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(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

CAS号：439143-49-4

英文名：(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

分子式

C33H57NO11Si

熔点

密度

分子量

671.891

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

英文名称

(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

中文别名

英文别名

3-(tert-butyl-dimethyl-silanyl)-6-(1-hydroxy-5-hydroxymethyl-9-methoxy-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-13-yloxy)-7-methoxy-4,7a-dimethyl-tetrahydro-pyrano[3,4-d]oxazol-2-one

CAS号

439143-49-4

分子式

C33H57NO11Si

分子量

671.891

精确质量

671.37

PSA

142.45

LOGP

4.0629

合成路线

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

(1S,5R,9R,10R,11S,12R,13S)-13-[(1R,2R,3S,5S,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-8-oxo-7-(tert-butyldimethylsilyl)bicyclo[4.3.0]non-3-yloxy]-1-hydroxy-5-(hydroxymethyl)-9-methoxy-7,10,12-trimethyl-4,15-dioxabicyclo[9.3.1]pentadec-7-en-3-one

上游原料

共找到4个上游原料 >

methyl 2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxyphenyl)methoxy]-1,4-dimethyl-6-(tert-butyldimethylsilyloxy)hept-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsiloxy)-2H-3,4,5,6-tetrahydropyran-2-yl)acetate

methyl 2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxyphenyl)methoxy]-1,4-dimethyl-6-(tert-butyldimethylsilyloxy)hept-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsiloxy)-2H-3,4,5,6-tetrahydropyran-2-yl)acetate

2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxypheny)methoxy]-1,4-dimethyl-6-(methylsulfonyloxy)hep-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(1,1,2,2-tetramethyl-1-silapropoxy)perhydro-2H-pyran-2-yl)acetic acid

2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxypheny)methoxy]-1,4-dimethyl-6-(methylsulfonyloxy)hep-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(1,1,2,2-tetramethyl-1-silapropoxy)perhydro-2H-pyran-2-yl)acetic acid

(3S,5S,1R,2R,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-3-phenylthio-7-(1,1,2,2-tetramethyl-1-silapropyl)bicyclo[4.3.0]nonan-8-one

(3S,5S,1R,2R,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-3-phenylthio-7-(1,1,2,2-tetramethyl-1-silapropyl)bicyclo[4.3.0]nonan-8-one

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

上游原料

methyl 2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxyphenyl)methoxy]-1,4-dimethyl-6-(tert-butyldimethylsilyloxy)hept-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsiloxy)-2H-3,4,5,6-tetrahydropyran-2-yl)acetate 2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxypheny)methoxy]-1,4-dimethyl-6-(methylsulfonyloxy)hep-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(1,1,2,2-tetramethyl-1-silapropoxy)perhydro-2H-pyran-2-yl)acetic acid (3S,5S,1R,2R,6R)-7-aza-2-methoxy-1,5-dimethyl-4,9-dioxa-3-phenylthio-7-(1,1,2,2-tetramethyl-1-silapropyl)bicyclo[4.3.0]nonan-8-one 2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal