Eremantholide A

Eremantholide A

CAS号：58030-93-6

英文名：(+)-Eremantholide A

分子式

C19H24O6

熔点

密度

1.31g/cm3

分子量

348.39

沸点

564.2ºC at 760 mmHg

溶解度

信号词

危险品标志

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基本信息

中文名称

Eremantholide A

英文名称

(+)-Eremantholide A

中文别名

英文别名

Eremantholid A、EREMANTHOLIDE A

CAS号

58030-93-6

分子式

C19H24O6

分子量

348.39

精确质量

348.157

PSA

82.06

LOGP

1.8696

物化性质

密度

1.31g/cm3

沸点

564.2ºC at 760 mmHg

闪点

203.5ºC

折射率

1.577

合成路线

(2aS,2a<sup>1</sup>R,4aS,6R,11aR,Z)-2a,6,10-trimethyl-3-(propan-2-ylidene)-2a,2a<sup>1</sup>,3,5,6,11a-hexahydro-2H-1,4,12-trioxa-6,9-methanocyclodeca[cd]pentalene-2,7(4aH)-dione

(2aS,2a<sup>1</sup>R,4aS,6R,11aR,Z)-2a,6,10-trimethyl-3-(propan-2-ylidene)-2a,2a<sup>1</sup>,3,5,6,11a-hexahydro-2H-1,4,12-trioxa-6,9-methanocyclodeca[cd]pentalene-2,7(4aH)-dione

Eremantholide A

Eremantholide A

上游原料

共找到32个上游原料 >

((1S,3aS,4R,6R,6aR)-4-hydroxy-6-(hydroxymethyl)-4-isopropyl-3a-methyl-3-oxohexahydrofuro[3,4-c]furan-1-yl)methyl pivalate

((1S,3aS,4R,6R,6aR)-4-hydroxy-6-(hydroxymethyl)-4-isopropyl-3a-methyl-3-oxohexahydrofuro[3,4-c]furan-1-yl)methyl pivalate

2,2-Dimethyl-propionic acid (1S,3aS,4R,6R,6aR)-4-isopropyl-4-methoxy-3a-methyl-3-oxo-6-trifluoromethanesulfonyloxymethyl-tetrahydro-furo[3,4-c]furan-1-ylmethyl ester

2,2-Dimethyl-propionic acid (1S,3aS,4R,6R,6aR)-4-isopropyl-4-methoxy-3a-methyl-3-oxo-6-trifluoromethanesulfonyloxymethyl-tetrahydro-furo[3,4-c]furan-1-ylmethyl ester

(1S,4S,5R,6R,8R)-6-(acetoxymethyl)-8-hydroxy-8-isopropyl-1-methyl-4-((pivaloyloxy)methyl)-3,7-dioxabicyclo(3.3.0)octan-2-one

(1S,4S,5R,6R,8R)-6-(acetoxymethyl)-8-hydroxy-8-isopropyl-1-methyl-4-((pivaloyloxy)methyl)-3,7-dioxabicyclo(3.3.0)octan-2-one

(R)-2-((S)-2-((2S,3R)-2-((benzyloxy)methyl)-5-oxotetrahydrofuran-3-yl)-2-(methoxymethoxy)ethyl)-5-ethyl-2-methylfuran-3(2H)-one

(R)-2-((S)-2-((2S,3R)-2-((benzyloxy)methyl)-5-oxotetrahydrofuran-3-yl)-2-(methoxymethoxy)ethyl)-5-ethyl-2-methylfuran-3(2H)-one

(1R,2S,5S,6S,7R)-8-hydroxy-1-isopropyl-2-methyl-5-[(pivaloyloxy)methyl]-4,9,10-trioxatricyclo[5.2.1.02,6]decan-3-one

(1R,2S,5S,6S,7R)-8-hydroxy-1-isopropyl-2-methyl-5-[(pivaloyloxy)methyl]-4,9,10-trioxatricyclo[5.2.1.02,6]decan-3-one

(1S,4S,5R,6R,8R)-6-(hydroxymethyl)-8-isopropyl-8-methoxy-1-methyl-4-[(pivaloyloxy)methyl]-3,7-dioxabicyclo[3.3.0]octan-2-one

(1S,4S,5R,6R,8R)-6-(hydroxymethyl)-8-isopropyl-8-methoxy-1-methyl-4-[(pivaloyloxy)methyl]-3,7-dioxabicyclo[3.3.0]octan-2-one

上游原料

((1S,3aS,4R,6R,6aR)-4-hydroxy-6-(hydroxymethyl)-4-isopropyl-3a-methyl-3-oxohexahydrofuro[3,4-c]furan-1-yl)methyl pivalate 2,2-Dimethyl-propionic acid (1S,3aS,4R,6R,6aR)-4-isopropyl-4-methoxy-3a-methyl-3-oxo-6-trifluoromethanesulfonyloxymethyl-tetrahydro-furo[3,4-c]furan-1-ylmethyl ester (1S,4S,5R,6R,8R)-6-(acetoxymethyl)-8-hydroxy-8-isopropyl-1-methyl-4-((pivaloyloxy)methyl)-3,7-dioxabicyclo(3.3.0)octan-2-one (R)-2-((S)-2-((2S,3R)-2-((benzyloxy)methyl)-5-oxotetrahydrofuran-3-yl)-2-(methoxymethoxy)ethyl)-5-ethyl-2-methylfuran-3(2H)-one (1R,2S,5S,6S,7R)-8-hydroxy-1-isopropyl-2-methyl-5-[(pivaloyloxy)methyl]-4,9,10-trioxatricyclo[5.2.1.02,6]decan-3-one (1S,4S,5R,6R,8R)-6-(hydroxymethyl)-8-isopropyl-8-methoxy-1-methyl-4-[(pivaloyloxy)methyl]-3,7-dioxabicyclo[3.3.0]octan-2-one (R)-2-(2-((2S,3R)-2-((benzyloxy)methyl)-5-oxotetrahydrofuran-3-yl)allyl)-5-ethyl-2-methylfuran-3(2H)-one (1S,4S,5R,6R,8R)-6-(acetoxymethyl)-8-isopropyl-8-methoxy-1-methyl-4-((pivaloyloxy)methyl)-3,7-dioxabicyclo(3.3.0)octan-2-one (R)-2-((S)-2-((2S,3R)-2-((benzyloxy)methyl)-5-oxotetrahydrofuran-3-yl)-2-hydroxyethyl)-5-ethyl-2-methylfuran-3(2H)-one (R)-2-(2-((2S,3S)-2-((benzyloxy)methyl)-5-oxotetrahydrofuran-3-yl)-2-oxoethyl)-5-ethyl-2-methylfuran-3(2H)-one (3S,3aR,4S,6aS)-3-Benzyloxymethyl-4-((R)-5-ethyl-2-methyl-3-oxo-2,3-dihydro-furan-2-ylmethyl)-6-isopropylidene-6a-methyl-tetrahydro-furo[3,4-c]furan-1-one (1S,4S,5R,6R,8R)-4-((tert-butyldiphenylsiloxy)methyl)-6-(hydroxymethyl)-8-isopropyl-8-methoxy-1-methyl-3,7-dioxabicyclo(3.3.0)octan-2-one (R)-2-[(S)-2-((2S,3R,4R)-2-Benzyloxymethyl-4-isobutyryl-5-oxo-tetrahydro-furan-3-yl)-2-methoxymethoxy-ethyl]-5-ethyl-2-methyl-furan-3-one Trifluoro-methanesulfonic acid (1R,3R,3aS,6S,6aR)-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-isopropyl-3-methoxy-3a-methyl-4-oxo-tetrahydro-furo[3,4-c]furan-1-ylmethyl ester (R)-2-((S)-2-((2S,3R,4S)-2-((benzyloxy)methyl)-4-isobutyryl-4-methyl-5-oxotetrahydrofuran-3-yl)-2-(methoxymethoxy)ethyl)-5-ethyl-2-methylfuran-3(2H)-one (3S,3aR,4S,6R,6aS)-3-(((tert-butyldiphenylsilyl)oxy)methyl)-4-(((R)-5-ethyl-2-methyl-3-oxo-2,3-dihydrofuran-2-yl)methyl)-6-isopropyl-6-methoxy-6a-methyltetrahydrofuro[3,4-c]furan-1(3H)-one ((1S,3aS,4R,6S,6aR)-6-(((R)-5-ethyl-2-methyl-3-oxo-2,3-dihydrofuran-2-yl)methyl)-4-isopropyl-4-methoxy-3a-methyl-3-oxotetrahydro-1H,3H-furo[3,4-c]furan-1-yl)methyl pivalate (3S,3aR,4S,6aS)-4-(((R)-5-ethyl-2-methyl-3-oxo-2,3-dihydrofuran-2-yl)methyl)-3-(hydroxymethyl)-6a-methyl-6-(propan-2-ylidene)tetrahydrofuro[3,4-c]furan-1(3H)-one (2aS,2a1R,3R,4aS,6R,11aS)-11-hydroxy-3-isopropyl-3-methoxy-2a,6,10-trimethyl-2a,2a1,3,5,6,10,11,11a-octahydro-2H-1,4,12-trioxa-6,9-methanocyclodeca[cd]pentalene-2,7(4aH)-dione (3S,3aR,4S,6aS)-4-(((R)-5-ethyl-2-methyl-3-oxo-2,3-dihydrofuran-2-yl)methyl)-3-(iodomethyl)-6a-methyl-6-(propan-2-ylidene)tetrahydrofuro[3,4-c]furan-1(3H)-one (1S,3aS,4R,6S,6aR)-6-(((R)-5-ethyl-2-methyl-3-oxo-2,3-dihydrofuran-2-yl)methyl)-4-isopropyl-4-methoxy-3a-methyl-3-oxohexahydrofuro[3,4-c]furan-1-carbaldehyde (2aS,2a<sup>1</sup>R,4aS,11R,12aS)-2a,7,11-trimethyl-2-(propan-2-ylidene)-2,2a,2a<sup>1</sup>,4a,5,11,12,12a-octahydro-3H-1,4,13-trioxa-6-thia-8,11-methanocycloundeca[cd]pentalene-3,10(7H)-dione 6,6-dioxide (2S,5R)-5-(2-bromoallyl)-2-(tert-butyl)-5-methyl-1,3-dioxolan-4-one (2aS,2a1R,4aS,11R,12aS)-7-chloro-2a,7,11-trimethyl-2-(propan-2-ylidene)-4a,5,7,11,12,12a-hexahydro-2H-1,4,13-trioxa-6-thia-8,11-methanocycloundeca[cd]pentalene-3,10(2aH,2a1H)-dione 6,6-dioxide (2aS,2a<sup>1</sup>R,4aS,11R,12aS)-2a,7,11-trimethyl-2-(propan-2-ylidene)-2,2a,2a<sup>1</sup>,4a,5,11,12,12a-octahydro-3H-1,4,13-trioxa-6-thia-8,11-methanocycloundeca[cd]pentalene-3,10(7H)-dione (2aS,2a1R,3R,4aS,6R,11S,11aS)-3-isopropyl-3-methoxy-2a,6,10-trimethyl-2,7-dioxo-2a,2a1,3,4a,5,6,7,10,11,11a-decahydro-2H-1,4,12-trioxa-6,9-methanocyclodeca[cd]pentalen-11-yl methanesulfonate 4-[5-(2-hydroxy-1-methyl-ethyl)-2-methyl-3-oxo-2,3-dihydro-furan-2-ylmethyl]-6-isopropyl-6-methoxy-6a-methyl-3-vinyl-tetrahydro-furo[3,4-c]furan-1-one (2R,4R)-4-(2-bromoallyl)-2-(tert-butyl)-4-methyl-5-methylene-1,3-dioxolane (2aS,2a<sup>1</sup>R,4aS,6R,11aR,Z)-2a,6,10-trimethyl-3-(propan-2-ylidene)-2a,2a<sup>1</sup>,3,5,6,11a-hexahydro-2H-1,4,12-trioxa-6,9-methanocyclodeca[cd]pentalene-2,7(4aH)-dione (3S,3aR,4S,6R,6aS)-4-(((R)-5-ethyl-2-methyl-3-oxo-2,3-dihydrofuran-2-yl)methyl)-3-(hydroxymethyl)-6-isopropyl-6-methoxy-6a-methyltetrahydrofuro[3,4-c]furan-1(3H)-one 4-(5-isopropenyl-2-methyl-3-oxo-2,3-dihydro-furan-2-ylmethyl)-6-isopropyl-6-methoxy-6a-methyl-3-vinyl-tetrahydro-furo[3,4-c]furan-1-one