-benzylidene-(5R)-methyl-6-oxo-(1R)-propylhexyl ester (R)-1-[1,3]Dithian-2-yl-pentan-2-ol {2-[5-(2-benzyloxy-ethyl)-4-methyl-tetrahydro-furan-2-yloxy]-ethyl}-trimethyl-silane tert-Butyl-((R)-1-[1,3]dithian-2-ylmethyl-butoxy)-dimethyl-silane [2-(5-allyl-4-methyl-tetrahydro-furan-2-yloxy)-ethyl]-trimethyl-silane 4-benzyl-3-{2-methyl-6-[3-methyl-5-(2-trimethylsilanyl-ethoxy)-tetrahydro-furan-2-yl]-hex-4-enoyl}-oxazolidin-2-one (2S,3R,7R)-1-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-3-methyl-2-triisopropylsilanyloxy-decan-5-ol (+)-(2R)-methyl-5-phenylpent-4-yn-1-ol (+)-4-[(3S)-methyl-(5R)-(3-phenyl-prop-2-ynyl)tetrahydrofuran-(2S)-yl]butan-1-ol (+)-(2S)-methyl-6-[(3S)-methyl-(5R)-(3-phenylprop-2-ynyl)tetrahydrofuran-(2S)-yl]hexanoic acid (3S,4S)-6-Benzyloxy-4-hydroxy-3-methyl-hexanenitrile (+)-2-[3-(tert-butyldimethylsilanyloxy)-(2R)-methylpropyl]-1-phenyl-hept-1-en-(4R)-ol 4-benzyloxy-3-hydroxy-2-methyl-butyric acid 1-(toluene-4-sulfonylamino)-indan-2-yl ester