百科

(S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran

(S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran

CAS号：438222-41-4

英文名：(S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran

分子式：C32H64O4Si3

分子量：597.105

合成路线

tert-Butyl-((Z)-4-{(4S,5S)-2,2-dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolan-4-yl}-but-3-enyloxy)-dimethyl-silane

tert-Butyl-((Z)-4-{(4S,5S)-2,2-dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolan-4-yl}-but-3-enyloxy)-dimethyl-silane

(S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran

(S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran

(4R,5S)-2,2-Dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolane-4-carbaldehyde

(4R,5S)-2,2-Dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolane-4-carbaldehyde

(S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran

(S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran

上游原料

(4R,5S)-2,2-Dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolane-4-carbaldehyde tert-Butyl-((Z)-4-{(4S,5S)-2,2-dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolan-4-yl}-but-3-enyloxy)-dimethyl-silane

下游产品

(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one 16,17-deoxy-laulimalide