(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

CAS号：636603-08-2

英文名：(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

分子式：C42H64O2Si2

分子量：657.127

合成路线

(S)-3-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-6-oxo-heptanal

(S)-3-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-6-oxo-heptanal

(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

(Z)-(S)-5-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-2-[(E)-4-methyl-7-(tetrahydro-pyran-2-yloxy)-hept-3-enyl]-8-oxo-non-2-enoic acid ethyl ester

(Z)-(S)-5-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-2-[(E)-4-methyl-7-(tetrahydro-pyran-2-yloxy)-hept-3-enyl]-8-oxo-non-2-enoic acid ethyl ester

(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

(1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene

上游原料

(S)-3-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-6-oxo-heptanal (Z)-(S)-5-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-2-[(E)-4-methyl-7-(tetrahydro-pyran-2-yloxy)-hept-3-enyl]-8-oxo-non-2-enoic acid ethyl ester

下游产品

pseudoplexaural 2-[(1R,4Z,8Z,12S,14S)-5,9,11-trimethyl-15-oxabicyclo[12.1.0]pentadeca-4,8-dien-12-yl]prop-2-en-1-ol {(4E,8E)-(1S,12S,14R)-12-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-5,9-dimethyl-15-oxa-bicyclo[12.1.0]pentadeca-4,8-dien-1-yl}-methanol