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(2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

(2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

CAS号：494844-44-9

英文名：(2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

分子式

C38H68O4Si

熔点

密度

分子量

617.03

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

英文名称

(2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

中文别名

英文别名

(8E,10E,14Z,16E)-(3R,4R,5R,6S,7R,13R)-4-(tert-Butyl-dimethyl-silanyloxy)-15-ethyl-17-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3,5,7,9,13-pentamethyl-heptadeca-8,10,14,16-tetraen-6-ol

CAS号

494844-44-9

分子式

C38H68O4Si

分子量

617.03

精确质量

616.489

PSA

47.92

LOGP

10.5735

合成路线

(2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-carbaldehyde

(2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-carbaldehyde

(2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

(2'R,6'R,8E,10E,14Z,16E,3R,4R,5R,6S,7R,13R)-(+)-4-tert-butyldimethylsilyloxy-17-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-15-ethyl-6-hydroxy-3,5,7,9,13-pentamethylheptadeca-8,10,14,16-tetraene

上游原料

共找到11个上游原料 >

(2'S,2R)-(-)-1'-(4-tert-butyldiphenylsilyloxy-2-methyl-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine

(2'S,2R)-(-)-1'-(4-tert-butyldiphenylsilyloxy-2-methyl-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine

Acetic acid (2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-ylmethyl ester

Acetic acid (2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-ylmethyl ester

(3Z,5R)-(+)-3-bromomethyl-7-tert-butyldiphenylsilyloxy-5-methylhept-3-ene

(3Z,5R)-(+)-3-bromomethyl-7-tert-butyldiphenylsilyloxy-5-methylhept-3-ene

(2E,4R,5S,6R,7R,8R)-(+)-ethyl 7-tert-butyldimethylsilyloxy-5-hydroxy-2,4,6,8-tetramethyldec-2-enoate

(2E,4R,5S,6R,7R,8R)-(+)-ethyl 7-tert-butyldimethylsilyloxy-5-hydroxy-2,4,6,8-tetramethyldec-2-enoate

(2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-carbaldehyde

(2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-carbaldehyde

(2E,4R,5S,6R,7R,8R)-(-)-1-bromo-7-tert-butyldimethylsilyloxy-5-hydroxy-2,4,6,8-tetramethyldec-2-ene

(2E,4R,5S,6R,7R,8R)-(-)-1-bromo-7-tert-butyldimethylsilyloxy-5-hydroxy-2,4,6,8-tetramethyldec-2-ene

上游原料

(2'S,2R)-(-)-1'-(4-tert-butyldiphenylsilyloxy-2-methyl-1-butylidenamino)-2'-(methoxymethyl)pyrrolidine Acetic acid (2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-ylmethyl ester (3Z,5R)-(+)-3-bromomethyl-7-tert-butyldiphenylsilyloxy-5-methylhept-3-ene (2E,4R,5S,6R,7R,8R)-(+)-ethyl 7-tert-butyldimethylsilyloxy-5-hydroxy-2,4,6,8-tetramethyldec-2-enoate (2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-carbaldehyde (2E,4R,5S,6R,7R,8R)-(-)-1-bromo-7-tert-butyldimethylsilyloxy-5-hydroxy-2,4,6,8-tetramethyldec-2-ene (2R,6R)-(+)-(6-isopropoxy-3,6-dihydro-2H-6-pyran-2-yl)methanol (2'R,6'R,1E,3Z,5R)-(+)-7-tert-butyldiphenylsilyloxy-1-(5',6'-dihydro-2'H-2'-isopropoxypyran-6'-yl)-3-ethyl-5-methylhepta-1,3-diene (4Z,6E)-(R)-5-Ethyl-7-((2R,6R)-6-isopropoxy-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dien-1-ol ethyl (Z,4R)-6-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-2-ethyl-4-methyl-2-hexenoate (2R,6R)-(+)-2-chloromethyl-6-isopropoxy-3,6-dihydro-2H-2-pyran