化合物简介
Vomitoxin, also known as deoxynivalenol (DON), is a type B trichothecene, an epoxy-sesquiterpenoid. This mycotoxin occurs predominantly in grains such as wheat, barley, oats, rye, and maize, and less often in rice, sorghum, and triticale. The occurrence of deoxynivalenol is associated primarily with Fusarium graminearum (Gibberella zeae) and F. culmorum, both of which are important plant pathogens which cause fusarium head blight in wheat and gibberella or fusarium ear blight in maize. A direct relationship between the incidence of fusarium head blight and contamination of wheat with deoxynivalenol has been established. The incidence of fusarium head blight is strongly associated with moisture at the time of flowering (anthesis), and the timing of rainfall, rather than the amount, is the most critical factor. However, increased amount of moisture towards harvest time has been associated with lower amount of vomitoxin in wheat grain due to leaching of toxins. Furthermore, deoxynivalenol contents are significantly affected by the susceptibility of cultivars towards Fusarium species, previous crop, tillage practices, and fungicide use. It occurs abundantly in grains in Norway due to heavy rainfall.
基本信息
中文名称
脱氧瓜萎镰菌醇
英文名称
Deoxynivalenol
中文别名
脱氧雪腐镰刀菌烯醇、3Α,7Α,15-三羟基-12,13-环氧单端孢霉-9-蒽-8-酮、呕吐毒素、3α,7α,15-Trihydroxy-12,13-epoxytrichothec-9-en-8-one、别名:呕吐毒素
英文别名
(3beta,7alpha,12R)-3,7,15-trihydroxy-12,13-epoxytrichothec-9-en-8-one、DEOXYNIVALENOL
CAS号
51481-10-8
分子式
C15H20O6
分子量
296.316
精确质量
296.126
PSA
99.52
LOGP
-0.8377
编号系统
UNII
JT37HYP23V
物化性质
密度
1.48g/cm3
沸点
543.9ºC at 760mmHg
熔点
151-153ºC
闪点
206.9ºC
折射率
1.632
稳定性
Stable. Incompatible with strong oxidizing agents.
储存条件
库房低温,通风,干燥,与食品原料分开存放
安全信息
危险类别码
R25; R68/20/21/22; R67; R66; R36; R20/21/22; R11; R36/37/38
危险品运输编码
UN 2811 6.1/PG 2
危险类别
6.1(a)
危险品标志
T; Xn; F; Xi
危险性防范说明
P264; P301 + P310
危险标志
GHS06
信号词
Danger
危险性描述
H300