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(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

CAS号：438222-74-3

英文名：(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

分子式

C32H46O7

熔点

密度

分子量

542.703

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

英文名称

(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

中文别名

英文别名

CAS号

438222-74-3

分子式

C32H46O7

分子量

542.703

精确质量

542.324

PSA

83.45

LOGP

5.5221

合成路线

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(R)-3-Methyl-4-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-butyric acid methyl ester

(R)-3-Methyl-4-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-butyric acid methyl ester

(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Hydroxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-11-methoxymethoxy-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

上游原料

共找到14个上游原料 >

(4R,5S)-2,2-Dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolane-4-carbaldehyde

(4R,5S)-2,2-Dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolane-4-carbaldehyde

Trimethyl-[(S)-4-methyl-2-methylene-5-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-pentyl]-silane

Trimethyl-[(S)-4-methyl-2-methylene-5-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-pentyl]-silane

{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-acetaldehyde

{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-acetaldehyde

4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Dihydroxy-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-ynoic acid methyl ester

4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Dihydroxy-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-ynoic acid methyl ester

2-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-ethanol

2-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-ethanol

(R)-3-Methyl-4-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-butyric acid methyl ester

(R)-3-Methyl-4-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-butyric acid methyl ester

下游产品

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11-hydroxy-7-[1-methoxy-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

11-hydroxy-7-[1-methoxy-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

上游原料

(4R,5S)-2,2-Dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolane-4-carbaldehyde Trimethyl-[(S)-4-methyl-2-methylene-5-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-pentyl]-silane {(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-acetaldehyde 4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Dihydroxy-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-ynoic acid methyl ester 2-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-ethanol (R)-3-Methyl-4-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-butyric acid methyl ester tert-Butyl-((Z)-4-{(4S,5S)-2,2-dimethyl-5-[(E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-[1,3]dioxolan-4-yl}-but-3-enyloxy)-dimethyl-silane (3Z,7E)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-8-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-3,7-dien-1-ol 4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Dihydroxy-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-ynoic acid (7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-1-((2R,6R)-6-vinyl-3,6-dihydro-2H-pyran-2-yl)-trideca-7,12-dien-6-ol (S)-4-Methyl-2-[(1E,5Z)-(3S,4S)-3,4,8-tris-(tert-butyl-dimethyl-silanyloxy)-octa-1,5-dienyl]-3,6-dihydro-2H-pyran (2E,7E)-(5S,6S)-5,6-Bis-(tert-butyl-dimethyl-silanyloxy)-8-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-octa-2,7-dienal 4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-10,11-Bis-(tert-butyl-dimethyl-silanyloxy)-6-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-ynoic acid methyl ester (5S,9S,10S,E)-9-((tert-butyldimethylsilyl)oxy)-12,12,13,13-tetramethyl-5-((S)-4-methyl-2-methylene-5-((2R,6R)-6-(prop-2-yn-1-yl)-3,6-dihydro-2H-pyran-2-yl)pentyl)-10-((E)-2-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)vinyl)-2,4,11-trioxa-12-silatetradec-6-ene

下游产品

11-hydroxy-7-[1-methoxy-3-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one