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(E)-(1S,5R,9R,10R,11R,12R,13S)-5-((1E,3E)-6-Cyclopropyl-hexa-1,3-dien-5-ynyl)-1,13-dihydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

(E)-(1S,5R,9R,10R,11R,12R,13S)-5-((1E,3E)-6-Cyclopropyl-hexa-1,3-dien-5-ynyl)-1,13-dihydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

CAS号：370562-09-7

英文名：(E)-(1S,5R,9R,10R,11R,12R,13S)-5-((1E,3E)-6-Cyclopropyl-hexa-1,3-dien-5-ynyl)-1,13-dihydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

分子式

C26H36O6

熔点

密度

分子量

444.56

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(E)-(1S,5R,9R,10R,11R,12R,13S)-5-((1E,3E)-6-Cyclopropyl-hexa-1,3-dien-5-ynyl)-1,13-dihydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

英文名称

(E)-(1S,5R,9R,10R,11R,12R,13S)-5-((1E,3E)-6-Cyclopropyl-hexa-1,3-dien-5-ynyl)-1,13-dihydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

中文别名

英文别名

CAS号

370562-09-7

分子式

C26H36O6

分子量

444.56

精确质量

444.251

PSA

85.22

LOGP

3.2897

合成路线

(E)-(2S,3S,4S,5R,9R)-3-Hydroxy-5-methoxy-9-(4-methoxy-phenoxy)-2,4,7-trimethyl-undeca-6,10-dienethioic acid S-tert-butyl ester

(E)-(2S,3S,4S,5R,9R)-3-Hydroxy-5-methoxy-9-(4-methoxy-phenoxy)-2,4,7-trimethyl-undeca-6,10-dienethioic acid S-tert-butyl ester

(E)-(1S,5R,9R,10R,11R,12R,13S)-5-((1E,3E)-6-Cyclopropyl-hexa-1,3-dien-5-ynyl)-1,13-dihydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

(E)-(1S,5R,9R,10R,11R,12R,13S)-5-((1E,3E)-6-Cyclopropyl-hexa-1,3-dien-5-ynyl)-1,13-dihydroxy-9-methoxy-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

上游原料

共找到4个上游原料 >

(E)-(6S,7R,8S,9R,10R,14R)-6,8-bis(tert-butyldimethylsilanyloxy)-14[(1E,3E)-4-iodobuta-1,3-dienyl]-10-methoxy-7,9,12-trimethyloxacyclotetradec-11-ene-2,4-dione

(E)-(6S,7R,8S,9R,10R,14R)-6,8-bis(tert-butyldimethylsilanyloxy)-14[(1E,3E)-4-iodobuta-1,3-dienyl]-10-methoxy-7,9,12-trimethyloxacyclotetradec-11-ene-2,4-dione

Carbonic acid (2E,5E)-(7R,8S)-9-(tert-butyl-dimethyl-silanyloxy)-7-methoxy-5,8-dimethyl-nona-2,5-dienyl ester 2,2,2-trichloro-ethyl ester

Carbonic acid (2E,5E)-(7R,8S)-9-(tert-butyl-dimethyl-silanyloxy)-7-methoxy-5,8-dimethyl-nona-2,5-dienyl ester 2,2,2-trichloro-ethyl ester

(E)-(6S,7R,8S,9R,10R,14R)-6,8-Bis-(tert-butyl-dimethyl-silanyloxy)-14-(1,2-dihydroxy-ethyl)-10-methoxy-7,9,12-trimethyl-oxacyclotetradec-11-ene-2,4-dione

(E)-(6S,7R,8S,9R,10R,14R)-6,8-Bis-(tert-butyl-dimethyl-silanyloxy)-14-(1,2-dihydroxy-ethyl)-10-methoxy-7,9,12-trimethyl-oxacyclotetradec-11-ene-2,4-dione

(E)-(2S,3S,4S,5R,9R)-3-Hydroxy-5-methoxy-9-(4-methoxy-phenoxy)-2,4,7-trimethyl-undeca-6,10-dienethioic acid S-tert-butyl ester

(E)-(2S,3S,4S,5R,9R)-3-Hydroxy-5-methoxy-9-(4-methoxy-phenoxy)-2,4,7-trimethyl-undeca-6,10-dienethioic acid S-tert-butyl ester

上游原料

(E)-(6S,7R,8S,9R,10R,14R)-6,8-bis(tert-butyldimethylsilanyloxy)-14[(1E,3E)-4-iodobuta-1,3-dienyl]-10-methoxy-7,9,12-trimethyloxacyclotetradec-11-ene-2,4-dione Carbonic acid (2E,5E)-(7R,8S)-9-(tert-butyl-dimethyl-silanyloxy)-7-methoxy-5,8-dimethyl-nona-2,5-dienyl ester 2,2,2-trichloro-ethyl ester (E)-(6S,7R,8S,9R,10R,14R)-6,8-Bis-(tert-butyl-dimethyl-silanyloxy)-14-(1,2-dihydroxy-ethyl)-10-methoxy-7,9,12-trimethyl-oxacyclotetradec-11-ene-2,4-dione (E)-(2S,3S,4S,5R,9R)-3-Hydroxy-5-methoxy-9-(4-methoxy-phenoxy)-2,4,7-trimethyl-undeca-6,10-dienethioic acid S-tert-butyl ester