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(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

CAS号：313963-48-3

英文名：(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

分子式：C21H42O5

分子量：374.555

合成路线

(-)-(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-2-hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane

(-)-(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-2-hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

[(2R,3S,5R,6R)-3-(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2- yl]methanol

[(2R,3S,5R,6R)-3-(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2- yl]methanol

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

(-)-(2R,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carbaldehyde

(-)-(2R,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carbaldehyde

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

上游原料

(-)-(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-2-hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane (-)-(2R,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carbaldehyde [(2R,3S,5R,6R)-3-(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2- yl]methanol

下游产品

3-{(2S,5S)-5-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-propionaldehyde (S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one (4R,12R,15S,16S,19R,20S,34S)-muricatetrocin C (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-hydroxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (12R,15S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(propan-16-onyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-hydroxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (12R,15S,16R/S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-hydroxyprop-17-ynyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(but-9-ynyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (12R,15S,16R/S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-hydroxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (E)-(4R,12R,15S,16S,19R,20S,34R)-4,16-di-tert-butyldimethylsilyloxy-19,20-butanediacetal-6-en-8-yne-muricatetrocin C