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(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one

(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one

CAS号：479673-57-9

英文名：(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one

分子式

C55H72O8

熔点

密度

分子量

861.155

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one

英文名称

(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one

中文别名

英文别名

CAS号

479673-57-9

分子式

C55H72O8

分子量

861.155

精确质量

860.523

PSA

81.68

LOGP

12.4017

合成路线

(2S)-2-[(4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]propan-1-ol

(2S)-2-[(4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]propan-1-ol

(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one

(3Z,5E,11Z,16Z)-(7R,8R,13S,14S,15S,20R,21S,22S)-8,14,20-Tris-(4-methoxy-benzyloxy)-7,13,15,21-tetramethyl-22-((Z)-(S)-1-methyl-penta-2,4-dienyl)-oxacyclodocosa-3,5,11,16-tetraen-2-one

上游原料

共找到15个上游原料 >

(Z)-(5S,6S,7S,8R)-11-iodo-8-(4-methoxybenzyloxy)-5,7-dimethylundeca-1,3-dien-6-yl tert-butyldimethylsilyl ether

(Z)-(5S,6S,7S,8R)-11-iodo-8-(4-methoxybenzyloxy)-5,7-dimethylundeca-1,3-dien-6-yl tert-butyldimethylsilyl ether

(2R,3R,4S,5R)-3,8-bis(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2,4-dimethyloctanal

(2R,3R,4S,5R)-3,8-bis(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2,4-dimethyloctanal

(6R, [7R,] [12S,] 13S, [14S,] [19R,] [20R,] [21R,] 22S)-21-(TERT-BUTYLDIMETHYLSILANYLOXY)- 7,13, [19-TRIS- (4-METHOXYBENZYLOXY)-6,] 12,14, 20,22-pentamethylhexacosa-2, 4,10, 15,23, 25- hexaenoic acid methyl ester

(6R, [7R,] [12S,] 13S, [14S,] [19R,] [20R,] [21R,] 22S)-21-(TERT-BUTYLDIMETHYLSILANYLOXY)- 7,13, [19-TRIS- (4-METHOXYBENZYLOXY)-6,] 12,14, 20,22-pentamethylhexacosa-2, 4,10, 15,23, 25- hexaenoic acid methyl ester

(2R,3R,4R,5R)-8-(tert-butyldimethylsilanyloxy)-3-hydroxy-5-(4-methoxybenzyloxy)-2,4-dimethyloctanoic acid, 2,6-dimethylphenyl ester

(2R,3R,4R,5R)-8-(tert-butyldimethylsilanyloxy)-3-hydroxy-5-(4-methoxybenzyloxy)-2,4-dimethyloctanoic acid, 2,6-dimethylphenyl ester

(2E,8Z)-(4R,5R,10S,11S,12R)-5,11-Bis-(4-methoxy-benzyloxy)-4,10,12-trimethyl-13-oxo-trideca-2,8-dienoic acid ethyl ester

(2E,8Z)-(4R,5R,10S,11S,12R)-5,11-Bis-(4-methoxy-benzyloxy)-4,10,12-trimethyl-13-oxo-trideca-2,8-dienoic acid ethyl ester

(2E,8Z,13Z,21Z)-(4R,5R,10S,11S,12S,17R,18S,19S,20S)-19-(tert-Butyl-dimethyl-silanyloxy)-5,11,17-tris-(4-methoxy-benzyloxy)-4,10,12,18,20-pentamethyl-tetracosa-2,8,13,21,23-pentaen-1-ol

(2E,8Z,13Z,21Z)-(4R,5R,10S,11S,12S,17R,18S,19S,20S)-19-(tert-Butyl-dimethyl-silanyloxy)-5,11,17-tris-(4-methoxy-benzyloxy)-4,10,12,18,20-pentamethyl-tetracosa-2,8,13,21,23-pentaen-1-ol

上游原料

(Z)-(5S,6S,7S,8R)-11-iodo-8-(4-methoxybenzyloxy)-5,7-dimethylundeca-1,3-dien-6-yl tert-butyldimethylsilyl ether (2R,3R,4S,5R)-3,8-bis(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2,4-dimethyloctanal (6R, [7R,] [12S,] 13S, [14S,] [19R,] [20R,] [21R,] 22S)-21-(TERT-BUTYLDIMETHYLSILANYLOXY)- 7,13, [19-TRIS- (4-METHOXYBENZYLOXY)-6,] 12,14, 20,22-pentamethylhexacosa-2, 4,10, 15,23, 25- hexaenoic acid methyl ester (2R,3R,4R,5R)-8-(tert-butyldimethylsilanyloxy)-3-hydroxy-5-(4-methoxybenzyloxy)-2,4-dimethyloctanoic acid, 2,6-dimethylphenyl ester (2E,8Z)-(4R,5R,10S,11S,12R)-5,11-Bis-(4-methoxy-benzyloxy)-4,10,12-trimethyl-13-oxo-trideca-2,8-dienoic acid ethyl ester (2E,8Z,13Z,21Z)-(4R,5R,10S,11S,12S,17R,18S,19S,20S)-19-(tert-Butyl-dimethyl-silanyloxy)-5,11,17-tris-(4-methoxy-benzyloxy)-4,10,12,18,20-pentamethyl-tetracosa-2,8,13,21,23-pentaen-1-ol (2Z,4E,10Z,15Z,23Z)-(6R,7R,12S,13S,14S,19R,20R,21S,22S)-21-Hydroxy-7,13,19-tris-(4-methoxy-benzyloxy)-6,12,14,20,22-pentamethyl-hexacosa-2,4,10,15,23,25-hexaenoic acid methyl ester (E)-(4R,5R)-8-(tert-Butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-4-methyl-oct-2-enoic acid ethyl ester (2S)-2-[(4R,5S)-2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]propan-1-ol (2R,3R,4S,5R)-3,8-Bis-(tert-butyl-dimethyl-silanyloxy)-5-(4-methoxy-benzyloxy)-2,4-dimethyl-octanoic acid 2,6-dimethyl-phenyl ester (E)-(4R,5R)-8-Hydroxy-5-(4-methoxy-benzyloxy)-4-methyl-oct-2-enoic acid ethyl ester (2S)-tert-butyl-{(4R,5S)-2-[2-(4-methoxyphenyl)-5-methyl[1,3]dioxan-4-yl]propoxy}dimethylsilane (2S,3S,4R,5R)-3,8-bis(tert-butyldimethylsilanyloxy)-5-(4-methoxybenzyloxy)-2,4-dimethyloctan-1-ol (2E,8Z)-(4R,5R,10S)-5-(4-Methoxy-benzyloxy)-10-[(4S,5S)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-4-methyl-undeca-2,8-dienoic acid ethyl ester (Z)-(4R,5S,6S,7S)-6-(tert-butyldimethylsilanyloxy)-4-(4-methoxybenzyloxy)-5,7-dimethylundeca-8,10-dien-1-ol