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(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

CAS号：350794-21-7

英文名：(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

分子式

C32H51N3O5Si2

熔点

密度

分子量

613.935

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

英文名称

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

中文别名

英文别名

(E)-4-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enoyl azide

CAS号

350794-21-7

分子式

C32H51N3O5Si2

分子量

613.935

精确质量

613.337

PSA

111.58

LOGP

8.75096

合成路线

共找到4条合成路线 >

(E)-4-((E)-(7S,9R,10S)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid allyl ester

(E)-4-((E)-(7S,9R,10S)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid allyl ester

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4,9-bis-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

上游原料

共找到18个上游原料 >

tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-but-3-enyloxy]-dimethyl-silane

tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-but-3-enyloxy]-dimethyl-silane

2-Allyl-6-methoxy-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-4-(4-methoxy-benzyloxy)-but-2-enyl]-4-methyl-hept-6-enyl ester

2-Allyl-6-methoxy-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-4-(4-methoxy-benzyloxy)-but-2-enyl]-4-methyl-hept-6-enyl ester

(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enoic acid

(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enoic acid

(2R,3S)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-methyl-pent-4-en-2-ol

(2R,3S)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-methyl-pent-4-en-2-ol

(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal

(E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal

tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-pent-4-enyloxy]-dimethyl-silane

tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-pent-4-enyloxy]-dimethyl-silane

下游产品

共找到4个下游商品 >

(2Z,4Z)-Hepta-2,4-dienoic acid {(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-amide

(2Z,4Z)-Hepta-2,4-dienoic acid {(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-amide

1,3-Bis-{(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-1-((2Z,4Z)-hepta-2,4-dienoyl)-urea

1,3-Bis-{(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-1-((2Z,4Z)-hepta-2,4-dienoyl)-urea

{(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-carbamic acid 2-trimethylsilanyl-ethyl ester

{(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-carbamic acid 2-trimethylsilanyl-ethyl ester

{(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-((2Z,4Z)-hepta-2,4-dienoyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

{(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-((2Z,4Z)-hepta-2,4-dienoyl)-carbamic acid 2-trimethylsilanyl-ethyl ester

上游原料

tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-but-3-enyloxy]-dimethyl-silane 2-Allyl-6-methoxy-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-[(E)-4-(4-methoxy-benzyloxy)-but-2-enyl]-4-methyl-hept-6-enyl ester (E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enoic acid (2R,3S)-1-((S)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-methyl-pent-4-en-2-ol (E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-hydroxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal tert-Butyl-[(1R,2S)-1-((S)-2,2-diethyl-[1,3]dioxolan-4-ylmethyl)-2-methyl-pent-4-enyloxy]-dimethyl-silane (E)-4-[(E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-but-2-enal (E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-7-((E)-4-hydroxy-but-2-enyl)-4-methoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one (3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-methyl-pentanal (3S,4R)-4-(tert-Butyl-dimethyl-silanyloxy)-5-((S)-2,2-diethyl-[1,3]dioxolan-4-yl)-3-methyl-pentan-1-ol (12E)-(7S,9R,10S)-7-[3-(carbomethoxy)prop-2-enyl]-4,9-dihydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (E)-4-((E)-(7S,9R,10S)-4-Methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-but-2-enoic acid allyl ester 3-(iodomethyl)-8-methoxy-3,4-dihydro-1H-isochromen-1-one (E)-(5R,7R,8S)-7-(tert-Butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-8-methyl-undeca-2,10-dien-5-ol (E)-(7S,9R,10S)-9-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-7-[(E)-4-(4-methoxy-benzyloxy)-but-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclododecen-5-one 2-Allyl-6-(tert-butyl-dimethyl-silanyloxy)-benzoic acid (1S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-((E)-3-methoxycarbonyl-allyl)-4-methyl-hept-6-enyl ester tert-Butyl-dimethyl-((1R,2S)-2-methyl-1-(S)-1-oxiranylmethyl-pent-4-enyloxy)-silane (2S,4R,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-5-methyl-oct-7-ene-1,2-diol

下游产品

(2Z,4Z)-Hepta-2,4-dienoic acid {(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-amide 1,3-Bis-{(E)-3-[(E)-(7S,9R,10S)-4,9-bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-1-((2Z,4Z)-hepta-2,4-dienoyl)-urea {(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-carbamic acid 2-trimethylsilanyl-ethyl ester {(E)-3-[(E)-(7S,9R,10S)-4,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl]-propenyl}-((2Z,4Z)-hepta-2,4-dienoyl)-carbamic acid 2-trimethylsilanyl-ethyl ester