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2-methoxy-6-(prop-2-enyl)benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-methoxymethoxy-4-methylhept-6-enyl ester

2-methoxy-6-(prop-2-enyl)benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-methoxymethoxy-4-methylhept-6-enyl ester

CAS号：398478-57-4

英文名：2-methoxy-6-(prop-2-enyl)benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-methoxymethoxy-4-methylhept-6-enyl ester

分子式

C31H42O7

熔点

密度

分子量

526.661

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

2-methoxy-6-(prop-2-enyl)benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-methoxymethoxy-4-methylhept-6-enyl ester

英文名称

2-methoxy-6-(prop-2-enyl)benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-methoxymethoxy-4-methylhept-6-enyl ester

中文别名

英文别名

2-Allyl-6-methoxy-benzoic acid (1S,3R,4S)-1-[2-(4-methoxy-benzyloxy)-ethyl]-3-methoxymethoxy-4-methyl-hept-6-enyl ester、(3S,5R,6S)-1-((4-methoxybenzyl)oxy)-5-(methoxymethoxy)-6-methylnon-8-en-3-yl 2-allyl-6-methoxybenzoate、(1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-(methoxymethoxy)-4-methylhept-6-enyl 2-allyl-6-methoxybenzoate

CAS号

398478-57-4

分子式

C31H42O7

分子量

526.661

精确质量

526.293

PSA

72.45

LOGP

6.156

合成路线

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(3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol

(3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol

2-methoxy-6-(prop-2-enyl)benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-methoxymethoxy-4-methylhept-6-enyl ester

2-methoxy-6-(prop-2-enyl)benzoic acid (1S,3R,4S)-1-[2-(4-methoxybenzyloxy)ethyl]-3-methoxymethoxy-4-methylhept-6-enyl ester

上游原料

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(5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-yn-1-ol

(5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-yn-1-ol

{(2S,3S)-3-[(2R,3S)-5-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methylpentyl]oxiran-2-yl}methanol

{(2S,3S)-3-[(2R,3S)-5-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methylpentyl]oxiran-2-yl}methanol

(3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol

(3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol

(2R,3R,5R)-5-(tert-butyldimethylsilyloxy)-7-(4-methoxybenzyloxy)-3-methoxymethoxy-2-(prop-2-enyl)heptan-1-ol

(2R,3R,5R)-5-(tert-butyldimethylsilyloxy)-7-(4-methoxybenzyloxy)-3-methoxymethoxy-2-(prop-2-enyl)heptan-1-ol

(3R,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloctane-1,3-diol

(3R,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloctane-1,3-diol

(3S,4R)-1-(tert-butyldiphenylsiloxy)-4-(methoxymethoxy)-5-[(4R)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]-3-methylpentane

(3S,4R)-1-(tert-butyldiphenylsiloxy)-4-(methoxymethoxy)-5-[(4R)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]-3-methylpentane

下游产品

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(12E)-(7S,9R,10S)-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-9-hydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-9-hydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-3-(carboxy)prop-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-7-[(2E)-3-(carboxy)prop-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxabenzocyclodecen-5-one

(12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxabenzocyclodecen-5-one

(12E)-(7S,9R,10S)-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-4-hydroxy-10-methyl-7,8,9,10,11,12,13,14-hexahydro-6-oxa-benzocyclodecen-5-one

(12E)-(7S,9R,10S)-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-4-hydroxy-10-methyl-7,8,9,10,11,12,13,14-hexahydro-6-oxa-benzocyclodecen-5-one

上游原料

(5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-yn-1-ol {(2S,3S)-3-[(2R,3S)-5-(tert-butyldiphenylsiloxy)-2-(methoxymethoxy)-3-methylpentyl]oxiran-2-yl}methanol (3S)-1-[(4-methoxyphenyl)methoxy]hex-5-en-3-ol (2R,3R,5R)-5-(tert-butyldimethylsilyloxy)-7-(4-methoxybenzyloxy)-3-methoxymethoxy-2-(prop-2-enyl)heptan-1-ol (3R,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloctane-1,3-diol (3S,4R)-1-(tert-butyldiphenylsiloxy)-4-(methoxymethoxy)-5-[(4R)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]-3-methylpentane (E,5R,6S)-8-(tert-butyldiphenylsiloxy)-5-(methoxymethoxy)-6-methyloct-2-ene-1-ol methyl (3S,4R)-4-hydroxy-3-methyl-8-(tetrahydro-2H-pyran-2-yloxy)oct-6-ynoate (3S,4R)-1-(tert-butyldiphenylsiloxy)-3-methyl-8-(tetrahydro-2H-pyran-2-yloxy)oct-6-yn-4-ol (4S,5S)-5-Iodomethyl-4-methyl-dihydro-furan-2-one methyl (3S)-3-[(2S)-oxiran-2-yl]butanoate (4S,5R,7R)-6-(tert-butyldimethylsilyloxy)-9-(4-methoxybenzyloxy)-5-methoxymethoxy-4-methylnon-1-ene (3S,4R)-4-(methoxymethoxy)-5-[(4R)-2-(4-methoxyphenyl)-1,3-dioxan-4-yl]-3-methylpentan-1-ol

下游产品

(12E)-(7S,9R,10S)-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-9-hydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-3-(carboxy)prop-2-enyl]-4-methoxy-9-methoxymethoxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxabenzocyclodecen-5-one (12E)-(7S,9R,10S)-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-4-hydroxy-10-methyl-7,8,9,10,11,12,13,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[(2E)-4-azido-4-oxo-but-2-enyl]-9-benzoyloxy-4-(tert-butyldimethylsilyloxy)-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-9-benzoyloxy-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-carboxyprop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (7S,9R,10S,12E)-(4-methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro[5H]-6-oxa-benzocyclododecen-7-yl)-acetaldehyde (12E)-(7S,9R,10S)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-4,9-dihydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-7-[3-(carbomethoxy)prop-2-enyl]-4,9-dihydroxy-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-4-benzoyloxy-9-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-9-benzoyloxy-4-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one (12E)-(7S,9R,10S)-4,9-bis-(tert-butyldimethylsilyloxy)-7-[(2E)-3-(carboallyloxy)prop-2-enyl]-10-methyl-7,8,9,10,11,14-hexahydro-6-oxa-benzocyclodecen-5-one Octanoic acid 2-((E)-(7S,9R,10S)-4-methoxy-9-methoxymethoxy-10-methyl-5-oxo-7,8,9,10,11,14-hexahydro-5H-6-oxa-benzocyclododecen-7-yl)-ethyl ester