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((2S,3S)-3-{(2R,3R,4E)-2-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]pent-4-enyl}oxiran-2-yl)-1-(tert-butyldimethylsilyloxy)methane

((2S,3S)-3-{(2R,3R,4E)-2-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]pent-4-enyl}oxiran-2-yl)-1-(tert-butyldimethylsilyloxy)methane

CAS号：527742-86-5

英文名：((2S,3S)-3-{(2R,3R,4E)-2-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]pent-4-enyl}oxiran-2-yl)-1-(tert-butyldimethylsilyloxy)methane

分子式

C38H58O6Si2

熔点

密度

分子量

667.035

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

((2S,3S)-3-{(2R,3R,4E)-2-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]pent-4-enyl}oxiran-2-yl)-1-(tert-butyldimethylsilyloxy)methane

英文名称

((2S,3S)-3-{(2R,3R,4E)-2-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]pent-4-enyl}oxiran-2-yl)-1-(tert-butyldimethylsilyloxy)methane

中文别名

英文别名

(S)-2-[(E)-(3S,4S)-5-[(2S,3S)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-oxiranyl]-4-(tert-butyl-diphenyl-silanyloxy)-3-methoxymethoxy-pent-1-enyl]-4-methyl-3,6-dihydro-2H-pyran

CAS号

527742-86-5

分子式

C38H58O6Si2

分子量

667.035

精确质量

666.377

PSA

58.68

LOGP

7.3914

合成路线

(6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one

(6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one

((2S,3S)-3-{(2R,3R,4E)-2-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]pent-4-enyl}oxiran-2-yl)-1-(tert-butyldimethylsilyloxy)methane

((2S,3S)-3-{(2R,3R,4E)-2-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]pent-4-enyl}oxiran-2-yl)-1-(tert-butyldimethylsilyloxy)methane

上游原料

共找到12个上游原料 >

methyl (2S)-2-{[tert-butyl(diphenyl)silyl]oxy}-6-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]-hex-4-ynoate

methyl (2S)-2-{[tert-butyl(diphenyl)silyl]oxy}-6-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]-hex-4-ynoate

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde

(S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde

(1E,4S)-4-(tert-butyldiphenylsilyloxy)-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-8-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]oct-1-en-6-yn-3-one

(1E,4S)-4-(tert-butyldiphenylsilyloxy)-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-8-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]oct-1-en-6-yn-3-one

(1E,3S,4S)-4-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-8-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]oct-1-en-6-yne

(1E,3S,4S)-4-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-8-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]oct-1-en-6-yne

(2S)-2-(tert-butyldiphenylsilyloxy)-6-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]hex-4-yn-1-ol

(2S)-2-(tert-butyldiphenylsilyloxy)-6-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]hex-4-yn-1-ol

(4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane

(4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane

上游原料

methyl (2S)-2-{[tert-butyl(diphenyl)silyl]oxy}-6-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]-hex-4-ynoate (S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde (1E,4S)-4-(tert-butyldiphenylsilyloxy)-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-8-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]oct-1-en-6-yn-3-one (1E,3S,4S)-4-(tert-butyldiphenylsilyloxy)-3-(methoxymethoxy)-1-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-8-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]oct-1-en-6-yne (2S)-2-(tert-butyldiphenylsilyloxy)-6-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]hex-4-yn-1-ol (4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane ethyl (5S)-5-(tert-butyldiphenylsilyloxy)-6-(4-methoxybenzyloxy)hex-2-ynoate ethyl (5S)-5-hydroxy-6-(4-methoxybenzyloxy)hex-2-ynoate (2S)-1-[(4-methoxybenzyl)oxy]-2-{[tert-butyl(diphenyl)silyl]oxy}-6-[(2R,S)-tetrahydro-2H-pyran-2-yloxy]hex-4-yne (S)-2-allyloxy-4-methyl-1-trityloxy-4-pentene (5S)-5-(tert-butyldiphenylsilyloxy)-6-(4-methoxybenzyloxy)hex-2-yn-1-ol (6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one