化合物简介
XPhos is an organophosphorus compound derived from biphenyl. Its palladium complexes exhibit high activity for Buchwald-Hartwig amination reactions involving aryl chlorides and aryl tosylates. Both palladium and copper complexes of the compound exhibit high activity for the coupling of aryl halides and aryl tosylates with various amides. The ligand has convenient handling characteristics since it is air-stable.
基本信息
中文名称
2-二环己基磷-2,4,6-三异丙基联苯
英文名称
2-(Dicyclohexylphosphino)-2,4,6-Triisopropylbiphenyl
中文别名
2-二环己、2-双环己基膦-2’,4’,6’-三异丙基联苯、2-二环己基磷-2\',4\',6\'-三异丙基联苯
英文别名
dicyclohexyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane
CAS号
564483-18-7
分子式
C33H49P
分子量
476.716
精确质量
476.357
PSA
13.59
LOGP
10.4964
编号系统
MDL号
MFCD04117682
物化性质
外观与性状
白色结晶粉末
沸点
569.8ºC at 760 mmHg
熔点
187-190°C(lit.)
闪点
317.7ºC
安全信息
安全说明
S37/39-S26-S36/37
WGK Germany
3
危险类别码
R22; R36/37/38
海关编码
2902909090
危险品标志
Xn
信号词
Warning
危险性描述
H351
危险性防范说明
P281
危险标志
GHS08