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(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-dimethyl-silanyloxy)-13-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-18-methyl-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-one

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-dimethyl-silanyloxy)-13-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-18-methyl-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-one

CAS号：488721-41-1

英文名：(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-dimethyl-silanyloxy)-13-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-18-methyl-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-one

分子式

C29H52O8Si

熔点

密度

分子量

556.804

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-dimethyl-silanyloxy)-13-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-18-methyl-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-one

英文名称

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-dimethyl-silanyloxy)-13-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-18-methyl-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-one

中文别名

英文别名

CAS号

488721-41-1

分子式

C29H52O8Si

分子量

556.804

精确质量

556.343

PSA

92.68

LOGP

5.1063

合成路线

{(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(E)-(2R,4R,5S,10R)-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,4,10-trihydroxy-5-methyl-dec-8-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester

{(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(E)-(2R,4R,5S,10R)-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,4,10-trihydroxy-5-methyl-dec-8-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-dimethyl-silanyloxy)-13-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-18-methyl-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-one

(1R,3S,5R,7R,9R,13R,15S,18S)-7-(tert-Butyl-dimethyl-silanyloxy)-13-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-3-hydroxy-18-methyl-12,19,20-trioxa-tricyclo[13.3.1.15,9]icosan-11-one

上游原料

共找到15个上游原料 >

[(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((S)-3-{(2R,3S,6S)-6-[(1R,2S)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-1-iodo-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-hydroxy-propyl)-tetrahydro-pyran-2-yl]-acetic acid methyl ester

[(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((S)-3-{(2R,3S,6S)-6-[(1R,2S)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-1-iodo-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-hydroxy-propyl)-tetrahydro-pyran-2-yl]-acetic acid methyl ester

(4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-propenyl)-tetrahydro-pyran-2-one

(4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-propenyl)-tetrahydro-pyran-2-one

Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methyl-7-triisopropylsilanyloxy-hept-2-enyl ester

Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methyl-7-triisopropylsilanyloxy-hept-2-enyl ester

Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-6-methyl-hept-2-enyl ester

Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-6-methyl-hept-2-enyl ester

(E)-(3R,5S)-3,5-Bis-triethylsilanyloxy-oct-6-enal

(E)-(3R,5S)-3,5-Bis-triethylsilanyloxy-oct-6-enal

Benzoic acid (E)-(1R,6S,7R,9R)-10-[(2R,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-ethoxycarbonylmethyl-tetrahydro-pyran-2-yl]-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7,9-dihydroxy-6-methyl-dec-2-enyl ester

Benzoic acid (E)-(1R,6S,7R,9R)-10-[(2R,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-ethoxycarbonylmethyl-tetrahydro-pyran-2-yl]-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7,9-dihydroxy-6-methyl-dec-2-enyl ester

上游原料

[(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((S)-3-{(2R,3S,6S)-6-[(1R,2S)-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-1-iodo-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-hydroxy-propyl)-tetrahydro-pyran-2-yl]-acetic acid methyl ester (4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-propenyl)-tetrahydro-pyran-2-one Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methyl-7-triisopropylsilanyloxy-hept-2-enyl ester Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-6-methyl-hept-2-enyl ester (E)-(3R,5S)-3,5-Bis-triethylsilanyloxy-oct-6-enal Benzoic acid (E)-(1R,6S,7R,9R)-10-[(2R,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-ethoxycarbonylmethyl-tetrahydro-pyran-2-yl]-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7,9-dihydroxy-6-methyl-dec-2-enyl ester (E)-(3R,5S)-3,5-Bis-triethylsilanyloxy-oct-6-enoic acid butyl ester {(2R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(E)-(2R,4R,5S,10R)-10-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,4,10-trihydroxy-5-methyl-dec-8-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester (2E,8E)-(5S,7S)-5,7-Dihydroxy-deca-2,8-dienoic acid ethyl ester Benzoic acid (E)-(1R,6S)-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-methyl-7-oxo-hept-2-enyl ester [(2R,4R,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-(2-oxo-propyl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester Benzoic acid (E)-(1R,6S,7R)-10-[(2S,4R,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-ethoxycarbonylmethyl-tetrahydro-pyran-2-yl]-1-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-7-hydroxy-6-methyl-9-oxo-dec-2-enyl ester [(2R,4S,6S)-4-Hydroxy-6-((E)-propenyl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester [4-(tert-butyl-dimethyl-silanyloxy)-6-(3-{6-[2-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-1-(2,4,6-triisopropyl-phenylselanyl)-ethyl]-3-methyl-tetrahydro-pyran-2-yl}-2-hydroxy-propyl)-tetrahydro-pyran-2-yl]-acetic acid methyl ester [(2R,4S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-propenyl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester