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(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

CAS号：379269-84-8

英文名：(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

分子式

C32H46O7

熔点

密度

分子量

542.703

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

英文名称

(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

中文别名

英文别名

CAS号

379269-84-8

分子式

C32H46O7

分子量

542.703

精确质量

542.324

PSA

83.45

LOGP

5.5221

合成路线

(Z)-4-[(2R,6R)-6-((S)-2,4-Dimethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid (E)-(1S,2S)-1-[(E)-3-((4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester

(Z)-4-[(2R,6R)-6-((S)-2,4-Dimethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid (E)-(1S,2S)-1-[(E)-3-((4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester

(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

上游原料

共找到6个上游原料 >

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde

(Z)-4-[(2R,6R)-6-((S)-2,4-Dimethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid (E)-(1S,2S)-1-[(E)-3-((4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester

(Z)-4-[(2R,6R)-6-((S)-2,4-Dimethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid (E)-(1S,2S)-1-[(E)-3-((4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester

(4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane

(4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane

(S)-2-allyloxy-4-methyl-1-trityloxy-4-pentene

(S)-2-allyloxy-4-methyl-1-trityloxy-4-pentene

(6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one

(6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one

(S)-2-[(E)-(3S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-hex-1-enyl]-4-methyl-3,6-dihydro-2H-pyran

(S)-2-[(E)-(3S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-hex-1-enyl]-4-methyl-3,6-dihydro-2H-pyran

上游原料

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde (Z)-4-[(2R,6R)-6-((S)-2,4-Dimethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid (E)-(1S,2S)-1-[(E)-3-((4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester (4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane (S)-2-allyloxy-4-methyl-1-trityloxy-4-pentene (6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one (S)-2-[(E)-(3S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-hex-1-enyl]-4-methyl-3,6-dihydro-2H-pyran