百科

井冈霉素

井冈霉素

CAS号：37248-47-8

英文名：validamycin A

分子式

C20H35NO13

熔点

130-135ºC

密度

1.69g/cm3

分子量

497.491

沸点

813.7ºC at 760mmHg

溶解度

信号词

危险品标志

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化合物简介

Validamycin is an antibiotic and fungicide produced by Streptomyces hygroscopicus. It is used as an inhibitor of trehalase. It is used for the control of sheath blight of rice and damping-off of cucumbers.

基本信息

中文名称

井冈霉素

英文名称

validamycin A

中文别名

井岗霉素

英文别名

valimon、VALDIDAMYCIN、SOLACOL、validamycin、VALIDACIN、jiangonmycin、Validamycin、VALIDAMYCIN A、Validamycin A、MYCIN、validomycin A、Jinganmycin A、1,5,6-trideoxy-4-O-β-D-glucopyranosyl-5-(hydroxymethyl)-1-[[(1S,4R,5S,6S)-4,5,6-trihydroxy-3-(hydroxymethyl)-2-cyclohexen-1-yl]amino]-D-chiro-inositol、(1R,2R,3S,4S,6R)-2,3-dihydroxy-6-hydroxymethyl-4-[(1S,4R,5S,6S)-4,5,6-trihydroxy-3-hydroxymethylcyclohex-2-enylamino]cyclohexyl β-D-glucopyranoside

CAS号

37248-47-8

分子式

C20H35NO13

分子量

497.491

精确质量

497.211

PSA

253.02

LOGP

-6.3618

编号系统

UNII

313E9620QS

物化性质

外观与性状

白色粉末

密度

1.69g/cm3

沸点

813.7ºC at 760mmHg

熔点

130-135ºC

闪点

445.9ºC

折射率

1.689

储存条件

库房通风低温干燥,与食品原料分开储运

生产方法及用途

生产方法

由吸水链霉素井冈变种发酵提取制成。工艺流程:砂土管—母斜面—茄子瓶—种子罐—发酵罐—放罐

用途

微生物源杀菌剂,主要用于防治水稻纹枯病,兼有保护和治疗作用,兼治小粒菌核病、玉米大斑病、蔬菜立枯病和根腐病,棉花、豆类、人参立枯病等。使用时可喷雾、拌种、灌土等。可与乐果、杀螟丹等农药混用。

合成路线

共找到2条合成路线 >

D-葡萄糖

6-氨基-4-(羟甲基)-4-环己基-[4H,5H]-1,2,3-三醇

6-氨基-4-(羟甲基)-4-环己基-[4H,5H]-1,2,3-三醇

井冈霉烯胺

井冈霉烯胺

4-(羟基甲基)-6-[[4,5,6-三羟基-3-(羟基甲基)-1-环己-2-烯基]氨基]环己烷-1,2,3,5-四醇

4-(羟基甲基)-6-[[4,5,6-三羟基-3-(羟基甲基)-1-环己-2-烯基]氨基]环己烷-1,2,3,5-四醇

井冈霉素

上游原料

共找到13个上游原料 >

validamycin A undeca-O-acetate

validamycin A undeca-O-acetate

validamycin A undecabenzyl ether

validamycin A undecabenzyl ether

(1R,2S,5R,7R,8R,9R,10R)-8,9-dibenzyloxy-5-phenyl-4,6,11-trioxatricyclo[8.1.0.02.7]undecane

(1R,2S,5R,7R,8R,9R,10R)-8,9-dibenzyloxy-5-phenyl-4,6,11-trioxatricyclo[8.1.0.02.7]undecane

4,7-O-benzylidenevalidoxylamine A hexa-O-acetate

4,7-O-benzylidenevalidoxylamine A hexa-O-acetate

2,3,4',5',6',7'-hexa-O-benzylvalidoxylamine A

2,3,4',5',6',7'-hexa-O-benzylvalidoxylamine A

2,3,4',5',6',7'-hexa-O-benzyl-4,5-O-benzyllidenevalidoxylamine B

2,3,4',5',6',7'-hexa-O-benzyl-4,5-O-benzyllidenevalidoxylamine B

下游产品

共找到4个下游商品 >

6-氨基-4-(羟甲基)-4-环己基-[4H,5H]-1,2,3-三醇

6-氨基-4-(羟甲基)-4-环己基-[4H,5H]-1,2,3-三醇

4-(羟基甲基)-6-[[2,3,4-三羟基-5-(羟基甲基)环己基]氨基]环己-4-烯-1,2,3-三醇

4-(羟基甲基)-6-[[2,3,4-三羟基-5-(羟基甲基)环己基]氨基]环己-4-烯-1,2,3-三醇

(2S,3R,4R,5S,6S)-2-(hydroxymethyl)-6-[(1R,2R,3S,4R,5R,6S)-2,3,5-trihydroxy-6-(hydroxymethyl)-4-[[(1R,4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino]cyclohexyl]oxyoxane-3,4,5-triol

(2S,3R,4R,5S,6S)-2-(hydroxymethyl)-6-[(1R,2R,3S,4R,5R,6S)-2,3,5-trihydroxy-6-(hydroxymethyl)-4-[[(1R,4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino]cyclohexyl]oxyoxane-3,4,5-triol

井冈霉烯胺

井冈霉烯胺

上游原料

validamycin A undeca-O-acetate validamycin A undecabenzyl ether (1R,2S,5R,7R,8R,9R,10R)-8,9-dibenzyloxy-5-phenyl-4,6,11-trioxatricyclo[8.1.0.02.7]undecane 4,7-O-benzylidenevalidoxylamine A hexa-O-acetate 2,3,4',5',6',7'-hexa-O-benzylvalidoxylamine A 2,3,4',5',6',7'-hexa-O-benzyl-4,5-O-benzyllidenevalidoxylamine B 7-O-acetyl-2,3,4',5',6',7'-hexa-O-benzylvalidoxylamine A D-葡萄糖 7,2'',3'',4'',6''-penta-O-acetyl-2,3,4',5',6',7'-hexa-O-benzylvalidamycin A 2,3,4',5',6',7'-hexa-O-benzyl-4,7-O-benzylidene-6-p-toluenesulphenylvalidoxylamine A 1D-(1,3,6/2)-6-amino-4-benzyloxymethyl-1,2,3-tri-O-benzyltrihydroxycyclohex-4-ene (4aR,6S,7S,8S,8aR)-7,8-bis(benzyloxy)-2-phenyl-N-((1S,4R,5S,6S)-4,5,6-tris(benzyloxy)-3-((benzyloxy)methyl)cyclohex-2-en-1-yl)hexahydro-4H-benzo[d][1,3]dioxin-6-amine (1S,2R,5R,7R,8S,10S)-8,9-dibenzyloxy-11-((1S)-(1,4,6/5)-4,5,6-tribenzyloxy-3-benzyloxymethylcyclohex-2enyl)-5-phenyl-4,6-dioxa-11-azatricyclo(8.1.0.0.2,7)undecane

下游产品

6-氨基-4-(羟甲基)-4-环己基-[4H,5H]-1,2,3-三醇 4-(羟基甲基)-6-[[2,3,4-三羟基-5-(羟基甲基)环己基]氨基]环己-4-烯-1,2,3-三醇 (2S,3R,4R,5S,6S)-2-(hydroxymethyl)-6-[(1R,2R,3S,4R,5R,6S)-2,3,5-trihydroxy-6-(hydroxymethyl)-4-[[(1R,4S,5R,6R)-4,5,6-trihydroxy-3-(hydroxymethyl)cyclohex-2-en-1-yl]amino]cyclohexyl]oxyoxane-3,4,5-triol 井冈霉烯胺