百科

2-[(1R,4Z,8Z,12S,14S)-5,9,11-trimethyl-15-oxabicyclo[12.1.0]pentadeca-4,8-dien-12-yl]prop-2-en-1-ol

CAS号：148149-83-1

英文名：2-[(1R,4Z,8Z,12S,14S)-5,9,11-trimethyl-15-oxabicyclo[12.1.0]pentadeca-4,8-dien-12-yl]prop-2-en-1-ol

分子式

C20H32O2

熔点

密度

分子量

304.467

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

2-[(1R,4Z,8Z,12S,14S)-5,9,11-trimethyl-15-oxabicyclo[12.1.0]pentadeca-4,8-dien-12-yl]prop-2-en-1-ol

英文名称

2-[(1R,4Z,8Z,12S,14S)-5,9,11-trimethyl-15-oxabicyclo[12.1.0]pentadeca-4,8-dien-12-yl]prop-2-en-1-ol

中文别名

英文别名

Pseudoplexaurol

CAS号

148149-83-1

分子式

C20H32O2

分子量

304.467

精确质量

304.24

PSA

32.76

LOGP

4.8014

合成路线

10067-33-1

(S)-(-)-p-mentha-1,8(10)-dien-9-ol

148149-83-1

2-[(1R,4Z,8Z,12S,14S)-5,9,11-trimethyl-15-oxabicyclo[12.1.0]pentadeca-4,8-dien-12-yl]prop-2-en-1-ol

上游原料

ethyl (5E)-6-methyl-9-tetrahydropyranyloxy-2-(diethylphosphono)-5-nonenoate

340155-84-2

5-tetrahydropyranyloxy-2-cyclopropyl-2-pentanol

10067-33-1

(S)-(-)-p-mentha-1,8(10)-dien-9-ol

636603-11-7

(S)-tert-butyl((2-(4-methylcyclohex-3-en-1-yl)allyl)oxy)diphenylsilane

636603-07-1

(5S,7Z,11E)-8-(((tert-butyldimethylsilyl)oxy)methyl)-5-(3-((tert-butyldiphenylsilyl)oxy)prop-1-en-2-yl)-12-methyl-15-((tetrahydro-2H-pyran-2-yl)oxy)pentadeca-7,11-dien-2-ol

上游原料

(S)-(-)-柠檬烯 ethyl (5E)-6-methyl-9-tetrahydropyranyloxy-2-(diethylphosphono)-5-nonenoate 5-tetrahydropyranyloxy-2-cyclopropyl-2-pentanol (S)-(-)-p-mentha-1,8(10)-dien-9-ol (S)-tert-butyl((2-(4-methylcyclohex-3-en-1-yl)allyl)oxy)diphenylsilane (5S,7Z,11E)-8-(((tert-butyldimethylsilyl)oxy)methyl)-5-(3-((tert-butyldiphenylsilyl)oxy)prop-1-en-2-yl)-12-methyl-15-((tetrahydro-2H-pyran-2-yl)oxy)pentadeca-7,11-dien-2-ol {(4E,8E)-(1S,12S,14R)-12-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-5,9-dimethyl-15-oxa-bicyclo[12.1.0]pentadeca-4,8-dien-1-yl}-methanol (1E,5E,9Z)-(S)-9-(tert-Butyl-dimethyl-silanyloxymethyl)-12-[1-(tert-butyl-diphenyl-silanyloxymethyl)-vinyl]-1,5-dimethyl-cyclotetradeca-1,5,9-triene (S,4E,8Z)-8-(((tert-butyldimethylsilyl)oxy)methyl)-11-(3-((tert-butyldiphenylsilyl)oxy)prop-1-en-2-yl)-4-methyl-14-oxopentadeca-4,8-dienal (5S,Z)-5-(3-((tert-butyldiphenylsilyl)oxy)prop-1-en-2-yl)-2-((E)-4-methyl-7-((tetrahydro-2H-pyran-2-yl)oxy)hept-3-en-1-yl)non-2-ene-1,8-diol (Z)-(S)-5-[1-(tert-Butyl-diphenyl-silanyloxymethyl)-vinyl]-2-[(E)-4-methyl-7-(tetrahydro-pyran-2-yloxy)-hept-3-enyl]-8-oxo-non-2-enoic acid ethyl ester