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Boc-D-苯甘氨酸

Boc-D-苯甘氨酸

CAS号：33125-05-2

英文名：(2R)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-phenylacetic acid

分子式

C13H17NO4

熔点

88-91°C

密度

1.182g/cm3

分子量

251.278

沸点

407.2ºC at 760mmHg

溶解度

信号词

危险品标志

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化合物简介

(αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.

基本信息

中文名称

Boc-D-苯甘氨酸

英文名称

(2R)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-phenylacetic acid

中文别名

N-Boc-D-苯基甘氨酸、BOC-D-苯甘氨酸、N-Boc-D-2-苯甘氨酸、N-(叔丁氧羰基)-D-2-苯甘氨酸、Boc-D-α-苯基甘氨酸、Boc-D-α-苯甘氨酸、N-叔丁氧羰基-D-苯甘氨酸

英文别名

N-Boc-D-2-phenylglycine、(R)-2-((tert-Butoxycarbonyl)amino)-2-phenylacetic acid、Boc-D-α-phenylglycine、Boc-D-Phg-OH、N-Boc-D-Phenylglycine、Boc-D-phenylglycine、BOC-D-alpha-phenylglycine、D-N-Boc-phenylglycine、N-(tert-Butoxycarbonyl)-D-2-phenylglycine、N-Boc-L-phenylglycine

CAS号

33125-05-2

分子式

C13H17NO4

分子量

251.278

精确质量

251.116

PSA

66.84

LOGP

2.5127

编号系统

MDL号

MFCD00062043

物化性质

密度

1.182g/cm3

沸点

407.2ºC at 760mmHg

熔点

88-91°C

闪点

200.1ºC

折射率

-140 ° (C=1, EtOH)

储存条件

Store at RT.

安全信息

安全说明

S24/25

WGK Germany

3

海关编码

2924299090

合成路线

共找到20条合成路线 >

tert-butyl N-(2-nitro-1-phenylethyl)carbamate

tert-butyl N-(2-nitro-1-phenylethyl)carbamate

Boc-D-苯甘氨酸

Boc-D-苯甘氨酸

N-(叔丁氧羰基)-L-2-苯甘氨酸

N-(叔丁氧羰基)-L-2-苯甘氨酸

海关数据

共找到8个国家海关数据 >

国家/地区名称	海关编码	更新时间	操作
中国	2924299090	2019-03	查看
美国	2924297690	2019-03	查看
印度	29242990	2019-03	查看
欧盟	29242998	2019-03	查看
英国	2924299899	2019-03	查看
日本	292429090	2019-03	查看
韩国	2924299090	2019-03	查看
加拿大	2924290030	2019-03	查看

上游原料

共找到40个上游原料 >

tert-butyl [(1R)-2-nitro-1-phenylethyl]carbamate

tert-butyl [(1R)-2-nitro-1-phenylethyl]carbamate

二碳酸二叔丁酯

二碳酸二叔丁酯

N-重氮基氨基甲酸叔-丁基酯

N-重氮基氨基甲酸叔-丁基酯

甲酸叔丁酯

甲酸叔丁酯

苯甲酰硝基甲烷

苯甲酰硝基甲烷

tert-butyl N-[benzenesulfonyl(phenyl)methyl]carbamate

tert-butyl N-[benzenesulfonyl(phenyl)methyl]carbamate

下游产品

共找到18个下游商品 >

D-苯甘氨酸甲酯盐酸盐

D-苯甘氨酸甲酯盐酸盐

N'-(N-tert-butoxycarbonyl-DL-phenylglycinyl)-5-nitro-2-furancarbohydrazide

N'-(N-tert-butoxycarbonyl-DL-phenylglycinyl)-5-nitro-2-furancarbohydrazide

D-(-)-alpha-苯甘氨酸

D-(-)-alpha-苯甘氨酸

[(2-Oxo-propylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester

[(2-Oxo-propylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester

[(1-Methyl-2-oxo-2-phenyl-ethylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester

[(1-Methyl-2-oxo-2-phenyl-ethylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester

[(2-Oxo-cyclohexylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester

[(2-Oxo-cyclohexylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester

上游原料

tert-butyl [(1R)-2-nitro-1-phenylethyl]carbamate 二碳酸二叔丁酯 N-重氮基氨基甲酸叔-丁基酯甲酸叔丁酯苯甲酰硝基甲烷 tert-butyl N-[benzenesulfonyl(phenyl)methyl]carbamate tert-butyl N-(2-nitro-1-phenylethyl)carbamate DL-α-氨基苯乙酸 N-(叔丁氧羰基)-L-2-苯甘氨酸 N-Boc-DL-苯甘氨醇 N-(trimethylsilyl)-N-(tert-butyloxycarbonyl)benzylamine N-(triisopropylsilyl)-N-(tert-butyloxycarbonyl)benzylamine 桂皮醛 (2S,3R)-3-((tert-butoxycarbonyl)amino)-3-phenyl-1,2-propanediol tert-butyl benzyl((1R,2S)-2,3-bis(benzyloxy)-1-phenylpropyl)carbamate 2-甲基-2-丙基[(1R)-2-氧代-1-苯基乙基]氨基甲酸酯 (1R,2R)-3-amino-3-phenyl-1,2-propanediol 苯甲醛 D-(-)-alpha-苯甘氨酸溴化苯基镁 (2R,3R)-3-diphenylmethylamino-3-phenyl-1,2-diol tert-butyl (R)-(2-(benzyloxy)-1-phenylethyl)carbamate (S)-(-)-(E)-1-phenylhexa-1,5-dien-3-ol (R)-Phenylglycine HCl (2R,3R)-3-[(tert-butoxycarbonyl)amino]-3-phenyl-1,2-propanediol (R)-2-nitro-1-phenylethan-1-amine (R)-1-phenyl-2-(phenylmethoxy)ethylamine 苄基-氨基甲酸叔丁酯 (R)-4-methoxy-N-(2-nitro-1-phenylethyl)aniline tert-butyl (1S,2E)-1-phenylhexa-2,5-dienylcarbamate 2-(叔丁氧羰基氧亚氨基)-2-苯乙腈 1-(t-butoxycarbonyl)-1,2,4-triazolo(4,3-a)pyridinium-3-olate 2,2,2-trichloro-N-[(1S,2E)-1-phenylhexa-1,5-dienyl]acetamide 二氧化碳 (苯基亚甲基)氨基甲酸叔丁酯 (1R,2S)-N-Benzyl-2,3-dibenzyloxy-1-phenyl-1-propylamine diethyl 2-tert-butoxycarbonyloxyiminomalonate tert-butyl [(1S)-1-phenylprop-2-en-1-yl]imidocarbonate 氨基甲酸叔丁酯

下游产品

D-苯甘氨酸甲酯盐酸盐 N'-(N-tert-butoxycarbonyl-DL-phenylglycinyl)-5-nitro-2-furancarbohydrazide D-(-)-alpha-苯甘氨酸 [(2-Oxo-propylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester [(1-Methyl-2-oxo-2-phenyl-ethylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester [(2-Oxo-cyclohexylcarbamoyl)-phenyl-methyl]-carbamic acid tert-butyl ester (6R,7R)-7-(2-tert-Butoxycarbonylamino-2-phenyl-acetylamino)-8-oxo-3-(1-trityl-1H-[1,2,3]triazol-4-ylsulfanylmethylsulfanyl)-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester (6R)-7t-((R)-2-tert-butoxycarbonylamino-2-phenyl-acetylamino)-3-(5-methyl-[1,3,4]thiadiazol-2-ylsulfanylmethyl)-5ξ,8-dioxo-(6rH)-5λ4-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid 2,2-dimethyl-propionyloxymethyl ester 1-(tert-butoxycarbonylamino)-1-phenylundecan-2-one 头孢来星 (6R)-7t-((R)-2-tert-butoxycarbonylamino-2-phenyl-acetylamino)-3-(5-methyl-[1,3,4]thiadiazol-2-ylsulfanylmethyl)-8-oxo-(6rH)-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid 2,2-dimethyl-propionyloxymethyl ester (R)-(+)-N-异丙基-1-苯基-2-(1-哌啶基)乙胺 2-((叔丁氧基羰基)氨基)-2-苯乙酸甲酯 N-Boc-DL-苯甘氨醇 1-(1-benzylpiperidin-4-yl)-4-phenyl-imidazolidin-2-one Boc-DL-Phg-Lys(Z)-CH2Cl N-(2-iodophenyl)-2-methyl-4-phenyloxazol-5-amine 2-甲基-2-丙基[(1R)-2-氧代-1-苯基乙基]氨基甲酸酯