百科

(S)-2-[(E)-(3S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-hex-1-enyl]-4-methyl-3,6-dihydro-2H-pyran

CAS号：527743-02-8

英文名：(S)-2-[(E)-(3S,4S)-4-(tert-Butyl-diphenyl-silanyloxy)-3-methoxymethoxy-6-triethylsilanyloxy-hex-1-enyl]-4-methyl-3,6-dihydro-2H-pyran

分子式：C36H56O5Si2

分子量：624.998

下游产品

(3E,9E)-(1R,7S,11S,15S,17R)-11-Methoxymethoxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

385809-28-9

385809-27-8

C.2-C.3-(E) des-epoxy-laulimalide

379269-65-5

(1S,2S,3E)-1-[3-((2E,4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-prop-2-enyl]-2-methoxymethoxy-4-[(2S)-(4-methyl-3,6-dihydro-2H-pyran-2-yl)]-but-3-enyl bis(2,2,2-rifluoroethoxy-phosphoryl)acetate

379269-89-3

(Z)-4-[(2R,6R)-6-((S)-2,4-Dimethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid (E)-(1S,2S)-1-[(E)-3-((4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester

379269-84-8

(3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

445306-76-3

(Z)-4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-6,11-Bis-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-10-triethylsilanyloxy-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-enoic acid 2-trimethylsilanyl-ethyl ester

379269-81-5

4-[6-(2-methyl-4-trimethylsilanylmethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid 1-[3-(4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester

379269-80-4

(1E,6E,3S,4S)-7-[(4R,6R)-(4,6-dimethyl-[1,3]dioxan-2-yl)]-3-methoxymethoxy-1-[(2S)-(4-methyl-3,6-dihydro-2H-pyran-2-yl)]-hepta-1,6-dien-4-ol

503064-81-1

(3Z,9E)-(1R,7S,11S,15S,17R)-11-((1R,3R)-3-Hydroxy-1-methyl-butoxy)-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

503064-82-2

(3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-11-((R)-1-methyl-3-oxo-butoxy)-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one

上游原料

(2S)-2-(4R,5R)-2,2-dimethyl-5-[(2S)-4-methyl-3,6-dihydro-2H-pyran-2-yl]-1,3-dioxolan-4-yl-4-methyl-3,6-dihydro-2H-pyran (S)-4-methyl-1-trityloxymethyl-3,6-dihydro-2H-pyran (S)-3,6-dihydro-4-methyl-2H-pyran-2-carbaldehyde (1S,2S)-1,2-bis-[4-methyl-3,6-dihydro-2H-pyran-(2S)-yl]-ethane-1,2-diol (4S,5S)-4,5-bis-1-[(S)-allyloxy-3-methylbut-3-enyl]-2,2-dimethyl-[1,3]-dioxolane (1S)-1-{(4R,5R)-5-[(1S)-1-hydroxy-3-methyl-3-butenyl]-2,2-dimethyl-1,3-dioxolan-4-yl}-3-methyl-3-buten-1-ol (2S)-2-(4-methoxybenzyloxy)-4-methyl-3,6-dihydro-2H-pyran (S)-2-allyloxy-4-methyl-1-trityloxy-4-pentene (6S)-6-(4-methoxybenzyloxy)-4-methyl-5,6-dihydro-2H-pyran-2-one

下游产品

(3E,9E)-(1R,7S,11S,15S,17R)-11-Methoxymethoxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one C.2-C.3-(E) des-epoxy-laulimalide (1S,2S,3E)-1-[3-((2E,4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-prop-2-enyl]-2-methoxymethoxy-4-[(2S)-(4-methyl-3,6-dihydro-2H-pyran-2-yl)]-but-3-enyl bis(2,2,2-rifluoroethoxy-phosphoryl)acetate (Z)-4-[(2R,6R)-6-((S)-2,4-Dimethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid (E)-(1S,2S)-1-[(E)-3-((4R,6R)-4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester (3Z,9E)-(1R,7S,11S,15S,17R)-11-Hydroxy-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one (Z)-4-{(2R,6R)-6-[(7E,12E)-(2S,6S,10S,11S)-6,11-Bis-methoxymethoxy-2-methyl-13-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-4-methylene-10-triethylsilanyloxy-trideca-7,12-dienyl]-5,6-dihydro-2H-pyran-2-yl}-but-2-enoic acid 2-trimethylsilanyl-ethyl ester 4-[6-(2-methyl-4-trimethylsilanylmethyl-pent-4-enyl)-5,6-dihydro-2H-pyran-2-yl]-but-2-enoic acid 1-[3-(4,6-dimethyl-[1,3]dioxan-2-yl)-allyl]-2-methoxymethoxy-4-(4-methyl-3,6-dihydro-2H-pyran-2-yl)-but-3-enyl ester (1E,6E,3S,4S)-7-[(4R,6R)-(4,6-dimethyl-[1,3]dioxan-2-yl)]-3-methoxymethoxy-1-[(2S)-(4-methyl-3,6-dihydro-2H-pyran-2-yl)]-hepta-1,6-dien-4-ol (3Z,9E)-(1R,7S,11S,15S,17R)-11-((1R,3R)-3-Hydroxy-1-methyl-butoxy)-7-[(E)-(S)-1-methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one (3Z,9E)-(1R,7S,11S,15S,17R)-7-[(E)-(S)-1-Methoxymethoxy-3-((S)-4-methyl-3,6-dihydro-2H-pyran-2-yl)-allyl]-15-methyl-13-methylene-11-((R)-1-methyl-3-oxo-butoxy)-6,21-dioxa-bicyclo[15.3.1]henicosa-3,9,19-trien-5-one