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(+)-epibrefeldin A

(+)-epibrefeldin A

CAS号：267667-13-0

英文名：(+)-epibrefeldin A

分子式

C16H24O4

熔点

203 - 204 °C (乙酸乙酯)

密度

分子量

280.359

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(+)-epibrefeldin A

英文名称

(+)-epibrefeldin A

中文别名

英文别名

4-epi-brefeldin A、(5E,13E)-(2S,3aR,4S,9S,14aS)-2,4-Dihydroxy-9-methyl-1,2,3,3a,4,9,10,11,12,14a-decahydro-8-oxa-cyclopentacyclotridecen-7-one、(+)-brefeldin、(+)-brefeldin A

CAS号

267667-13-0

分子式

C16H24O4

分子量

280.359

精确质量

280.167

PSA

66.76

LOGP

1.9624

物化性质

熔点

203 - 204 °C (乙酸乙酯)

合成路线

4-oxo-brefeldin A

4-oxo-brefeldin A

布雷非德菌素 A

布雷非德菌素 A

(+)-epibrefeldin A

(+)-epibrefeldin A

上游原料

共找到9个上游原料 >

{(1S,2R,4R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-acetaldehyde

{(1S,2R,4R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-acetaldehyde

{(1R,2R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-oxo-cyclopentyl}-acetonitrile

{(1R,2R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-oxo-cyclopentyl}-acetonitrile

{(1R,2R,4R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-acetonitrile

{(1R,2R,4R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-acetonitrile

(E)-4-{(1R,2S,4S)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-4-(tetrahydro-pyran-2-yloxy)-but-2-enoic acid ethyl ester

(E)-4-{(1R,2S,4S)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-4-(tetrahydro-pyran-2-yloxy)-but-2-enoic acid ethyl ester

4-oxo-brefeldin A

4-oxo-brefeldin A

(Z,8S)-8-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-nonen-2-one

(Z,8S)-8-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-nonen-2-one

上游原料

{(1S,2R,4R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-acetaldehyde {(1R,2R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-oxo-cyclopentyl}-acetonitrile {(1R,2R,4R)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-acetonitrile (E)-4-{(1R,2S,4S)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-4-(tetrahydro-pyran-2-yloxy)-but-2-enoic acid ethyl ester 4-oxo-brefeldin A (Z,8S)-8-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-nonen-2-one (+)-4-cyanomethylcyclopent-2-en-1-one (E)-4-{(1R,2S,4S)-2-[(E)-(S)-6-(tert-Butyl-dimethyl-silanyloxy)-hept-1-enyl]-4-methoxymethoxy-cyclopentyl}-4-hydroxy-but-2-enoic acid ethyl ester (2S,4S,6R)-6-[((Z,6S)-6-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-1-heptenyl)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]methyl-4-methylbenzenesulfonate