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(1S,2S,4R,6R,7S,8S,9R,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-15-mesityl-2,6,8,12,17-pentamethyl-5,11-dioxo-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-7-yl acetate

(1S,2S,4R,6R,7S,8S,9R,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-15-mesityl-2,6,8,12,17-pentamethyl-5,11-dioxo-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-7-yl acetate

CAS号：565226-37-1

英文名：(1S,2S,4R,6R,7S,8S,9R,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-15-mesityl-2,6,8,12,17-pentamethyl-5,11-dioxo-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-7-yl acetate

分子式

C42H58O9

熔点

密度

分子量

706.905

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(1S,2S,4R,6R,7S,8S,9R,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-15-mesityl-2,6,8,12,17-pentamethyl-5,11-dioxo-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-7-yl acetate

英文名称

(1S,2S,4R,6R,7S,8S,9R,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-15-mesityl-2,6,8,12,17-pentamethyl-5,11-dioxo-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-7-yl acetate

中文别名

英文别名

CAS号

565226-37-1

分子式

C42H58O9

分子量

706.905

精确质量

706.408

PSA

109.89

LOGP

7.4016

合成路线

(1S,2R,5S,6R,7R,8R,9R,12S,13S,15S,17R)-5-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-7,9-dihydroxy-2,6,8,12,17-pentamethyl-10-methylene-15-(2,4,6-trimethyl-phenyl)-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one

(1S,2R,5S,6R,7R,8R,9R,12S,13S,15S,17R)-5-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-7,9-dihydroxy-2,6,8,12,17-pentamethyl-10-methylene-15-(2,4,6-trimethyl-phenyl)-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one

(1S,2S,4R,6R,7S,8S,9R,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-15-mesityl-2,6,8,12,17-pentamethyl-5,11-dioxo-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-7-yl acetate

(1S,2S,4R,6R,7S,8S,9R,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-15-mesityl-2,6,8,12,17-pentamethyl-5,11-dioxo-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-7-yl acetate

上游原料

共找到17个上游原料 >

(2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde

(2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde

(3S,4R,5R,6S,7S,8S)-8-Benzyloxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-non-1-en-4-ol

(3S,4R,5R,6S,7S,8S)-8-Benzyloxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-non-1-en-4-ol

(2S,3S,4R,5R,6S)-7-(tert-butyldiphenylsilyloxy)-3,5-(isopropylidenedioxy)-2,4,6-trimethyl-heptanol

(2S,3S,4R,5R,6S)-7-(tert-butyldiphenylsilyloxy)-3,5-(isopropylidenedioxy)-2,4,6-trimethyl-heptanol

(2S,3S,4S,5R,6S)-1-Benzyloxy-2,4,6-trimethyl-oct-7-ene-3,5-diol

(2S,3S,4S,5R,6S)-1-Benzyloxy-2,4,6-trimethyl-oct-7-ene-3,5-diol

(1S,2R,5S,6R,7R,8R,9R,12S,13S,15S,17R)-5-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-7,9-dihydroxy-2,6,8,12,17-pentamethyl-10-methylene-15-(2,4,6-trimethyl-phenyl)-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one

(1S,2R,5S,6R,7R,8R,9R,12S,13S,15S,17R)-5-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-7,9-dihydroxy-2,6,8,12,17-pentamethyl-10-methylene-15-(2,4,6-trimethyl-phenyl)-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one

(R)-2-((4S,5R,6S)-6-{(S)-3-[(2S,4R,5R,6S)-6-((1S,2R,3R,4S)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-pentyl)-5-methyl-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxan-4-yl]-1-methyl-but-3-enyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid

(R)-2-((4S,5R,6S)-6-{(S)-3-[(2S,4R,5R,6S)-6-((1S,2R,3R,4S)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-pentyl)-5-methyl-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxan-4-yl]-1-methyl-but-3-enyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid

上游原料

(2S,3S)-3-Benzyloxy-2-methyl-butyraldehyde (3S,4R,5R,6S,7S,8S)-8-Benzyloxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-non-1-en-4-ol (2S,3S,4R,5R,6S)-7-(tert-butyldiphenylsilyloxy)-3,5-(isopropylidenedioxy)-2,4,6-trimethyl-heptanol (2S,3S,4S,5R,6S)-1-Benzyloxy-2,4,6-trimethyl-oct-7-ene-3,5-diol (1S,2R,5S,6R,7R,8R,9R,12S,13S,15S,17R)-5-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-7,9-dihydroxy-2,6,8,12,17-pentamethyl-10-methylene-15-(2,4,6-trimethyl-phenyl)-4,14,16-trioxa-bicyclo[11.3.1]heptadecan-3-one (R)-2-((4S,5R,6S)-6-{(S)-3-[(2S,4R,5R,6S)-6-((1S,2R,3R,4S)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-pentyl)-5-methyl-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxan-4-yl]-1-methyl-but-3-enyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propionic acid (S)-2-[(4R,5S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-propan-1-ol 4-[(1R,2S)-1-((S)-2-Benzyloxy-1-methyl-ethyl)-2-methyl-but-3-enyloxymethyl]-1,2-dimethoxy-benzene (2S,4S,5R,6R,7S,8S,9R,10S,11S)-11-Benzyloxy-2-{(4S,5R,6R)-6-[(S)-2-(tert-butyl-diphenyl-silanyloxy)-1-methyl-ethyl]-2,2,5-trimethyl-[1,3]dioxan-4-yl}-9-(4-methoxy-benzyloxy)-6,8,10-trimethyl-5,7-bis-triethylsilanyloxy-dodecan-4-ol 2,2-Dimethyl-propionic acid (2R,3S,4R,5S,6R,7S,8S)-8-benzyloxy-2-hydroxy-6-(4-methoxy-benzyloxy)-3,5,7-trimethyl-4-triethylsilanyloxy-nonyl ester (1R,4S,5S,9S,10R,13R,14R,15S,17S,19R,20R)-13-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-4,7,7,10,14,19,20-heptamethyl-2-methylene-17-(2,4,6-trimethyl-phenyl)-6,8,12,16,18-pentaoxa-tricyclo[13.3.1.15,9]icosan-11-one 1-[(1S,2R)-1-((1S,2S)-2-Benzyloxy-1-methyl-propyl)-2-methyl-but-3-enyloxymethyl]-4-methoxy-benzene (1S,2S,4R,5R,6R,7R,8R,9S,12R,13S,15S,17R)-9-((2S,3S)-3-(benzyloxy)butan-2-yl)-5,7-dihydroxy-15-mesityl-2,6,8,12,17-pentamethyl-10,14,16-trioxaspiro[bicyclo[11.3.1]heptadecane-4,2'-oxiran]-11-one (2S,5R,6R,7R,8R,9S,10S,11S)-11-Benzyloxy-2-[(4S,5R,6R)-6-((S)-2-hydroxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-9-(4-methoxy-benzyloxy)-6,8,10-trimethyl-4-methylene-dodecane-5,7-diol (S)-2-((4R,5R,6S)-6-{(S)-3-[(2S,4R,5R,6S)-6-[(1S,2R,3S,4S)-4-Benzyloxy-2-(4-methoxy-benzyloxy)-1,3-dimethyl-pentyl]-5-methyl-2-(2,4,6-trimethyl-phenyl)-[1,3]dioxan-4-yl]-1-methyl-but-3-enyl}-2,2,5-trimethyl-[1,3]dioxan-4-yl)-propan-1-ol (4S,5S,6R)-4-((S)-2-Benzyloxy-1-methyl-ethyl)-2,2,5-trimethyl-6-((S)-1-methyl-allyl)-[1,3]dioxane (3R,4S,5R,6S)-6-Benzyloxy-3,5-dimethyl-hept-1-en-4-ol