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(3Z,9E)-(1R,7S,11S,15R,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,13-dione

(3Z,9E)-(1R,7S,11S,15R,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,13-dione

CAS号：478491-13-3

英文名：(3Z,9E)-(1R,7S,11S,15R,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,13-dione

分子式

C41H68O7Si2

熔点

密度

分子量

729.145

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(3Z,9E)-(1R,7S,11S,15R,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,13-dione

英文名称

(3Z,9E)-(1R,7S,11S,15R,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,13-dione

中文别名

英文别名

CAS号

478491-13-3

分子式

C41H68O7Si2

分子量

729.145

精确质量

728.45

PSA

80.29

LOGP

9.9658

合成路线

(E)-(R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

(E)-(R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

(3Z,9E)-(1R,7S,11S,15R,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,13-dione

(3Z,9E)-(1R,7S,11S,15R,17R)-11-(tert-Butyl-dimethyl-silanyloxy)-7-[(E)-(S)-1-(tert-butyl-dimethyl-silanyloxy)-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-triene-5,13-dione

上游原料

共找到4个上游原料 >

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde

(Z)-4-[(2R,6S)-6-((E)-4-Oxo-pent-2-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid methyl ester

(Z)-4-[(2R,6S)-6-((E)-4-Oxo-pent-2-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid methyl ester

(E)-(R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

(E)-(R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester

tert-butyl-{(4E)(1S,2S)-2-(4-methoxy-benzyloxy)-1-[(1E)-2-((2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-6-trityloxy-hex-4-enyloxy}dimethylsilane

tert-butyl-{(4E)(1S,2S)-2-(4-methoxy-benzyloxy)-1-[(1E)-2-((2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-6-trityloxy-hex-4-enyloxy}dimethylsilane

上游原料

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde (Z)-4-[(2R,6S)-6-((E)-4-Oxo-pent-2-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid methyl ester (E)-(R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-hex-2-enoic acid methyl ester tert-butyl-{(4E)(1S,2S)-2-(4-methoxy-benzyloxy)-1-[(1E)-2-((2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-vinyl]-6-trityloxy-hex-4-enyloxy}dimethylsilane