百科

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

CAS号：288395-87-9

英文名：(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

分子式：C25H25NO8

分子量：467.468

合成路线

(3aS,3bR,12S,12aR)-4-(4-methoxybenzyl)-2,2-dimethyl-5-oxo-3a,3b,4,5,12,12a-hexahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridine-6,12-diyl diacetate

(3aS,3bR,12S,12aR)-4-(4-methoxybenzyl)-2,2-dimethyl-5-oxo-3a,3b,4,5,12,12a-hexahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridine-6,12-diyl diacetate

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

2,4-Cyclohexadien-1-carbonsaeure-methylester

2,4-Cyclohexadien-1-carbonsaeure-methylester

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

bromo-5 hydroxy-4 benzodioxole-1,3

bromo-5 hydroxy-4 benzodioxole-1,3

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(+)-methyl (1β,2α,6β)-2-hydroxy-7-oxabicyclo[4,1,0]hept-3-ene-4-carboxylate

(+)-methyl (1β,2α,6β)-2-hydroxy-7-oxabicyclo[4,1,0]hept-3-ene-4-carboxylate

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

5-bromo-4-(1-ethoxyethoxy)-2H-benzo[d]1,3-dioxolane

5-bromo-4-(1-ethoxyethoxy)-2H-benzo[d]1,3-dioxolane

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

methyl 5-(butyryloxy)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylate

methyl 5-(butyryloxy)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylate

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

(3aS,3bR,12S,12aR)-6,12-dihydroxy-4-(4-methoxybenzyl)-2,2-dimethyl-3b,4,12,12a-tetrahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridin-5(3aH)-one

上游原料

(3aS,3bR,12S,12aR)-4-(4-methoxybenzyl)-2,2-dimethyl-5-oxo-3a,3b,4,5,12,12a-hexahydrobis([1,3]dioxolo)[4,5-c:4',5'-j]phenanthridine-6,12-diyl diacetate 2,4-Cyclohexadien-1-carbonsaeure-methylester 5-bromo-4-(1-ethoxyethoxy)-2H-benzo[d]1,3-dioxolane methyl 5-(butyryloxy)-7-oxabicyclo[4.1.0]hept-3-ene-3-carboxylate bromo-5 hydroxy-4 benzodioxole-1,3 (+)-methyl (1β,2α,6β)-2-hydroxy-7-oxabicyclo[4,1,0]hept-3-ene-4-carboxylate

下游产品

(2S,5aS,2aR,5bR)-2,8-dihydroxy-4,4-dimethyl-2,6,2a,5a,5b-pentahydro-10H-1,3-dioxolano(4,5-c)1,3-dioxoleno(4,5-j)phenanthridin-7-one 水仙环素