百科

(2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester

(2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester

CAS号：479673-56-8

英文名：(2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester

分子式：C56H76O9

分子量：893.197

合成路线

(2S)-tert-butyl-{(4R,5S)-2-[2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]propoxy}dimethylsilane

(2S)-tert-butyl-{(4R,5S)-2-[2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]propoxy}dimethylsilane

(2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester

(2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester

(2E,8Z,13Z,21Z)-(4R,5R,10S,11S,12S,17R,18S,19S,20S)-19-(tert-Butyl-dimethyl-silanyloxy)-5,11,17-tris-(4-methoxy-benzyloxy)-4,10,12,18,20-pentamethyl-tetracosa-2,8,13,21,23-pentaen-1-ol

(2E,8Z,13Z,21Z)-(4R,5R,10S,11S,12S,17R,18S,19S,20S)-19-(tert-Butyl-dimethyl-silanyloxy)-5,11,17-tris-(4-methoxy-benzyloxy)-4,10,12,18,20-pentamethyl-tetracosa-2,8,13,21,23-pentaen-1-ol

(2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester

(2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester

上游原料

(2E,8Z,13Z,21Z)-(4R,5R,10S,11S,12S,17R,18S,19S,20S)-19-(tert-Butyl-dimethyl-silanyloxy)-5,11,17-tris-(4-methoxy-benzyloxy)-4,10,12,18,20-pentamethyl-tetracosa-2,8,13,21,23-pentaen-1-ol (2S)-tert-butyl-{(4R,5S)-2-[2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]propoxy}dimethylsilane

下游产品

(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one