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amphidinolide T3

amphidinolide T3

CAS号：326591-70-2

英文名：amphidinolide T3

分子式

C25H42O5

熔点

密度

分子量

422.598

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

amphidinolide T3

英文名称

amphidinolide T3

中文别名

英文别名

(1S,6S,9R,13R,15R,17R,19S)-15-Hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxa-bicyclo[15.2.1]icosane-7,14-dione

CAS号

326591-70-2

分子式

C25H42O5

分子量

422.598

精确质量

422.303

PSA

72.83

LOGP

4.9946

合成路线

(2S,3S,5R)-2-Allyl-3-methyl-5-trityloxymethyl-tetrahydro-furan

(2S,3S,5R)-2-Allyl-3-methyl-5-trityloxymethyl-tetrahydro-furan

amphidinolide T3

amphidinolide T3

上游原料

共找到34个上游原料 >

(1S,6S,9R,13R,15R,17R,19S)-(-)-15-tert-butyldiphenylsilyloxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosane-7,14-dione

(1S,6S,9R,13R,15R,17R,19S)-(-)-15-tert-butyldiphenylsilyloxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosane-7,14-dione

(3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal

(3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal

(1S,6S,9R,13R,14R,15R,17R,19S)-14,15-dihydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icosan-7-one

(1S,6S,9R,13R,14R,15R,17R,19S)-14,15-dihydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icosan-7-one

(2S,3S,5R)-2-Allyl-3-methyl-5-trityloxymethyl-tetrahydro-furan

(2S,3S,5R)-2-Allyl-3-methyl-5-trityloxymethyl-tetrahydro-furan

(S)-6-((2S,3S,5R)-5-{(R)-2-Hydroxy-2-[2-((1R,5R)-5-hydroxy-1-methyl-3-methylene-octyl)-[1,3]dithian-2-yl]-ethyl}-3-methyl-tetrahydro-furan-2-yl)-2-methyl-hexanoic acid

(S)-6-((2S,3S,5R)-5-{(R)-2-Hydroxy-2-[2-((1R,5R)-5-hydroxy-1-methyl-3-methylene-octyl)-[1,3]dithian-2-yl]-ethyl}-3-methyl-tetrahydro-furan-2-yl)-2-methyl-hexanoic acid

{(R)-1-[2-((R)-3-Benzyloxymethoxy-2-methyl-propyl)-[1,3]dithian-2-ylmethyl]-butoxy}-tert-butyl-dimethyl-silane

{(R)-1-[2-((R)-3-Benzyloxymethoxy-2-methyl-propyl)-[1,3]dithian-2-ylmethyl]-butoxy}-tert-butyl-dimethyl-silane

上游原料

(1S,6S,9R,13R,15R,17R,19S)-(-)-15-tert-butyldiphenylsilyloxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosane-7,14-dione (3R)-3-{[(tert-butyl)dimethylsilyl]oxy}hexanal (1S,6S,9R,13R,14R,15R,17R,19S)-14,15-dihydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]icosan-7-one (2S,3S,5R)-2-Allyl-3-methyl-5-trityloxymethyl-tetrahydro-furan (S)-6-((2S,3S,5R)-5-{(R)-2-Hydroxy-2-[2-((1R,5R)-5-hydroxy-1-methyl-3-methylene-octyl)-[1,3]dithian-2-yl]-ethyl}-3-methyl-tetrahydro-furan-2-yl)-2-methyl-hexanoic acid {(R)-1-[2-((R)-3-Benzyloxymethoxy-2-methyl-propyl)-[1,3]dithian-2-ylmethyl]-butoxy}-tert-butyl-dimethyl-silane (2S,3S,5R)-2-(3-Iodo-propyl)-3-methyl-5-trityloxymethyl-tetrahydro-furan ((1R,5R)-6-Benzyloxymethoxy-5-methyl-3-methylene-1-propyl-hexyloxy)-tert-butyl-dimethyl-silane (2S,3S,5R)-2-((R)-4-Benzenesulfonyl-6-benzyloxy-5-methyl-hexyl)-3-methyl-5-trityloxymethyl-tetrahydro-furan (2S,3S,5R)-2-((S)-6-Benzyloxy-5-methyl-hexyl)-3-methyl-5-trityloxymethyl-tetrahydro-furan (2S,3S,5R)-2-((S)-6-Benzyloxy-5-methyl-hexyl)-5-iodomethyl-3-methyl-tetrahydro-furan 3-((2S,3S,5R)-3-Methyl-5-trityloxymethyl-tetrahydro-furan-2-yl)-propan-1-ol (2R,3S,4R,2'R,4'S,5'S)-(-)-1-(5-allyl-4-methyltetrahydrofuran-2-yl)-5-(tert-butyldimethylsilanyloxy)-2-(tert-butyldiphenylsilanyloxy)-3-methoxymethoxy-4-methylpentane Acetic acid (1R,3S,4R)-3-methyl-4-(toluene-4-sulfonyloxy)-1-trityloxymethyl-hept-6-enyl ester (2R,3S,4R,2'R,4'S,5'S)-(-)-1-(5-allyl-4-methyltetrahydrofuran-2-yl)-5-(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpentan-2-ol (R)-1-[1,3]Dithian-2-yl-pentan-2-ol Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester ethyl (R)-3-(tert-butyldimethylsilyloxy)hexanoate tert-Butyl-((R)-1-[1,3]dithian-2-ylmethyl-butoxy)-dimethyl-silane tert-Butyl-((1R,5R)-5-[1,3]dithian-2-yl-3-methylene-1-propyl-hexyloxy)-dimethyl-silane (2R,3S,4R,2'R,4'S,5'S)-(-)-1-(5-allyl-4-methyltetrahydrofuran-2-yl)-2-(tert-butyldiphenylsilanyloxy)-3-methoxymethoxy-4-methylpentan-5-ol [(2R,4S,5S)-5-((S)-6-Benzyloxy-5-methyl-hexyl)-4-methyl-tetrahydro-furan-2-yl]-acetaldehyde (3S,4R)-(-)-5-(tert-butyldimethylsilanyloxy)-3-methoxymethoxy-4-methylpentan-2-one Acetic acid (R)-2-[(2R,4S,5S)-5-((S)-6-benzyloxy-5-methyl-hexyl)-4-methyl-tetrahydro-furan-2-yl]-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-ethyl ester (1S,6S,9R,13R,14S,15R,17R,19S)-(-)-15-tert-butyldiphenylsilyloxy-14-hydroxy-6,13,19-trimethyl-11-methylene-9-propyl-8,20-dioxabicyclo[15.2.1]eicosan-7-one Acetic acid (R)-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-2-[(2R,4S,5S)-5-((S)-6-hydroxy-5-methyl-hexyl)-4-methyl-tetrahydro-furan-2-yl]-ethyl ester (2S,3S,5R)-2-((S)-6-Benzyloxy-5-methyl-hexyl)-5-[1,3]dithian-2-ylmethyl-3-methyl-tetrahydro-furan (2R,3S,4R,2'R,4'S,5'S)-(-)-1-(5-allyl-4-methyltetrahydrofuran-2-yl)-2-(tert-butyldiphenylsilanyloxy)-3-methoxymethoxy-4-methyl-5-iodopentane (2R)-4-((2R)-2-[1-(tert-butyl)-1,1-dimethylsilyl]oxypentyl)-2-methyl-4-pentenal Acetic acid (R)-1-{2-[(1R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-1-methyl-3-methylene-octyl]-[1,3]dithian-2-yl}-2-[(2R,4S,5S)-4-methyl-5-((S)-5-methyl-6-oxo-hexyl)-tetrahydro-furan-2-yl]-ethyl ester (S)-6-((2S,3S,5R)-5-{(R)-2-Acetoxy-2-[2-((1R,5R)-5-hydroxy-1-methyl-3-methylene-octyl)-[1,3]dithian-2-yl]-ethyl}-3-methyl-tetrahydro-furan-2-yl)-2-methyl-hexanoic acid (2'S,3'R,4S,5R)-(-)-3-(3-methoxymethoxy-2,4-dimethylpent-4-enoyl)-4-methyl-5-phenyloxazolidin-2-one