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(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-{(3aR,5S,6R,6aR)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl}-ethanol

(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-{(3aR,5S,6R,6aR)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl}-ethanol

CAS号：270070-72-9

英文名：(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-{(3aR,5S,6R,6aR)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl}-ethanol

分子式

C45H58O6Si2

熔点

密度

分子量

751.109

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-{(3aR,5S,6R,6aR)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl}-ethanol

英文名称

(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-{(3aR,5S,6R,6aR)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl}-ethanol

中文别名

英文别名

CAS号

270070-72-9

分子式

C45H58O6Si2

分子量

751.109

精确质量

750.377

PSA

66.38

LOGP

6.9394

合成路线

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{(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester

{(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester

(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-{(3aR,5S,6R,6aR)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl}-ethanol

(S)-2-(tert-Butyl-diphenyl-silanyloxy)-1-{(3aR,5S,6R,6aR)-6-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl}-ethanol

上游原料

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{(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methanesulfonyloxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester

{(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methanesulfonyloxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester

{(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester

{(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester

(3aR,4aS,5S,8aR,8bR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-8a-vinyl-hexahydro-[1,3]dioxolo[4,5]furo[2,3-c]pyran-7-one

(3aR,4aS,5S,8aR,8bR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-8a-vinyl-hexahydro-[1,3]dioxolo[4,5]furo[2,3-c]pyran-7-one

(2R,3R,4R,5S)-4-<(ethoxycarbonyl)methyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

(2R,3R,4R,5S)-4-<(ethoxycarbonyl)methyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

下游产品

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(S)-2-[(3aR,5S,6R,6aR)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(2-hydroxy-ethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-2-methoxy-ethanol

(S)-2-[(3aR,5S,6R,6aR)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(2-hydroxy-ethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-2-methoxy-ethanol

(3R,4S,5R)-5-Acetoxymethyl-5-(bis-ethylsulfanyl-methyl)-2-(2,2-dimethyl-propionyloxy)-4-hydroxy-3-methoxy-cyclopent-1-enecarboxylic acid methyl ester

(3R,4S,5R)-5-Acetoxymethyl-5-(bis-ethylsulfanyl-methyl)-2-(2,2-dimethyl-propionyloxy)-4-hydroxy-3-methoxy-cyclopent-1-enecarboxylic acid methyl ester

2,2-Dimethyl-propionic acid 2-{(3aR,5S,6R,6aR)-5-[(S)-2-(2,2-dimethyl-propionyloxy)-1-methoxy-ethyl]-6-hydroxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-ethyl ester

2,2-Dimethyl-propionic acid 2-{(3aR,5S,6R,6aR)-5-[(S)-2-(2,2-dimethyl-propionyloxy)-1-methoxy-ethyl]-6-hydroxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-ethyl ester

(3aR,4aS,5R,7aR,7bR)-7a-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(2,2-dimethyl-propionyloxy)-5-methoxy-2,2-dimethyl-4a,5,7a,7b-tetrahydro-3aH-cyclopenta[4,5]furo[2,3-d][1,3]dioxole-7-carboxylic acid methyl ester

(3aR,4aS,5R,7aR,7bR)-7a-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(2,2-dimethyl-propionyloxy)-5-methoxy-2,2-dimethyl-4a,5,7a,7b-tetrahydro-3aH-cyclopenta[4,5]furo[2,3-d][1,3]dioxole-7-carboxylic acid methyl ester

(R)-[(3aR,5S,6R,6aR)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-6-methoxycarbonylmethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-methoxy-acetic acid methyl ester

(R)-[(3aR,5S,6R,6aR)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-6-methoxycarbonylmethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-methoxy-acetic acid methyl ester

(3R,3aS,6R,6aS)-3a-Acetoxymethyl-5-(2,2-dimethyl-propionyloxy)-2,3-dihydroxy-6-methoxy-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-4-carboxylic acid methyl ester

(3R,3aS,6R,6aS)-3a-Acetoxymethyl-5-(2,2-dimethyl-propionyloxy)-2,3-dihydroxy-6-methoxy-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-4-carboxylic acid methyl ester

上游原料

{(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-methanesulfonyloxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester {(3aR,5S,6R,6aR)-5-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-acetic acid ethyl ester (3aR,4aS,5S,8aR,8bR)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-8a-vinyl-hexahydro-[1,3]dioxolo[4,5]furo[2,3-c]pyran-7-one (2R,3R,4R,5S)-4-<(ethoxycarbonyl)methyl>-2,3-(isopropylidenedioxy)-5-<(1R)-1,2-(isopropylidenedioxy)ethyl>-4-vinyltetrahydrofuran

下游产品

(S)-2-[(3aR,5S,6R,6aR)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(2-hydroxy-ethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-2-methoxy-ethanol (3R,4S,5R)-5-Acetoxymethyl-5-(bis-ethylsulfanyl-methyl)-2-(2,2-dimethyl-propionyloxy)-4-hydroxy-3-methoxy-cyclopent-1-enecarboxylic acid methyl ester 2,2-Dimethyl-propionic acid 2-{(3aR,5S,6R,6aR)-5-[(S)-2-(2,2-dimethyl-propionyloxy)-1-methoxy-ethyl]-6-hydroxymethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-ethyl ester (3aR,4aS,5R,7aR,7bR)-7a-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(2,2-dimethyl-propionyloxy)-5-methoxy-2,2-dimethyl-4a,5,7a,7b-tetrahydro-3aH-cyclopenta[4,5]furo[2,3-d][1,3]dioxole-7-carboxylic acid methyl ester (R)-[(3aR,5S,6R,6aR)-6-(tert-Butyl-dimethyl-silanyloxymethyl)-6-methoxycarbonylmethyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-methoxy-acetic acid methyl ester (3R,3aS,6R,6aS)-3a-Acetoxymethyl-5-(2,2-dimethyl-propionyloxy)-2,3-dihydroxy-6-methoxy-3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-4-carboxylic acid methyl ester (3R,4S,5S)-5-Acetoxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-2-(2,2-dimethyl-propionyloxy)-3-methoxy-5-methyl-cyclopent-1-enecarboxylic acid methyl ester (3aR,4aS,5R,7aR,7bR)-7a-Acetoxymethyl-6-(2,2-dimethyl-propionyloxy)-5-methoxy-2,2-dimethyl-4a,5,7a,7b-tetrahydro-3aH-cyclopenta[4,5]furo[2,3-d][1,3]dioxole-7-carboxylic acid methyl ester 2,2-Dimethyl-propionic acid 2-{(3aR,5S,6R,6aR)-5-[(S)-2-(2,2-dimethyl-propionyloxy)-1-methoxy-ethyl]-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl}-ethyl ester (3R,4S,5S)-5-Acetoxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-3-methoxy-2-methoxymethoxy-5-methyl-cyclopent-1-enecarboxylic acid methyl ester