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(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
CAS号:381665-44-7
英文名:(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
分子式:C26H47IO5Si2
分子量:622.724
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合成路线
490021-01-7
(E)-(3R,5R,6R,9R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-9-triethylsilanyloxy-dodeca-7,11-dien-1-yn-6-ol
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
490021-04-0
(E)-(R)-5-(4-Methoxy-benzyloxy)-6-methyl-hepta-2,6-dien-1-ol
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
381665-50-5
(E)-(2R,3R)-5-((2R,6R)-6-Isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-3-triethylsilanyloxy-1-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-4-en-2-ol
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
500702-41-0
(6R)-6-[(1E,3R,4R)-3,4-dihydroxy-6-(4-methoxyphenylmethyloxy)-3-methyl-1-hexen-1-yl]-5,6-dihydro-2H-pyran-2-one
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
381665-52-7
(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
381665-43-6
(R)-6-[(E)-(3R,4R,6R)-6-Hydroxy-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
490021-06-2
(2S,3R)-2-Chloromethyl-3-[(R)-2-(4-methoxy-benzyloxy)-3-methyl-but-3-enyl]-oxirane
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
503004-55-5
(2R,2'R,3E)-2-methoxymethoxy-2-methyl-4-(6'-oxo-3',6'-dihydro-2H-pyran-2'-yl)but-3-enal
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
503004-62-4
(3'R,6R,1'E)-6-(3'-methoxymethoxy-3'-methyl-4'-triisopropylsilyloxybut-1'-enyl)-5,6-dihydro-pyran-2-one
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
490021-13-1
Acrylic acid (E)-(1R,4R,5R,7R)-1-allyl-7-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-5-(4-methoxy-benzyloxy)-4-methyl-non-2-en-8-ynyl ester
381665-44-7
(6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one
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上游原料
(R)-6-[(E)-(3R,4R,6R)-6-Hydroxy-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one
(E)-(R)-5-(4-Methoxy-benzyloxy)-6-methyl-hepta-2,6-dien-1-ol
(E)-(3R,5R,6R,9R)-3-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-6-methyl-9-triethylsilanyloxy-dodeca-7,11-dien-1-yn-6-ol
(2S,3R)-2-Chloromethyl-3-[(R)-2-(4-methoxy-benzyloxy)-3-methyl-but-3-enyl]-oxirane
(R)-6-[(E)-(3R,4R,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-(4-methoxy-benzyloxy)-3-methyl-3-triethylsilanyloxy-8-trimethylsilanyl-oct-1-en-7-ynyl]-5,6-dihydro-pyran-2-one
(3'R,6R,1'E)-6-(3'-methoxymethoxy-3'-methyl-4'-triisopropylsilyloxybut-1'-enyl)-5,6-dihydro-pyran-2-one
(E)-(2R,3R)-5-((2R,6R)-6-Isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-3-triethylsilanyloxy-1-(2-trimethylsilanylethynyl-[1,3]dithian-2-yl)-pent-4-en-2-ol
(6R)-6-[(1E,3R,4R)-3,4-dihydroxy-6-(4-methoxyphenylmethyloxy)-3-methyl-1-hexen-1-yl]-5,6-dihydro-2H-pyran-2-one
(2R,2'R,3E)-2-methoxymethoxy-2-methyl-4-(6'-oxo-3',6'-dihydro-2H-pyran-2'-yl)but-3-enal
(E)-(4R,7R,8R,10R)-10-(tert-Butyl-dimethyl-silanyloxy)-8-(4-methoxy-benzyloxy)-7-methyl-dodeca-1,5-dien-11-yne-4,7-diol
Acrylic acid (E)-(1R,4R,5R,7R)-1-allyl-7-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-5-(4-methoxy-benzyloxy)-4-methyl-non-2-en-8-ynyl ester
下游产品
福司曲星
diallyl (1R,3R,4Z,6Z,8E)-3-{[tert-butyl(dimethyl)silyl]oxy}-10-{[tert-butyl(diphenyl)silyl]oxy}-1-{(1R)-1-methyl-3-[(2R)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-[(triethylsilyl)oxy]allyl}deca-4,6,8-trien-1-yl phosphate