百科

gamma-玉红霉素

CAS号：27267-71-6

英文名：methyl (2S)-4',9',10-trihydroxy-7'-methoxy-5',8',9-trioxospiro[3,4-dihydropyrano[4,3-g]chromene-2,2'-3H-benzo[f][1]benzofuran]-7-carboxylate

分子式

C26H18O12

熔点

密度

1.77g/cm3

分子量

522.414

沸点

909.3ºC at 760mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

gamma-玉红霉素

英文名称

methyl (2S)-4',9',10-trihydroxy-7'-methoxy-5',8',9-trioxospiro[3,4-dihydropyrano[4,3-g]chromene-2,2'-3H-benzo[f][1]benzofuran]-7-carboxylate

中文别名

英文别名

Cyclohexanecarboxaldehyde,2,2-dimethyl-6-methylene、2,2-dimethyl-6-methylene-cyclohexanecarbaldehyde、2,2-dimethyl-6-methylene-1-cyclohexanecarbaldehyde、2,2-Dimethyl-6-methylen-cyclohexancarbaldehyd

CAS号

27267-71-6

分子式

C26H18O12

分子量

522.414

精确质量

522.08

PSA

179.03

LOGP

2.2621

物化性质

密度

1.77g/cm3

沸点

909.3ºC at 760mmHg

闪点

313.4ºC

折射率

1.758

蒸汽压

3.55E-35mmHg at 25°C

合成路线

959587-11-2

methyl 4,7,9,10'-tetramethoxy-5,8,9'-trioxo-4',5,8,9'-tetrahydro-3H,3'H-spiro[naphtho[2,3-b]furan-2,2'-pyrano[4,3-g]chromene]-7'-carboxylate

上游原料

4-O-(Tetrahydro-2H-pyran-2-yl)-purpuromycin

151158-33-7

4-Chloro-purpuromycin

13261-43-3

1,4-Naphthalenedione, 2-hydroxy-5,7,8-trimethoxy-

53969-01-0

绛红霉素

1198596-64-3

2-azido-5,7,8-trimethoxynaphthalene-1,4-dione

136008-98-5

2-bromo-5,7,8-trimethoxynaphthalen-1-ol

上游原料

4-O-(Tetrahydro-2H-pyran-2-yl)-purpuromycin 4-Chloro-purpuromycin 绛红霉素 2-azido-5,7,8-trimethoxynaphthalene-1,4-dione 2-bromo-5,7,8-trimethoxynaphthalen-1-ol 5,7,8-trimethoxy-3,4-dihydro-2H-naphthalen-1-one 2-bromo-5,7,8-trimethoxynaphthalene-1,4-dione methyl 10-methoxy-2-methylene-9-oxo-2,3,4,9-tetrahydropyrano[4,3-g]chromene-7-carboxylate methyl 4,7,9,10'-tetramethoxy-5,8,9'-trioxo-4',5,8,9'-tetrahydro-3H,3'H-spiro[naphtho[2,3-b]furan-2,2'-pyrano[4,3-g]chromene]-7'-carboxylate methyl 6,7,9,10'-tetramethoxy-4,5,9'-trioxo-4,4',5,9'-tetrahydro-3H,3'H-spiro[naphtho[1,2-b]furan-2,2'-pyrano[4,3-g]chromene]-7'-carboxylate methyl 5,7,8,10'-tetramethoxy-4,9,9'-trioxo-4,4',9,9'-tetrahydro-3H,3'H-spiro[naphtho[2,3-b]furan-2,2'-pyrano[4,3-g]chromene]-7'-carboxylate 4',9',10-Tris-O-acetyl-4-O-(methylsulfonyl)-purpuromycin