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(12E)-(7S,9R,10S)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

CAS号：320573-55-5

英文名：(12E)-(7S,9R,10S)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

分子式

C21H30O6

熔点

密度

分子量

378.459

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(12E)-(7S,9R,10S)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

英文名称

(12E)-(7S,9R,10S)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

中文别名

英文别名

(7S,9R,10S,12E)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one、(E)-(7S,9R,10S)-7-(2-Hydroxy-ethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one、(3S,5R,6S)-3-(2-hydroxyethyl)-14-methoxy-5-(methoxymethoxy)-6-methyl-3,4,5,6,7,10-hexahydro-1H-2-benzoxacyclododecen-1-one

CAS号

320573-55-5

分子式

C21H30O6

分子量

378.459

精确质量

378.204

PSA

74.22

LOGP

3.1207

合成路线

共找到14条合成路线 >

(5R,6S)-5-methoxymethyl-6,9-dimethyl-3-oxo-dec-8-enoic tert-butyl ester

(5R,6S)-5-methoxymethyl-6,9-dimethyl-3-oxo-dec-8-enoic tert-butyl ester

(12E)-(7S,9R,10S)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-(2-hydroxyethyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

上游原料

共找到21个上游原料 >

(5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-yn-1-ol

(5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-yn-1-ol

(3R,5R,6S)-5-methoxymethyl-6,9-dimethyl-dec-8-ene-1,3-diol

(3R,5R,6S)-5-methoxymethyl-6,9-dimethyl-dec-8-ene-1,3-diol

{(2S,3S)-3-[(2R,3S)-5-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methylpentyl]oxiran-2-yl}methanol

{(2S,3S)-3-[(2R,3S)-5-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methylpentyl]oxiran-2-yl}methanol

(3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol

(3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol

(2R,3R,5R)-5-(tert-butyldimethylsilyloxy)-7-(4-methoxybenzyloxy)-3-methoxymethoxy-2-(prop-2-enyl)heptan-1-ol

(2R,3R,5R)-5-(tert-butyldimethylsilyloxy)-7-(4-methoxybenzyloxy)-3-methoxymethoxy-2-(prop-2-enyl)heptan-1-ol

(3R,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloctane-1,3-diol

(3R,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloctane-1,3-diol

下游产品

共找到14个下游商品 >

(12E)-(7S,9R,10S)-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-9-hydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-9-hydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-3-(carboxy)prop-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-3-(carboxy)prop-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxabenzocyclodecen-5-one

(12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxabenzocyclodecen-5-one

(12E)-(7S,9R,10S)-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-4-hydroxy-10-methyl-7,8,9,10,11,12,13,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-4-hydroxy-10-methyl-7,8,9,10,11,12,13,14-hexahydro-6-oxa-benzocyclodecen-5-one

上游原料

(5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-yn-1-ol (3R,5R,6S)-5-methoxymethyl-6,9-dimethyl-dec-8-ene-1,3-diol {(2S,3S)-3-[(2R,3S)-5-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methylpentyl]oxiran-2-yl}methanol (3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol (2R,3R,5R)-5-(tert-butyldimethylsilyloxy)-7-(4-methoxybenzyloxy)-3-methoxymethoxy-2-(prop-2-enyl)heptan-1-ol (3R,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloctane-1,3-diol (3S,4R)-1-(tert-butyldiphenylsiloxy)-4-(methoxymethoxy)-5-[(4R)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]-3-methylpentane (E,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-ene-1-ol methyl (3S,4R)-4-hydroxy-3-methyl-8-(tetrahydro-2H-pyran-2-yloxy)oct-6-ynoate (3S,4R)-1-(tert-butyldiphenylsiloxy)-3-methyl-8-(tetrahydro-2H-pyran-2-yloxy)oct-6-yn-4-ol (4S)-4,7-dimethyl-3-oxo-oct-6-enoic methyl ester (4S,5S)-5-Iodomethyl-4-methyl-dihydro-furan-2-one methyl (3S)-3-[(2S)-oxiran-2-yl]butanoate (4S,5R,7R)-6-(tert-butyldimethylsilyloxy)-9-(4-methoxybenzyloxy)-5-methoxymethoxy-4-methylnon-1-ene (3R,4S)-3-methoxymethyl-4,7-dimethyl-oct-6-enoic methyl ester (3R,5R,6S)-1-(4-methoxybenzyl)-5-methoxymethyl-6,9-dimethyl-dec-8-en-3-ol (3S,4R)-4-(methoxymethoxy)-5-[(4R)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]-3-methylpentan-1-ol (3R,4S)-3-hydroxy-4,7-dimethyl-oct-6-enoic methyl ester 2-allyl-6-methoxy-benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyl)-ethyl]-3-methoxymethyl-4,7-dimethyl-oct-6-enyl ester (5R,6S)-5-methoxymethyl-6,9-dimethyl-3-oxo-dec-8-enoic tert-butyl ester

下游产品

(12E)-(7S,9R,10S)-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-9-hydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-3-(carboxy)prop-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxabenzocyclodecen-5-one (12E)-(7S,9R,10S)-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-4-hydroxy-10-methyl-7,8,9,10,11,12,13,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-9-benzoyloxy-4-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-9-benzoyloxy-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[3-(carbomethoxy)prop-2-enyl]-4,9-dihydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (E)-4-((E)-(7S,9R,10S)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid allyl ester (12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-9-benzoyloxy-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (7S,9R,10S,12E)-7-(3-iodoallyl)-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one (7S,9R,10S,12E)-4,9-dihydroxy-7-(3-iodoallyl)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one