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(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one

(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one

CAS号：313963-53-0

英文名：(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one

分子式

C53H102O9Si2

熔点

密度

分子量

939.543

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one

英文名称

(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one

中文别名

英文别名

CAS号

313963-53-0

分子式

C53H102O9Si2

分子量

939.543

精确质量

938.706

PSA

90.91

LOGP

14.9077

合成路线

[(2S,5R)-5-(3-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-methanol

[(2S,5R)-5-(3-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-methanol

(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one

(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one

上游原料

共找到32个上游原料 >

(2R/S,5S)-5-(tert-butyldiphenylsilyloxymethyl)-2-(prop-2-yne-1-oxy)tetrahydrofuran

(2R/S,5S)-5-(tert-butyldiphenylsilyloxymethyl)-2-(prop-2-yne-1-oxy)tetrahydrofuran

(-)-(2R,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carbaldehyde

(-)-(2R,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carbaldehyde

(12R,15S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(propan-16-onyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane

(12R,15S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(propan-16-onyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane

3-{(2S,5S)-5-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-propionaldehyde

3-{(2S,5S)-5-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-propionaldehyde

(2S,3S,5R,6R)-3-Dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carbaldehyde

(2S,3S,5R,6R)-3-Dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carbaldehyde

(12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane

(12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane

上游原料

(2R/S,5S)-5-(tert-butyldiphenylsilyloxymethyl)-2-(prop-2-yne-1-oxy)tetrahydrofuran (-)-(2R,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane-2-carbaldehyde (12R,15S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(propan-16-onyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane 3-{(2S,5S)-5-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-propionaldehyde (2S,3S,5R,6R)-3-Dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carbaldehyde (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (2S,5S)-2-(tert-butyldiphenylsilyloxymethyl)-5-(1-benzyloxyprop-2-ynyl)tetrahydrofuran (3S,6R,9R)-6-(2'-benzyloxy)-ethyl-3-methyl-4-phenyl-1,3,4,5,6,9-hexahydro-4-aza-5-oxoisobenzofuran-1-one [(2S,5R)-5-(3-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-methanol (2'R,4R,5S)-3-(4'-benzyloxy-2'-hydroxybutylidene)-4-N-phenylaminodihydro-5-methylfuran-2-one (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-hydroxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (2'S,3R,4R,5S)-3-(4'-hydroxy-2'-tert-butyldimethylsilyloxy)butyl-4-N-phenyl-N-trifluoroacetamido-2,3,4,5-tetrahydro-5-methylfuran-2-one (12R,15S,16R/S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-hydroxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane N-{(2S,3R,4R)-4-[(S)-2-(tert-Butyl-dimethyl-silanyloxy)-4-oxo-butyl]-2-methyl-5-oxo-tetrahydro-furan-3-yl}-2,2,2-trifluoro-N-phenyl-acetamide [(2R,3S,5R,6R)-3-(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2- yl]methanol (2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-2-dodecane-[1,4]-dioxane (2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-2-dodecane-3-(2',2'-gem-dibromo)ethenyl-[1,4]-dioxane (2'R,4R,5S)-3-(4'-benzyloxy-2'-(tert-butyldimethylsilyloxy)butylidene)-4-N-phenylaminodihydro-5-methylfuran-2-one (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-hydroxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (-)-(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-2-hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane (5S)-3-[(E)-4-benzyloxybut-1-enyl]-2,5-dihydro-5-methylfuran-2-one (2S,5S)-2-(hydroxymethyl)-5-(1-benzyloxyprop-2-ynyl)tetrahydrofuran (E)-(2'S,3R,4R,5S)-3-(5'-iodo-2'-tert-butyldimethylsilyloxy)pent-4'-enyl-N-phenyl-N-trifluoroacetamido-2,3,4,5-tetrahydro-5-methylfuran-2-one tert-Butyl-[(2R,3S,5R,6R)-3-((E)-dodec-1-enyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxy]-dimethyl-silane (2S,5R)-2-(carboxymethyl)-5-(1-benzyloxypropyl)tetrahydrofuran (2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane (12R,15S,16R/S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-hydroxyprop-17-ynyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (2'S,3R,4R,5S)-3-(4'-benzyloxy-2'-tert-butyldimethylsilyloxy)butyl-4-N-phenylamino-2,3,4,5-tetrahydro-5-methylfuran-2-one (12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(but-9-ynyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane (2'S,3R,4R,5S)-3-(4'-benzyloxy-2'-tert-butyldimethylsilyloxy)butyl-4-N-phenyl-N-trifluoroacetamido-2,3,4,5-tetrahydro-5-methylfuran-2-one (E)-(4R,12R,15S,16S,19R,20S,34R)-4,16-di-tert-butyldimethylsilyloxy-19,20-butanediacetal-6-en-8-yne-muricatetrocin C (2R/S,5S)-5-(tert-butyldiphenylsilyloxymethyl)tetrahydrofuran-2-ol