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(2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

(2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

CAS号：410523-55-6

英文名：(2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

分子式

C38H68O4Si

熔点

密度

分子量

617.03

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

英文名称

(2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

中文别名

英文别名

(8E,10E,14Z,16E)-(3S,4R,5R,6S,7R,13R)-4-(tert-Butyl-dimethyl-silanyloxy)-15-ethyl-17-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3,5,7,9,13-pentamethyl-heptadeca-8,10,14,16-tetraen-6-ol

CAS号

410523-55-6

分子式

C38H68O4Si

分子量

617.03

精确质量

616.489

PSA

47.92

LOGP

10.5735

合成路线

(2R,4S,5R,6S)-(-)-1-benzyloxy-5-hydroxy-2,4,6-trimethyloctan-3-one

(2R,4S,5R,6S)-(-)-1-benzyloxy-5-hydroxy-2,4,6-trimethyloctan-3-one

(2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

(2'R,6'R,8E,10E,14Z,16E,3S,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

上游原料

共找到7个上游原料 >

(2'S,2R)-(-)-1'-(4-tert-butyldiphenylsilyloxy-2-methyl-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine

(2'S,2R)-(-)-1'-(4-tert-butyldiphenylsilyloxy-2-methyl-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine

(R)-6-chloromethyl-5,6-dihydropyran-2-one

(R)-6-chloromethyl-5,6-dihydropyran-2-one

(2R,4S,5R,6S)-1-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-octan-3-one

(2R,4S,5R,6S)-1-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-octan-3-one

(2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one

(2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one

(2R,3S,4R,5R,6S)-5-tert-butyldimethylsilyloxy-2,4,6-trimethyloctan-1,3-diol

(2R,3S,4R,5R,6S)-5-tert-butyldimethylsilyloxy-2,4,6-trimethyloctan-1,3-diol

(2R,4S,5R,6S)-(-)-1-benzyloxy-5-hydroxy-2,4,6-trimethyloctan-3-one

(2R,4S,5R,6S)-(-)-1-benzyloxy-5-hydroxy-2,4,6-trimethyloctan-3-one

上游原料

(2'S,2R)-(-)-1'-(4-tert-butyldiphenylsilyloxy-2-methyl-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine (R)-6-chloromethyl-5,6-dihydropyran-2-one (2R,4S,5R,6S)-1-Benzyloxy-5-(tert-butyl-dimethyl-silanyloxy)-2,4,6-trimethyl-octan-3-one (2R,4S,5R,6S)-(-)-5-tert-butyldimethylsilyloxy-1-hydroxy-2,4,6-trimethyloctan-3-one (2R,3S,4R,5R,6S)-5-tert-butyldimethylsilyloxy-2,4,6-trimethyloctan-1,3-diol (2R,4S,5R,6S)-(-)-1-benzyloxy-5-hydroxy-2,4,6-trimethyloctan-3-one ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate