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乙醇钽(V)

乙醇钽(V)

CAS号:6074-84-6
英文名:Tantalum(V) Ethoxide
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化合物简介
Tantalum(V) ethoxide is an metalorganic compound with formula Ta2(OC2H5)10, often abbreviated as Ta2(OEt)10. It is a colorless solid that dissolves in some organic solvents but hydrolyzes readily. In solution, it aggregates to form bioctahedral dimers with composition [(EtO)4Ta(μ-OEt)]2. Several approaches for preparing tantalum(V) ethoxide are known but salt metathesis from tantalum(V) chloride is generally the most successful synthetic approach. It is mainly used for the manufacture of tantalum(V) oxide thin-film materials by approaches including chemical vapor deposition, atomic layer deposition, and sol-gel processing. These materials have semiconductor, electrochromic, and optical applications.
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生产方法及用途
生产方法
制备用仪器和试剂事先都需经干燥和除水处理,并避免潮气的进入。 10g五氯化钽悬浮在200mL无水苯中,慢慢加入25mL无水乙醇,发生猛烈的反应并产生氯化氢气体。待猛烈的反应平息后,通入过量的氨气,待析出氯化铵沉淀后,滤出。滤液在减压下蒸发,将剩余物进行真空蒸馏,收集145~147℃/13.34Pa产品约11g。
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