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(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one

(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one

CAS号：632358-05-5

英文名：(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one

分子式

C41H70O7Si2

熔点

密度

分子量

731.161

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one

英文名称

(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one

中文别名

英文别名

CAS号

632358-05-5

分子式

C41H70O7Si2

分子量

731.161

精确质量

730.466

PSA

83.45

LOGP

9.6151

合成路线

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2,2-Dimethyl-propionic acid 2-[(4aS,5S,7S,8aR)-7-((E)-4-hydroxy-but-1-enyl)-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl]-ethyl ester

2,2-Dimethyl-propionic acid 2-[(4aS,5S,7S,8aR)-7-((E)-4-hydroxy-but-1-enyl)-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl]-ethyl ester

(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one

(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-23-(2-hydroxy-ethyl)-12,15,24-trimethyl-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-3-one

上游原料

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(2S,4R)-1-Benzyloxy-4-(4-methoxy-benzyloxy)-5-methyl-hex-5-en-2-ol

(2S,4R)-1-Benzyloxy-4-(4-methoxy-benzyloxy)-5-methyl-hex-5-en-2-ol

2,2-Dimethyl-propionic acid 2-((4aS,5S,7S,8aR)-7-formyl-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl)-ethyl ester

2,2-Dimethyl-propionic acid 2-((4aS,5S,7S,8aR)-7-formyl-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl)-ethyl ester

2,2-Dimethyl-propionic acid 2-((2S,3R,4R,6S)-6-benzyloxymethyl-4-hydroxy-3-hydroxymethyl-3-methyl-tetrahydro-pyran-2-yl)-ethyl ester

2,2-Dimethyl-propionic acid 2-((2S,3R,4R,6S)-6-benzyloxymethyl-4-hydroxy-3-hydroxymethyl-3-methyl-tetrahydro-pyran-2-yl)-ethyl ester

2,2-Dimethyl-propionic acid 2-[(2S,3R,4R,6S)-6-benzyloxymethyl-4-hydroxy-3-(2-hydroxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-ethyl ester

2,2-Dimethyl-propionic acid 2-[(2S,3R,4R,6S)-6-benzyloxymethyl-4-hydroxy-3-(2-hydroxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-ethyl ester

2,2-Dimethyl-propionic acid 2-{(4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-[(E)-4-(1-phenyl-1H-tetrazol-5-ylsulfanyl)-but-1-enyl]-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl}-ethyl ester

2,2-Dimethyl-propionic acid 2-{(4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-[(E)-4-(1-phenyl-1H-tetrazol-5-ylsulfanyl)-but-1-enyl]-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl}-ethyl ester

2,2-Dimethyl-propionic acid 2-{(4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-[(E)-4-(1-phenyl-1H-tetrazole-5-sulfonyl)-but-1-enyl]-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl}-ethyl ester

2,2-Dimethyl-propionic acid 2-{(4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-[(E)-4-(1-phenyl-1H-tetrazole-5-sulfonyl)-but-1-enyl]-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl}-ethyl ester

下游产品

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[(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-12,15,24-trimethyl-3-oxo-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-23-yl]-acetaldehyde

[(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-12,15,24-trimethyl-3-oxo-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-23-yl]-acetaldehyde

上游原料

(2S,4R)-1-Benzyloxy-4-(4-methoxy-benzyloxy)-5-methyl-hex-5-en-2-ol 2,2-Dimethyl-propionic acid 2-((4aS,5S,7S,8aR)-7-formyl-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl)-ethyl ester 2,2-Dimethyl-propionic acid 2-((2S,3R,4R,6S)-6-benzyloxymethyl-4-hydroxy-3-hydroxymethyl-3-methyl-tetrahydro-pyran-2-yl)-ethyl ester 2,2-Dimethyl-propionic acid 2-[(2S,3R,4R,6S)-6-benzyloxymethyl-4-hydroxy-3-(2-hydroxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-ethyl ester 2,2-Dimethyl-propionic acid 2-{(4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-[(E)-4-(1-phenyl-1H-tetrazol-5-ylsulfanyl)-but-1-enyl]-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl}-ethyl ester 2,2-Dimethyl-propionic acid 2-{(4aS,5S,7S,8aR)-2,2,4a-trimethyl-7-[(E)-4-(1-phenyl-1H-tetrazole-5-sulfonyl)-but-1-enyl]-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl}-ethyl ester 2,2-dimethyl-propionic acid 2-(7-{7-[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-6-methyl-hepta-1,4,6-trienyl}-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl)-ethyl ester (E)-3-((1S,3R)-1-Benzyloxymethyl-3-hydroxy-4-methyl-pent-4-enyloxy)-acrylic acid ethyl ester 2,2-dimethyl-propionic acid 2-[6-{7-[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-6-methyl-hepta-1,4,6-trienyl}-3-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-3-methyl-tetrahydro-pyran-2-yl]-ethyl ester 2,2-Dimethyl-propionic acid 2-((4aS,5S,7S,8aR)-7-benzyloxymethyl-2,2,4a-trimethyl-hexahydro-1,6-dioxa-2-sila-naphthalen-5-yl)-ethyl ester 2,2-Dimethyl-propionic acid 2-{(4aS,5S,7S,8aR)-7-[(E)-4-(tert-butyl-diphenyl-silanyloxy)-but-1-enyl]-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl}-ethyl ester <2R,3R>-3-hydroxy-N-methoxy-N,2-dimethyl-4-(phenylmethoxy)butanamide 2,2-Dimethyl-propionic acid 2-((4aS,5S,7S,8aR)-7-hydroxymethyl-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl)-ethyl ester 2,2-Dimethyl-propionic acid 2-((4aS,5S,7S,8aR)-7-benzyloxymethyl-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl)-ethyl ester (E)-3-((1R,2R,3S)-3-Benzyloxy-1-benzyloxymethyl-4-bromo-2-methyl-butoxy)-acrylic acid ethyl ester 2,2-Dimethyl-propionic acid 2-[(2S,3S,4R,6S)-6-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-3-vinyl-tetrahydro-pyran-2-yl]-ethyl ester 2,2-Dimethyl-propionic acid 2-[(4aS,5S,7S,8aR)-7-((E)-4-hydroxy-but-1-enyl)-2,2,4a-trimethyl-tetrahydro-pyrano[4,3-d][1,3]dioxin-5-yl]-ethyl ester <3(2R,3R),4R,5S>-3-<3-hydroxy-2-methyl-1-oxo-4-(phenylmethoxy)butyl>-4-methyl-5-phenyl-2-oxazolidinone 2,2-Dimethyl-propionic acid 2-[(2S,3S,4R,6S)-6-benzyloxymethyl-4-(tert-butyl-dimethyl-silanyloxy)-3-(2-hydroxy-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-ethyl ester (Z)-3-[(2S,3R,4R,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-((E)-3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methyl-propenal 2,2-dimethyl-propionic acid 2-(6-{7-[4-(tert-butyl-dimethyl-silanyloxy)-6-(3-iodo-allyl)-3-methyl-tetrahydro-pyran-2-yl]-6-methyl-hepta-1,4,6-trienyl}-4-hydroxy-3-hydroxymethyl-3-methyl-tetrahydro-pyran-2-yl)-ethyl ester

下游产品

[(4E,6E,14Z,16E,19E)-(1R,9R,11R,12R,13S,21S,23S,24S)-11-(tert-Butyl-dimethyl-silanyloxy)-24-(tert-butyl-dimethyl-silanyloxymethyl)-12,15,24-trimethyl-3-oxo-2,22,26-trioxa-tricyclo[19.3.1.19,13]hexacosa-4,6,14,16,19-pentaen-23-yl]-acetaldehyde