化合物简介
Phanephos is an organophosphorus compound with the chemical formula (C2H4)2(C6H3PPh2)2 (Ph = C6H5). It is a white solid that is soluble in organic solvents. It is an example of a chiral diphosphine used in asymmetric hydrogenation. Many substituents have been introduced in place of the phenyl groups, e.g., i-Pr, C6H11, etc and a variety of chiral phosphine ligands have been reported in asymmetric catalysis since the 1960s.
基本信息
中文名称
(R)-4,12-二(二苯基膦基)[2.2]对环芳烷
英文名称
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
中文别名
(R)-(–)-4,12-双(二苯基膦)-[2.2]-对环芳烷
英文别名
(R)-Phanephos、(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane
CAS号
364732-88-7
分子式
C40H34P2
分子量
576.645
精确质量
576.214
PSA
27.18
LOGP
7.0868
编号系统
MDL号
MFCD03094575
PubChem号
24885681
物化性质
熔点
222-225ºC
安全信息
危险类别码
R37
危险品标志
Xi