百科

(12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane

CAS号：443303-96-6

英文名：(12R,15S,16S,19R,20S,34R,35R)-34,35-dimethoxy-34,35-dimethyl-19-(12-(9-benzyloxypropyl)-15-(16-tert-butyldimethylsilyloxypropyl)tetrahydrofuran)-20-dodecanyl-[33,36]-dioxane

分子式：C43H78O7Si

分子量：735.161

上游原料

313963-27-8

(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-2-dodecane-[1,4]-dioxane

443303-99-9

(2S,3S,5R,6R)-3-Dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carbaldehyde

313963-28-9

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-2-dodecane-3-(2',2'-gem-dibromo)ethenyl-[1,4]-dioxane

313963-30-3

(2R/S,5S)-5-(tert-butyldiphenylsilyloxymethyl)-2-(prop-2-yne-1-oxy)tetrahydrofuran

243964-15-0

(-)-(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-2-hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane

313963-33-6

(2S,5S)-2-(tert-butyldiphenylsilyloxymethyl)-5-(1-benzyloxyprop-2-ynyl)tetrahydrofuran

313963-47-2

tert-Butyl-[(2R,3S,5R,6R)-3-((E)-dodec-1-enyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxy]-dimethyl-silane

313963-34-7

[(2S,5R)-5-(3-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-methanol

313963-24-5

(2S,5R)-2-(carboxymethyl)-5-(1-benzyloxypropyl)tetrahydrofuran

313963-48-3

(2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane

243964-13-8

[(2R,3S,5R,6R)-3-(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2- yl]methanol

上游原料

(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-5,6-dimethoxy-5,6-dimethyl-2-dodecane-[1,4]-dioxane (2S,3S,5R,6R)-3-Dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carbaldehyde (2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-2-dodecane-3-(2',2'-gem-dibromo)ethenyl-[1,4]-dioxane (2R/S,5S)-5-(tert-butyldiphenylsilyloxymethyl)-2-(prop-2-yne-1-oxy)tetrahydrofuran (-)-(2S,3R,5R,6R)-3-tert-butyldimethylsilyloxymethyl-2-hydroxymethyl-5,6-dimethoxy-5,6-dimethyl-1,4-dioxane (2S,5S)-2-(tert-butyldiphenylsilyloxymethyl)-5-(1-benzyloxyprop-2-ynyl)tetrahydrofuran tert-Butyl-[(2R,3S,5R,6R)-3-((E)-dodec-1-enyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-ylmethoxy]-dimethyl-silane [(2S,5R)-5-(3-Benzyloxy-propyl)-tetrahydro-furan-2-yl]-methanol (2S,5R)-2-(carboxymethyl)-5-(1-benzyloxypropyl)tetrahydrofuran (2S,3R,5R,6R)-5,6-dimethoxy-5,6-dimethyl-3-hydroxymethyl-2-dodecane-[1,4]-dioxane [(2R,3S,5R,6R)-3-(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl-1,4-dioxan-2- yl]methanol

下游产品

(S)-3-((R)-2-(tert-Butyl-dimethyl-silanyloxy)-9-{(2R,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((2R,3S,5R,6R)-3-dodecyl-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxan-2-yl)-propyl]-tetrahydro-furan-2-yl}-nonyl)-5-methyl-5H-furan-2-one (4R,12R,15S,16S,19R,20S,34S)-muricatetrocin C