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(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
CAS号:350794-21-7
英文名:(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
分子式:C32H51N3O5Si2
分子量:613.935
搜索商品
合成路线
320573-57-7
(E)-4-((E)-(7S,9R,10S)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid allyl ester
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
398478-61-0
(12E)-(7S,9R,10S)-7-[3-(carbomethoxy)prop-2-enyl]-4,9-dihydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
356548-45-3
3-(iodomethyl)-8-methoxy-3,4-dihydro-1H-isochromen-1-one
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
474254-56-3
(2R,3S)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-methyl-pent-4-en-2-ol
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
474254-53-0
(E)-(5R,7R,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-8-methyl-undeca-2,10-dien-5-ol
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
474254-52-9
2-Allyl-6-methoxy-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-4-(4-methoxy-benzyloxy)-but-2-enyl]-4-methyl-hept-6-enyl ester
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
350794-20-6
2-Allyl-6-(tert-butyl-dimethyl-silanyloxy)-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-((E)-3-methoxycarbonyl-allyl)-4-methyl-hept-6-enyl ester
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
474254-66-5
(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
474254-65-4
(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
474254-64-3
(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-7-((E)-4-hydroxy-but-2-enyl)-4-methoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
350794-21-7
(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
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上游原料
tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-but-3-enyloxy]-dimethyl-silane
2-Allyl-6-methoxy-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-4-(4-methoxy-benzyloxy)-but-2-enyl]-4-methyl-hept-6-enyl ester
(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enoic acid
(2R,3S)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-methyl-pent-4-en-2-ol
(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal
tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-pent-4-enyloxy]-dimethyl-silane
(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal
(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-7-((E)-4-hydroxy-but-2-enyl)-4-methoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
(3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-methyl-pentanal
(3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-methyl-pentan-1-ol
(12E)-(7S,9R,10S)-7-[3-(carbomethoxy)prop-2-enyl]-4,9-dihydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one
(E)-4-((E)-(7S,9R,10S)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid allyl ester
3-(iodomethyl)-8-methoxy-3,4-dihydro-1H-isochromen-1-one
(E)-(5R,7R,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-8-methyl-undeca-2,10-dien-5-ol
(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-7-[(E)-4-(4-methoxy-benzyloxy)-but-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one
2-Allyl-6-(tert-butyl-dimethyl-silanyloxy)-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-((E)-3-methoxycarbonyl-allyl)-4-methyl-hept-6-enyl ester
tert-Butyl-dimethyl-((1R,2S)-2-methyl-1-(S)-1-oxiranylmethyl-pent-4-enyloxy)-silane
(2S,4R,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-methyl-oct-7-ene-1,2-diol
下游产品
(2Z,4Z)-Hepta-2,4-dienoic acid {(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-amide
1,3-Bis-{(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-1-((2Z,4Z)-hepta-2,4-dienoyl)-urea
{(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-carbamic acid 2-trimethylsilanyl-ethyl ester
{(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-((2Z,4Z)-hepta-2,4-dienoyl)-carbamic acid 2-trimethylsilanyl-ethyl ester