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(1R,3R,3aR,7R,7aR)-2-[3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)-3(2R,3R)-methyloxiranyl]-ethanol
CAS号:294674-52-5
英文名:(1R,3R,3aR,7R,7aR)-2-[3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)-3(2R,3R)-methyloxiranyl]-ethanol
分子式:C20H30O3
分子量:318.45
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合成路线
294674-51-4
(1R,3R,3aR,7R,7aR)-4-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,5,7a-hexahydroisobenzofuran-1-yl)-(Z)-pent-3-ene-1-ol
294674-52-5
(1R,3R,3aR,7R,7aR)-2-[3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)-3(2R,3R)-methyloxiranyl]-ethanol
170309-21-4
(5R)-3-iodo-5-isopropyl-2-methylcyclohexa-1,3-diene
294674-52-5
(1R,3R,3aR,7R,7aR)-2-[3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)-3(2R,3R)-methyloxiranyl]-ethanol
294674-48-9
(R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane
294674-52-5
(1R,3R,3aR,7R,7aR)-2-[3-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)-3(2R,3R)-methyloxiranyl]-ethanol
上游原料
(R)-4-((R)-3-Isopropyl-6-methyl-cyclohexa-1,5-dienyl)-2-((Z)-1-methyl-4-triisopropylsilanyloxy-but-1-enyl)-5-(3-trimethylsilanyl-prop-2-ynyl)-[1,3]dioxolane
(1R,3R,3aR,7R,7aR)-4-(7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,5,7a-hexahydroisobenzofuran-1-yl)-(Z)-pent-3-ene-1-ol
(5R)-3-iodo-5-isopropyl-2-methylcyclohexa-1,3-diene
下游产品
2,2-Dimethyl-propionic acid (R)-4-(tert-butyl-dimethyl-silanyloxy)-4-((1R,3R,3aR,7R,7aR)-7-isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydro-isobenzofuran-1-yl)-pentyl ester
2,2-dimethylpropionic acid (3S,4S)-bis-(tert-butyldimethylsiloxy)-4-(1R,3R,3aR,7R,7aR)-(7-isopropyl-4-methyl-3-(prop-2-ynyl)-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)pentyl ester
(3R,7R,8R,10S,11S,14R,15R,16R)-14-(tert-butyldimethylsiloxy)-3-isopropyl-6,10,14-trimethyl-15-oxatricyclo[6.6.1.00,0]pentadec-5-ene-10,11-diol
(R)-4-((1R,3R,3aR,7R,7aR)-7-Isopropyl-4-methyl-3-prop-2-ynyl-1,3,3a,6,7,7a-hexahydro-isobenzofuran-1-yl)-pentane-1,4-diol
(1R,2R,3R,7R,8R,11S,13S,14S)-13,14-bis-(tert-butyldimethylsiloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.02,7]pentadec-5-en-11-ol
(3S,4S)-bis-(tert-butyldimethylsiloxy)-4-(1R,3R,3aR,7R,7aR)-[3-(2-iodoallyl)-7-isopropyl-4-methyl-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl]pentanal
(3S,4R)-dihydroxy-4-(1R,3R,3aR,7R,7aR)-(7-isopropyl-4-methyl-3-(prop-2-ynyl)-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)pentyl alcohol
alcyonin
(1'R,2R,4a'R,5'R,8'S,11'R,12'R,12a'R)-11'-((tert-butyldimethylsilyl)oxy)-1'-isopropyl-4',11'-dimethyl-2',4a',5',6',8',9',10',11',12',12a'-decahydro-1'H-spiro[oxirane-2,7'-[5,12]epoxybenzo[10]annulen]-8'-ol
cladieunicellin B
acetic acid (3R,7R,8R,11S,14R,15R,16R)-14-(tert-butyldimethylsilyloxy)-3-isopropyl-6,14-dimethyl-10-methylene-15-oxatricyclo[6.6.1.00,0]pentadec-5-en-11-yl ester
2,2-dimethylpropionic acid (3S,4R)-dihydroxy-4-(1R,3R,3aR,7R,7aR)-(7-isopropyl-4-methyl-3-(prop-2-ynyl)-1,3,3a,6,7,7a-hexahydroisobenzofuran-1-yl)pentyl ester