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candicanoside A

candicanoside A

CAS号：263570-67-8

英文名：candicanoside A

分子式

C39H60O12

熔点

密度

分子量

720.886

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

candicanoside A

英文名称

candicanoside A

中文别名

英文别名

(16β,22S,23S)-16,23:18,23-diepoxy-22-(2-methylprop-1-enyl)-24-norchol-5-en-3β-yl O-α-L-rhamnopyranosyl-(1 -> 2)-β-D-glucopyranoside

CAS号

263570-67-8

分子式

C39H60O12

分子量

720.886

精确质量

720.408

PSA

176.76

LOGP

2.1659

合成路线

(R)-3-((1aR,3aR,3bS,5aR,6R,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-7-oxohexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoic acid

(R)-3-((1aR,3aR,3bS,5aR,6R,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-7-oxohexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoic acid

candicanoside A

candicanoside A

上游原料

共找到21个上游原料 >

(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(allyloxy)-5-((2-(azidomethyl)benzoyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate

(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(allyloxy)-5-((2-(azidomethyl)benzoyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate

methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(acetoxymethyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate

methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(acetoxymethyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate

(1aR,3aR,3bS,5aR,6R,7R,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-6-((R)-4-hydroxybutan-2-yl)-10-methoxy-3a-methylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-7-ol

(1aR,3aR,3bS,5aR,6R,7R,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-6-((R)-4-hydroxybutan-2-yl)-10-methoxy-3a-methylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-7-ol

methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate

methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate

methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(hydroxymethyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate

methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(hydroxymethyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate

(R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butan-1-ol

(R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butan-1-ol

上游原料

(2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(allyloxy)-5-((2-(azidomethyl)benzoyl)oxy)tetrahydro-2H-pyran-3,4-diyl diacetate methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(acetoxymethyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate (1aR,3aR,3bS,5aR,6R,7R,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-6-((R)-4-hydroxybutan-2-yl)-10-methoxy-3a-methylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-7-ol methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate methyl (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(hydroxymethyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate (R)-3-((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-1,1a,2,3,3a,3b,4,5,5a,8,8a,8b,9,10-tetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butan-1-ol (3S,4S,5S,5aR,6S,7aS,7bR,11S,13aR,13bS,15aR)-5,13a-dimethyl-4-(2-methylprop-1-en-1-yl)-4,5,5a,6,7,7a,7b,8,10,11,12,13,13a,13b,14,15-hexadecahydro-1H,3H-3,6-epoxynaphtho[2',1':4,5]indeno[7a,1-c]oxepin-11-ol (2R,2aR,3aR,5aR,5bS,7aR,7bR,8S,9S,11aS,12aS,12bR)-7a-(((tert-butyldimethylsilyl)oxy)methyl)-2-methoxy-5a,8-dimethyl-9-(2-methylprop-1-en-1-yl)octadecahydro-2H-cyclopropa[1',7a']indeno[5',4':4,5]indeno[2,1-b]pyran-10-yl acetate methyl (R)-3-((1aR,3aR,3bS,5aR,6R,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-7-oxohexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoate 3,4,6-tri-O-acetyl-2-O-[2-(azidomethyl)benzoyl]-D-glucopyranosyl trichloroacetimidate (2R,2aR,3aR,5aR,5bS,7aR,7bR,8R,11aS,12aS,12bR)-7a-(((tert-butyldimethylsilyl)oxy)methyl)-2-methoxy-5a,8-dimethyloctadecahydro-10H-cyclopropa[1',7a']indeno[5',4':4,5]indeno[2,1-b]pyran-10-one (R)-3-((1aR,3aR,3bS,5aR,6R,8aS,8bR,10R,10aR)-5a-(((tert-butyldimethylsilyl)oxy)methyl)-10-methoxy-3a-methyl-7-oxohexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)butanoic acid (S)-1-((1aR,3aR,3bS,5aS,6S,8aS,8bS,10R,10aR)-10-methoxy-3a,5a-dimethylhexadecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-6-yl)ethan-1-ol (1S,3aR,5aS,5bR,7aR,8aR,9R,10aR,10bS,12aS)-9-methoxy-1,5b-dimethylhexadecahydro-3H-cyclopropa[1',7a']indeno[5',4':4,5]indeno[1,7a-c]furan-1-ol (2R,2aR,3aR,5aR,5bS,7aR,7bR,8S,11aS,12aS,12bR,Z)-7a-(((tert-butyldimethylsilyl)oxy)methyl)-2-methoxy-5a,8-dimethyl-9-(2-methylpropylidene)octadecahydro-10H-cyclopropa[1',7a']indeno[5',4':4,5]indeno[2,1-b]pyran-10-one (2R,2aR,3aR,5aR,5bS,7aR,7bR,8S,9S,11aS,12aS,12bR)-7a-(((tert-butyldimethylsilyl)oxy)methyl)-2-methoxy-5a,8-dimethyl-9-(2-methylprop-1-en-1-yl)octadecahydro-10H-cyclopropa[1',7a']indeno[5',4':4,5]indeno[2,1-b]pyran-10-one ((1aR,3aR,3bS,5aR,8aS,8bR,10R,10aR,Z)-6-ethylidene-10-methoxy-3a-methyltetradecahydrocyclopenta[a]cyclopropa[2,3]cyclopenta[1,2-f]naphthalen-5a(1H)-yl)methyl acetate allyl 2-O-(2-azidomethyl)benzoyl-4,6-O-benzylidene-α-D-glucopyranoside