(3aR,4R,6E,9S,10Z,11aR)-9-乙酰氧基-6,10-二甲基-3-亚甲基-2-氧代-2,3,3A,4,5,8,9,11A-八氢环癸并[b]呋喃-4-基(2E)-4-羟基-2-(羟基甲基)-2-丁烯酸酯

(3aR,4R,6E,9S,10Z,11aR)-9-乙酰氧基-6,10-二甲基-3-亚甲基-2-氧代-2,3,3A,4,5,8,9,11A-八氢环癸并[b]呋喃-4-基(2E)-4-羟基-2-(羟基甲基)-2-丁烯酸酯

CAS号：38458-58-1

英文名：2-Butenoic acid, 4-hydroxy-2-(hydroxymethyl)-, 9-(acetyloxy)-2,3,3a,4,5,8,9,11a-octahydro-6,10-dimethyl-3-methylene-2-oxocyclodeca[b]furan-4-yl ester, [3aR-[3aR*,4R*(Z),6E,9S*,10Z,11aR*]]-

分子式

C22H28O8

熔点

密度

1.26g/cm3

分子量

420.453

沸点

618.9ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

(3aR,4R,6E,9S,10Z,11aR)-9-乙酰氧基-6,10-二甲基-3-亚甲基-2-氧代-2,3,3A,4,5,8,9,11A-八氢环癸并[b]呋喃-4-基(2E)-4-羟基-2-(羟基甲基)-2-丁烯酸酯

英文名称

2-Butenoic acid, 4-hydroxy-2-(hydroxymethyl)-, 9-(acetyloxy)-2,3,3a,4,5,8,9,11a-octahydro-6,10-dimethyl-3-methylene-2-oxocyclodeca[b]furan-4-yl ester, [3aR-[3aR*,4R*(Z),6E,9S*,10Z,11aR*]]-

中文别名

英文别名

germacranolide eucannabinolide、Hiyodorilactone A、Eucannabinolide、Eucannabinolid、Schkuhrin I、(E)-4-Hydroxy-2-hydroxymethyl-2-butenoic acid (3aR,4R,6E,9S,10Z,11aR)-9-acetoxy-2,3,3a,4,5,8,9,11a-octahydro-6,10-dimethyl-3-methylene-2-oxocyclodeca[b]furan-4-yl ester、Hyodorilactone A

CAS号

38458-58-1

分子式

C22H28O8

分子量

420.453

精确质量

420.178

PSA

119.36

LOGP

1.5251

物化性质

密度

1.26g/cm3

沸点

618.9ºC at 760 mmHg

闪点

211.5ºC

折射率

1.555

合成路线

(3aS,5Z,7S,9E,11aS)-7-((benzyloxy)methoxy)-6,10-dimethyl-3,3a,7,8,11,11a-hexahydrocyclodeca[b]furan-2,4-dione

(3aS,5Z,7S,9E,11aS)-7-((benzyloxy)methoxy)-6,10-dimethyl-3,3a,7,8,11,11a-hexahydrocyclodeca[b]furan-2,4-dione

(3aR,4R,6E,9S,10Z,11aR)-9-乙酰氧基-6,10-二甲基-3-亚甲基-2-氧代-2,3,3A,4,5,8,9,11A-八氢环癸并[b]呋喃-4-基(2E)-4-羟基-2-(羟基甲基)-2-丁烯酸酯

(3aR,4R,6E,9S,10Z,11aR)-9-乙酰氧基-6,10-二甲基-3-亚甲基-2-氧代-2,3,3A,4,5,8,9,11A-八氢环癸并[b]呋喃-4-基(2E)-4-羟基-2-(羟基甲基)-2-丁烯酸酯

上游原料

共找到15个上游原料 >

(3aR,4R,6E,9S,10Z,11aS)-4,9-dihydroxy-6,10-dimethyl-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one

(3aR,4R,6E,9S,10Z,11aS)-4,9-dihydroxy-6,10-dimethyl-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one

(3aS,4S,6E,9S,10Z,11aS)-9-((benzyloxy)methoxy)-4-hydroxy-6,10-dimethyl-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one

(3aS,4S,6E,9S,10Z,11aS)-9-((benzyloxy)methoxy)-4-hydroxy-6,10-dimethyl-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one

(3aS,4R,6E,9S,10Z,11aS)-6,10-dimethyl-3-methylene-4,9-bis((trimethylsilyl)oxy)-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one

(3aS,4R,6E,9S,10Z,11aS)-6,10-dimethyl-3-methylene-4,9-bis((trimethylsilyl)oxy)-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one

惕各酸甲酯

惕各酸甲酯

dihydroxytiglic acid acetonide

dihydroxytiglic acid acetonide

(1S,3Z,5S,7E,10S)-5-((benzyloxy)methoxy)-11,11-dimethoxy-4,8-dimethylbicyclo[8.2.0]dodeca-3,7-dien-2-one

(1S,3Z,5S,7E,10S)-5-((benzyloxy)methoxy)-11,11-dimethoxy-4,8-dimethylbicyclo[8.2.0]dodeca-3,7-dien-2-one

上游原料

(3aR,4R,6E,9S,10Z,11aS)-4,9-dihydroxy-6,10-dimethyl-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one (3aS,4S,6E,9S,10Z,11aS)-9-((benzyloxy)methoxy)-4-hydroxy-6,10-dimethyl-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one (3aS,4R,6E,9S,10Z,11aS)-6,10-dimethyl-3-methylene-4,9-bis((trimethylsilyl)oxy)-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one 惕各酸甲酯 dihydroxytiglic acid acetonide (1S,3Z,5S,7E,10S)-5-((benzyloxy)methoxy)-11,11-dimethoxy-4,8-dimethylbicyclo[8.2.0]dodeca-3,7-dien-2-one (1R,4S,6S)-4-((benzyloxy)methoxy)-1-(3,3-dimethoxycyclobut-1-en-1-yl)-3-methyl-6-(prop-1-en-2-yl)cyclohex-2-en-1-ol Desacetyleupaformonin Methyl-2(Z)-4-brom-2-brommethyl-2-butenoat (3aR,4R,6E,9S,10Z,11aS)-9-((benzyloxy)methoxy)-4-hydroxy-6,10-dimethyl-3a,4,5,8,9,11a-hexahydrocyclodeca[b]furan-2(3H)-one 3β-acetoxy-8β-hydroxycostunolide (3aS,5Z,7S,9E,11aS)-7-((benzyloxy)methoxy)-6,10-dimethyl-3,3a,7,8,11,11a-hexahydrocyclodeca[b]furan-2,4-dione (3aR,4S,5Z,7S,9E,11aS)-7-((benzyloxy)methoxy)-4-hydroxy-6,10-dimethyl-3a,4,7,8,11,11a-hexahydrocyclodeca[b]furan-2(3H)-one (3aR,6E,9S,10Z,11aS)-9-((benzyloxy)methoxy)-6,10-dimethyl-3,3a,5,8,9,11a-hexahydrocyclodeca[b]furan-2,4-dione (3aS,6E,9S,10Z,11aS)-9-((benzyloxy)methoxy)-6,10-dimethyl-3,3a,5,8,9,11a-hexahydrocyclodeca[b]furan-2,4-dione