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(1S,11S,12S,13S,5R,9R,10R)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(1,1,2,2-tetramethyl-1-silaproxy)bicyclo[9.3.1]pentadec-7-en-3-one

(1S,11S,12S,13S,5R,9R,10R)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(1,1,2,2-tetramethyl-1-silaproxy)bicyclo[9.3.1]pentadec-7-en-3-one

CAS号：439143-60-9

英文名：(1S,11S,12S,13S,5R,9R,10R)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(1,1,2,2-tetramethyl-1-silaproxy)bicyclo[9.3.1]pentadec-7-en-3-one

分子式

C33H54O8Si

熔点

密度

分子量

606.863

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1S,11S,12S,13S,5R,9R,10R)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(1,1,2,2-tetramethyl-1-silaproxy)bicyclo[9.3.1]pentadec-7-en-3-one

英文名称

(1S,11S,12S,13S,5R,9R,10R)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(1,1,2,2-tetramethyl-1-silaproxy)bicyclo[9.3.1]pentadec-7-en-3-one

中文别名

英文别名

(1S,5R,9R,10R,11S,12S,13S)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(tert-butyldimethylsilyloxy)bicyclo[9.3.1]pentadec-7-en-3-one、(E)-(1S,5R,9R,10R,11S,12S,13S)-13-(tert-Butyl-dimethyl-silanyloxy)-1,9-dimethoxy-5-(4-methoxy-benzyloxymethyl)-7,10,12-trimethyl-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-3-one

CAS号

439143-60-9

分子式

C33H54O8Si

分子量

606.863

精确质量

606.359

PSA

81.68

LOGP

6.6729

合成路线

共找到2条合成路线 >

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

(1S,11S,12S,13S,5R,9R,10R)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(1,1,2,2-tetramethyl-1-silaproxy)bicyclo[9.3.1]pentadec-7-en-3-one

(1S,11S,12S,13S,5R,9R,10R)-1,9-dimethoxy-5-[(4-methoxyphenyl)methoxy]-7,10,12-trimethyl-4,15-dioxa-13-(1,1,2,2-tetramethyl-1-silaproxy)bicyclo[9.3.1]pentadec-7-en-3-one

上游原料

共找到2个上游原料 >

methyl 2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxyphenyl)methoxy]-1,4-dimethyl-6-(tert-butyldimethylsilyloxy)hept-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsiloxy)-2H-3,4,5,6-tetrahydropyran-2-yl)acetate

methyl 2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxyphenyl)methoxy]-1,4-dimethyl-6-(tert-butyldimethylsilyloxy)hept-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsiloxy)-2H-3,4,5,6-tetrahydropyran-2-yl)acetate

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

下游产品

共找到2个下游商品 >

3-(tert-butyl-dimethyl-silanyl)-6-[1,9-dimethoxy-5-(4-methoxy-benzyloxymethyl)-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-13-yloxy]-7-methoxy-4,7a-dimethyl-tetrahydro-pyrano[3,4-d]oxazol-2-one

3-(tert-butyl-dimethyl-silanyl)-6-[1,9-dimethoxy-5-(4-methoxy-benzyloxymethyl)-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-13-yloxy]-7-methoxy-4,7a-dimethyl-tetrahydro-pyrano[3,4-d]oxazol-2-one

13-[3-(tert-butyl-dimethyl-silanyl)-7-methoxy-4,7a-dimethyl-2-oxo-hexahydro-pyrano[3,4-d]oxazol-6-yloxy]-1-hydroxy-9-methoxy-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-ene-5-carbaldehyde

13-[3-(tert-butyl-dimethyl-silanyl)-7-methoxy-4,7a-dimethyl-2-oxo-hexahydro-pyrano[3,4-d]oxazol-6-yloxy]-1-hydroxy-9-methoxy-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-ene-5-carbaldehyde

上游原料

methyl 2-(6-{(3E)(6S,1R,2R)-2-methoxy-7-[(4-methoxyphenyl)methoxy]-1,4-dimethyl-6-(tert-butyldimethylsilyloxy)hept-3-enyl}(2S,4S,5S,6S)-2-methoxy-5-methyl-4-(tert-butyldimethylsiloxy)-2H-3,4,5,6-tetrahydropyran-2-yl)acetate 2-(6-{(1E)(4S)-5-[(4-methoxyphenyl)methoxy]-2-methyl-4-(tert-butyldimethylsilyloxy)pent-1-enyl}(4S,5R,6R)-2,2,5-trimethyl(1,3-dioxan-4-yl))(2S)propanal

下游产品

3-(tert-butyl-dimethyl-silanyl)-6-[1,9-dimethoxy-5-(4-methoxy-benzyloxymethyl)-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-en-13-yloxy]-7-methoxy-4,7a-dimethyl-tetrahydro-pyrano[3,4-d]oxazol-2-one 13-[3-(tert-butyl-dimethyl-silanyl)-7-methoxy-4,7a-dimethyl-2-oxo-hexahydro-pyrano[3,4-d]oxazol-6-yloxy]-1-hydroxy-9-methoxy-7,10,12-trimethyl-3-oxo-4,15-dioxa-bicyclo[9.3.1]pentadec-7-ene-5-carbaldehyde