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福司曲星

福司曲星

CAS号：87810-56-8

英文名：2H-Pyran-2-one, 5,6-dihydro-6-[3,6,13-trihydroxy-3-methyl- 4-(phosphonooxy)-1,7,9,11-tridecatetraenyl]-, monosodiumsalt

分子式

C19H27NaO9P+

熔点

77ºC

密度

1.413g/cm3

分子量

453.376

沸点

737.9ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

福司曲星

英文名称

2H-Pyran-2-one, 5,6-dihydro-6-[3,6,13-trihydroxy-3-methyl- 4-(phosphonooxy)-1,7,9,11-tridecatetraenyl]-, monosodiumsalt

中文别名

英文别名

CL-1565A、Antibiotic CI-920、Antibiotic CL-1565A

CAS号

87810-56-8

分子式

C19H27NaO9P+

分子量

453.376

精确质量

453.129

PSA

163.56

LOGP

1.0551

编号系统

UNII

ZO1648L551

物化性质

密度

1.413g/cm3

沸点

737.9ºC at 760 mmHg

熔点

77ºC

闪点

400.1ºC

折射率

1.623

合成路线

(6R,8R,9Z,11Z,13E)-8-((tert-butyldimethylsilyl)oxy)-3,3-diethyl-5,18,18-trimethyl-5-((E)-2-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)vinyl)-17,17-diphenyl-4,16-dioxa-3,17-disilanonadeca-9,11,13-trien-6-yl dihydrogen phosphate

(6R,8R,9Z,11Z,13E)-8-((tert-butyldimethylsilyl)oxy)-3,3-diethyl-5,18,18-trimethyl-5-((E)-2-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)vinyl)-17,17-diphenyl-4,16-dioxa-3,17-disilanonadeca-9,11,13-trien-6-yl dihydrogen phosphate

福司曲星

上游原料

共找到49个上游原料 >

(2E,4Z,6Z,8R,10R)-(tert-butyldiphenylsilyl)oxy-8-(tert-butyldimethylsilyl)oxy-10-formyl-10-(triethylsilyl)oxy-2,4,6-undecatriene

(2E,4Z,6Z,8R,10R)-(tert-butyldiphenylsilyl)oxy-8-(tert-butyldimethylsilyl)oxy-10-formyl-10-(triethylsilyl)oxy-2,4,6-undecatriene

(2E,4Z,6Z,8R,10R)-11-acetoxy-1-(tert-butyldiphenylsilyl)oxy-8-(tert-butyldimethylsilyl)oxy-10-(triethylsilyl)oxy-2,4,6-undecatriene

(2E,4Z,6Z,8R,10R)-11-acetoxy-1-(tert-butyldiphenylsilyl)oxy-8-(tert-butyldimethylsilyl)oxy-10-(triethylsilyl)oxy-2,4,6-undecatriene

(6R)-6-[(1E,3R,4R)-6-[(4-methoxybenzyl)oxy]-3-methyl-3,4-bis[(triethylsilyl)oxy]hex-1-en-1-yl]-5,6-dihydro-2H-pyran-2-one

(6R)-6-[(1E,3R,4R)-6-[(4-methoxybenzyl)oxy]-3-methyl-3,4-bis[(triethylsilyl)oxy]hex-1-en-1-yl]-5,6-dihydro-2H-pyran-2-one

diethyl ((3R,5R,6Z,8Z,10E)-5-((tert-butyldimethylsilyl)oxy)-12-((tert-butyldiphenylsilyl)oxy)-2-oxo-3-((triethylsilyl)oxy)dodeca-6,8,10-trien-1-yl)phosphonate

diethyl ((3R,5R,6Z,8Z,10E)-5-((tert-butyldimethylsilyl)oxy)-12-((tert-butyldiphenylsilyl)oxy)-2-oxo-3-((triethylsilyl)oxy)dodeca-6,8,10-trien-1-yl)phosphonate

(3Z,5R,7R)-8-acetoxy-5-(tert-butyldimethylsilyl)oxy-1,1-dibromo-7-(triethylsilyl)oxy-1,3-octadiene

(3Z,5R,7R)-8-acetoxy-5-(tert-butyldimethylsilyl)oxy-1,1-dibromo-7-(triethylsilyl)oxy-1,3-octadiene

(2E,5R)-5,6-isopropylidenedioxy-2-methyl-2-hexen-1-ol

(2E,5R)-5,6-isopropylidenedioxy-2-methyl-2-hexen-1-ol

上游原料

(2E,4Z,6Z,8R,10R)-(tert-butyldiphenylsilyl)oxy-8-(tert-butyldimethylsilyl)oxy-10-formyl-10-(triethylsilyl)oxy-2,4,6-undecatriene (2E,4Z,6Z,8R,10R)-11-acetoxy-1-(tert-butyldiphenylsilyl)oxy-8-(tert-butyldimethylsilyl)oxy-10-(triethylsilyl)oxy-2,4,6-undecatriene (6R)-6-[(1E,3R,4R)-6-[(4-methoxybenzyl)oxy]-3-methyl-3,4-bis[(triethylsilyl)oxy]hex-1-en-1-yl]-5,6-dihydro-2H-pyran-2-one diethyl ((3R,5R,6Z,8Z,10E)-5-((tert-butyldimethylsilyl)oxy)-12-((tert-butyldiphenylsilyl)oxy)-2-oxo-3-((triethylsilyl)oxy)dodeca-6,8,10-trien-1-yl)phosphonate (3Z,5R,7R)-8-acetoxy-5-(tert-butyldimethylsilyl)oxy-1,1-dibromo-7-(triethylsilyl)oxy-1,3-octadiene (2E,5R)-5,6-isopropylidenedioxy-2-methyl-2-hexen-1-ol (3R,4R,5E)-4-methyl-6-[(2R)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-3,4-bis[(triethylsilyl)oxy]hex-5-enal (R)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-5,6-dihydro-2H-pyran-2-one (6R)-6-{(1E,3R)-3-methyl-6-oxo-3,4-bis[(triethylsilyl)oxy]oct-1-en-7-yn-1-yl}-5,6-dihydro-2H-pyran-2-one (5R,6R,8R,9Z,11Z,13E)-8-((tert-butyldimethylsilyl)oxy)-2,2,3,3,5,18,18-heptamethyl-5-((E)-2-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)vinyl)-17,17-diphenyl-4,16-dioxa-3,17-disilanonadeca-9,11,13-trien-6-yl bis(4-methoxybenzyl) phosphate (5R)-5-(((4-methoxybenzyl)oxy)methyl)tetrahydrofuran-2-ol (5R)-5-[(4-methoxyphenyl)methoxymethyl]oxolan-2-one (6R)-6-[(1E,3R,4R,6R,7Z)-6-{[tert-butyl(dimethyl)silyl]oxy}-4-hydroxy-8-iodo-3-methyl-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl]-5,6-dihydro-2H-pyran-2-one methyl (2Z,4R,6R)-4-(tert-butyldimethylsilyl)oxy-6-hydroxy-7-(4-methoxybenzyl)oxy-2-heptenoate (3R,5R)-2,3-dihydroxy-5-[((4-methoxybenzyl)oxy)methyl]tetrahydrofuran (R)-γ-羟甲基-γ-丁内酯 (R)-4,5-二氢-5-羟甲基-2(3H)-呋喃酮 (R)-5-羟甲基-2-氧代四氢呋喃 (2E,4Z,6Z,8R,10R)-1,8-bis(tert-butyldimethylsilyl)oxy-11-hydroxy-6-(triethylsilyl)oxy-2,4,6-undecatriene diallyl (1R,3R,4Z,6Z,8E)-3-{[tert-butyl(dimethyl)silyl]oxy}-10-{[tert-butyl(diphenyl)silyl]oxy}-1-{(1R)-1-methyl-3-[(2R)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-[(triethylsilyl)oxy]allyl}deca-4,6,8-trien-1-yl phosphate (3Z,5R,7R)-5-(tert-butyldimethylsilyl)oxy-1,1-dibromo-8-(4-methoxybenzyl)oxy-7-(triethylsilyl)oxy-1,3-octadiene (1E,4R,6R,7Z,9Z,11E)-6,13-bis((tert-butyldimethylsilyl)oxy)-1-((2R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-4-((triethylsilyl)oxy)trideca-1,7,9,11-tetraen-3-one (2Z,4R,6R)-4-(tert-butyldimethylsilyl)oxy-7-(4-methoxybenzyl)oxy-6-(triethylsilyl)oxy-2-hepten-1-ol (R)-6-hydroxymethyl-2-isopropyloxy-5,6-dihydro-2H-pyran diethyl ((3R,5R,6Z,8Z,10E)-5-((tert-butyldimethylsilyl)oxy)-12-((tert-butyldiphenylsilyl)oxy)-2-hydroxy-3-((triethylsilyl)oxy)dodeca-6,8,10-trien-1-yl)phosphonate (2E,4Z,6Z,8R,10R)-1-(tert-butyldiphenylsilyl)oxy-8-(tert-butyldimethylsilyl)oxy-11-hydroxy-10-(triethylsilyl)oxy-2,4,6-undecatriene (1Z,3Z,5R,7R)-8-acetoxy-1-bromo-5-(tert-butyldimethylsilyl)oxy-7-(triethylsilyl)oxy-1,3-octadiene (2E,5R)-1-benzoyloxy-5,6-isopropylidenedioxy-2-methyl-2-hexene (6R,8R,9Z,11Z,13E)-8-((tert-butyldimethylsilyl)oxy)-3,3-diethyl-5,18,18-trimethyl-5-((E)-2-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)vinyl)-17,17-diphenyl-4,16-dioxa-3,17-disilanonadeca-9,11,13-trien-6-yl dihydrogen phosphate (6R)-6-[(1E,3R,4R)-3,4-dihydroxy-6-(4-methoxyphenylmethyloxy)-3-methyl-1-hexen-1-yl]-5,6-dihydro-2H-pyran-2-one tert-butyl(((2R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-methoxy)diphenylsilane (6R,1'E,3'R,4'R,6'R,7'Z,9'Z,11'E)-6-(13'-tert-butyldiphenylsiloxy-3',4',6'-trihydroxy-3'-methyl-1',7',9',11'-tridecatetraenyl)-5,6-dihydro-2H-pyran-2-one (3Z,5R,7R)-5-(tert-butyldimethylsilyl)oxy-1,1-dibromo-8-hydroxy-7-(triethylsilyl)oxy-1,3-octadiene (6R)-6-[(1E,3R,4R)-6-hydroxy-3-methyl-3,4-bis[(triethylsilyl)oxy]hex-1-en-1-yl]-5,6-dihydro-2H-pyran-2-one methyl (R,E)-4-(2,2-dimethyl-1,3-dioxolan-4-yl)-2-methylbut-2-enoate (2R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-carbaldehyde (R)-6-((1E,3R,4R,6R,7Z,9Z,11E)-3,6-bis((tert-butyldimethylsilyl)oxy)-13-((tert-butyldiphenylsilyl)oxy)-4-hydroxy-3-methyltrideca-1,7,9,11-tetraen-1-yl)-5,6-dihydro-2H-pyran-2-one (6R)-6-{(1E,3R,4R,7Z)-4-hydroxy-8-iodo-3-methyl-6-oxo-3-[(triethylsilyl)oxy]octa-1,7-dien-1-yl}-5,6-dihydro-2H-pyran-2-one (6R,1'E,3'R,4'R,6'R,7'Z,9'Z,11'E)-6-(6'-tert-butyldimethylsiloxy-13'-tert-butyldiphenylsiloxy-3',4'-dihydroxy-3'-methyl-1',7',9',11'-tridecatetraenyl)-5,6-dihydro-2H-pyran-2-one (5R,6R,8R,9Z,11Z,13E)-8-((tert-butyldimethylsilyl)oxy)-3,3-diethyl-5,18,18-trimethyl-5-((E)-2-((R)-6-oxo-3,6-dihydro-2H-pyran-2-yl)vinyl)-17,17-diphenyl-4,16-dioxa-3,17-disilanonadeca-9,11,13-trien-6-yl bis(4-methoxybenzyl) phosphate methyl (2Z,4R,6R)-4-(tert-butyldimethylsilyl)oxy-7-(4-methoxybenzyl)oxy-6-(triethylsilyl)oxy-2-heptenoate (3R,5R)-3-(tert-butyldimethylsilyl)oxy-2-hydroxy-5-[((4-methoxybenzyl)oxy)methyl]tetrahydrofuran (2E,4Z,6Z,8R,10R)-11-acetoxy-1,8-bis(tert-butyldimethylsilyl)oxy-6-(triethylsilyl)oxy-2,4,6-undecatriene (2R,4R,5Z,7Z,9E)-4,11-bis((tert-butyldimethylsilyl)oxy)-2-((triethylsilyl)oxy)undeca-5,7,9-trienal diethyl ((3R,5R,6Z,8Z,10E)-5,12-bis((tert-butyldimethylsilyl)oxy)-2-oxo-3-((triethylsilyl)oxy)dodeca-6,8,10-trien-1-yl)phosphonate (3RS,6R)-6-{[(tert-butyldiphenylsilyl)oxy]methyl}-3-(phenylselenyl)-3,4,5,6-tetrahydro-2H-pyran-2-one (6R)-6-{(1E,3R,4R,6R,7Z,9Z,11E)-6-{[tert-butyl(dimethyl)silyl]oxy}-13-{[tert-butyl(diphenyl)silyl]oxy}-4-hydroxy-3-methyl-3-[(triethylsilyl)oxy]trideca-1,7,9,11-tetraen-1-yl}-5,6-dihydro-2H-pyran-2-one (2Z,4R,6R)-4-(tert-butyldimethylsilyl)oxy-7-(4-methoxybenzyl)oxy-6-(triethylsilyl)oxy-2-heptenal (R)-5-[(4-methoxybenzyl)oxy]methyl-4,5-dihydrofurane