曲林菌素

曲林菌素

CAS号：30387-51-0

英文名：ASPERLIN

分子式

C10H12O5

熔点

密度

1.28g/cm3

分子量

212.199

沸点

360.4ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

曲林菌素

英文名称

ASPERLIN

中文别名

英文别名

Asperlin (usan)、(+)-Asperlin

CAS号

30387-51-0

分子式

C10H12O5

分子量

212.199

精确质量

212.068

PSA

65.13

LOGP

0.187

编号系统

UNII

8KOW0SA4L3

物化性质

密度

1.28g/cm3

沸点

360.4ºC at 760 mmHg

闪点

162.3ºC

折射率

1.511

安全信息

海关编码

2932999099

合成路线

(+)-Acetylphomalactone

(+)-Acetylphomalactone

曲林菌素

(5R,6S,1'R,2'S)-5-acetoxy-5,6-dihydro-6-(1',2'-epoxypropyl)-2H-pyran-2-one

(5R,6S,1'R,2'S)-5-acetoxy-5,6-dihydro-6-(1',2'-epoxypropyl)-2H-pyran-2-one

上游原料

共找到30个上游原料 >

2H-Pyran-3(6H)-one, 6-hydroxy-2-(1E)-1-propenyl-, (2S)-

2H-Pyran-3(6H)-one, 6-hydroxy-2-(1E)-1-propenyl-, (2S)-

(S)-1-((1R,2R,5S,7R)-2-(4-methoxyphenoxy)-6,8-dioxabicyclo[3.2.1]oct-3-en-7-yl)ethan-1-ol

(S)-1-((1R,2R,5S,7R)-2-(4-methoxyphenoxy)-6,8-dioxabicyclo[3.2.1]oct-3-en-7-yl)ethan-1-ol

(2S)-6-hydroxy-2-[(1S,2R)-1',2'-epoxypropyl]-2,6-dihydropyran-3-one

(2S)-6-hydroxy-2-[(1S,2R)-1',2'-epoxypropyl]-2,6-dihydropyran-3-one

Benzoic acid (1R,2R)-2-hydroxy-2-[(2S,3R)-6-methoxy-3-(4-methoxy-phenoxy)-3,6-dihydro-2H-pyran-2-yl]-1-methyl-ethyl ester

Benzoic acid (1R,2R)-2-hydroxy-2-[(2S,3R)-6-methoxy-3-(4-methoxy-phenoxy)-3,6-dihydro-2H-pyran-2-yl]-1-methyl-ethyl ester

(4aR,6S,8aS)-6-Ethoxy-6,8a-dihydro-4aH-pyrano[3,2-b]pyran-2-one

(4aR,6S,8aS)-6-Ethoxy-6,8a-dihydro-4aH-pyrano[3,2-b]pyran-2-one

(1R,2R,5R,7S)-2-(4-Methoxy-phenoxy)-7-phenylsulfanylmethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-ene

(1R,2R,5R,7S)-2-(4-Methoxy-phenoxy)-7-phenylsulfanylmethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-ene

上游原料

(S)-1-((1R,2R,5S,7R)-2-(4-methoxyphenoxy)-6,8-dioxabicyclo[3.2.1]oct-3-en-7-yl)ethan-1-ol (2S)-6-hydroxy-2-[(1S,2R)-1',2'-epoxypropyl]-2,6-dihydropyran-3-one Benzoic acid (1R,2R)-2-hydroxy-2-[(2S,3R)-6-methoxy-3-(4-methoxy-phenoxy)-3,6-dihydro-2H-pyran-2-yl]-1-methyl-ethyl ester (4aR,6S,8aS)-6-Ethoxy-6,8a-dihydro-4aH-pyrano[3,2-b]pyran-2-one (1R,2R,5R,7S)-2-(4-Methoxy-phenoxy)-7-phenylsulfanylmethyl-6,8-dioxa-bicyclo[3.2.1]oct-3-ene (5S,6S)-4-((R)-2-(3-methoxypentan-3-yl)pyrrolidin-1-yl)-6-((E)-prop-1-en-1-yl)-5-(2-(trimethylsilyl)ethoxy)-5,6-dihydro-2H-pyran-2-one (2S,3R,6R)-6-ethoxyethoxy-2-((1S,2R)-1',2'-epoxypropyl)-2,6-dihydropyran-3-ol (1R,2R,5R,7S)-2-(4-methoxyphenoxy)-7-((phenylsulfinyl)methyl)-6,8-dioxabicyclo[3.2.1]oct-3-ene (5R,6R,1'S,2'R)-5,6-dihydro-5-hydroxy-6-(1',2'-epoxypropyl)-2H-pyran-2-one (R)-((1R,2R,5R,7S)-2-(4-methoxyphenoxy)-6,8-dioxabicyclo[3.2.1]oct-3-en-7-yl)(phenylthio)methyl acetate (1R,2R)-1-((2R,3R)-6-methoxy-3-(4-methoxyphenoxy)-3,6-dihydro-2H-pyran-2-yl)-1-((methylsulfonyl)oxy)propan-2-yl benzoate (5R,6R)-5-(4-methoxyphenoxy)-6-((2S,3R)-3-methyloxiran-2-yl)-5,6-dihydro-2H-pyran-2-one (5R,6S)-5-Hydroxy-6-((E)-3-hydroxy-propenyl)-5,6-dihydro-pyran-2-one (2S,3S,6R)-6-ethoxyethoxy-2-((1S,2R)-1',2'-epoxypropyl)-2,6-dihydropyran-3-ol 醋酸 (1R,5R,7S)-7-((phenylthio)methyl)-6,8-dioxabicyclo[3.2.1]oct-3-ene (1R,2R)-1-((2R,3R)-6-((tert-butyldimethylsilyl)oxy)-3-(4-methoxyphenoxy)-3,6-dihydro-2H-pyran-2-yl)-1-((methylsulfonyl)oxy)propan-2-yl benzoate (5R,6S)-6-((E)-2-[1,3]Dithiolan-2-yl-vinyl)-5-hydroxy-5,6-dihydro-pyran-2-one (2S,6R)-6-ethoxyethoxy-2-((1S,2R)-1',2'-epoxypropyl)-2,6-dihydropyran-3-one (2S,3S,6R)-3-benzoyloxy-6-ethoxyethoxy-2-<(1S,2R)-1',2'-epoxypropyl>-2,6-dihydropyran (1R,4S,5R,7S)-4-bromo-7-((phenylthio)methyl)-6,8-dioxabicyclo[3.2.1]oct-2-ene tert-Butyl-[(5R,6R)-5-(4-methoxy-phenoxy)-6-((2S,3R)-3-methyl-oxiranyl)-5,6-dihydro-2H-pyran-2-yloxy]-dimethyl-silane (+)-Acetylphomalactone (1S,2R,3R)-1-(2-furyl)-2,3-epoxybutan-1-ol (+/-)-(E)-1-(2-furyl)but-2-en-1-ol (1R,5R,7R)-6,8-dioxabicyclo[3.2.1]oct-3-en-7-ylmethyl methanesulfonate (2S,3S,6R)-3-acetoxy-6-ethoxyethoxy-2-<(1S,2R)-1',2'-epoxypropyl>-2,6-dihydropyran