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4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

CAS号：657389-56-5

英文名：4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

分子式

C41H69NO7Si2

熔点

密度

分子量

744.16

沸点

溶解度

信号词

危险品标志

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基本信息

中文名称

4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

英文名称

4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

中文别名

英文别名

CAS号

657389-56-5

分子式

C41H69NO7Si2

分子量

744.16

精确质量

743.461

PSA

81.41

LOGP

11.0866

合成路线

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(4S)-4-(2'-iodo-allyl)-2,2-dimethyl-[1,3]-dioxane

(4S)-4-(2'-iodo-allyl)-2,2-dimethyl-[1,3]-dioxane

4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-2-(4-methoxy-benzyloxymethyl)-oxazole

上游原料

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(4S,1'R,3'R)-4-[6'-ethoxycarbonyl-1'-(triethylsilanyloxy)-3'-(triisopropylsilanyloxy)-hex-(5'E)-enyl]-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester

(4S,1'R,3'R)-4-[6'-ethoxycarbonyl-1'-(triethylsilanyloxy)-3'-(triisopropylsilanyloxy)-hex-(5'E)-enyl]-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester

(4S,1'R,3'R)-2,2-dimethyl-4-[1'-(triethylsilanyloxy)-3'-(triisopropylsilanyloxy)-hex-5'-enyl]-oxazolidine-3-carboxylic acid tert-butyl ester

(4S,1'R,3'R)-2,2-dimethyl-4-[1'-(triethylsilanyloxy)-3'-(triisopropylsilanyloxy)-hex-5'-enyl]-oxazolidine-3-carboxylic acid tert-butyl ester

(3S)-3-(tert-butyldimethylsilanyloxy)-5-iodo-hex-1-ol

(3S)-3-(tert-butyldimethylsilanyloxy)-5-iodo-hex-1-ol

(3R)-2',2'-dimethyl-propionic acid 3-hydroxy-hex-5-ynyl ester

(3R)-2',2'-dimethyl-propionic acid 3-hydroxy-hex-5-ynyl ester

(4S)-4-(2'-iodo-allyl)-2,2-dimethyl-[1,3]-dioxane

(4S)-4-(2'-iodo-allyl)-2,2-dimethyl-[1,3]-dioxane

(4S,1'R)-2,2-dimethyl-4-[1'-(triethylsilanyloxy)-but-3'-enyl]-oxazolidine-3-carboxylic acid tert-butyl ester

(4S,1'R)-2,2-dimethyl-4-[1'-(triethylsilanyloxy)-but-3'-enyl]-oxazolidine-3-carboxylic acid tert-butyl ester

下游产品

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[4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-oxazol-2-yl]-methanol

[4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-oxazol-2-yl]-methanol

上游原料

(4S,1'R,3'R)-4-[6'-ethoxycarbonyl-1'-(triethylsilanyloxy)-3'-(triisopropylsilanyloxy)-hex-(5'E)-enyl]-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester (4S,1'R,3'R)-2,2-dimethyl-4-[1'-(triethylsilanyloxy)-3'-(triisopropylsilanyloxy)-hex-5'-enyl]-oxazolidine-3-carboxylic acid tert-butyl ester (3S)-3-(tert-butyldimethylsilanyloxy)-5-iodo-hex-1-ol (3R)-2',2'-dimethyl-propionic acid 3-hydroxy-hex-5-ynyl ester (4S)-4-(2'-iodo-allyl)-2,2-dimethyl-[1,3]-dioxane (4S,1'R)-2,2-dimethyl-4-[1'-(triethylsilanyloxy)-but-3'-enyl]-oxazolidine-3-carboxylic acid tert-butyl ester (4S,1'R,3'R)-4-[6'-ethoxycarbonyl-1'-hydroxy-3'-(triisopropylsilanyloxy)-hex-(5'E)-enyl]-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester (1S,2'S,4'R,6'R)-[6'-{2-hydroxy-1-[2-(4-methoxybenzyloxy)-acetylamino]-ethyl}-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl]-acetic acid ethyl ester (2'R,4'R,6'R)-2-(4-methoxybenzyloxymethyl)-4-(6'-oxiranylmethyl-4'-triisopropylsilanyloxy-tetrahydropyran-2'-yl)-oxazole (2'S,4'R,6'R)-[6'-{2-(4-methoxybenzyloxymethyl)-oxazol-4-yl}-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl]-acetaldehyde (4S,1'R)-2,2-dimethyl-4-[3'-oxo-1'-(triethylsilanyloxy)-propyl]-oxazolidine-3-carboxylic acid tert-butyl ester (2'S,4'R,6'R,5R)-methanesulfonic acid 5,7-dihydroxy-1-{6'-[2-(4-methoxybenzyloxymethyl)-oxazol-4-yl]-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl-methyl}-3-methyleneheptyl ester (2'R,4'R,6'R,4''R)-4-(2'',2''-dimethyl-[1'',3'']-dioxan-4''-ylmethyl)-1-{6'-[2-(4-methoxybenzyloxymethyl)-oxazol-4-yl]-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl}-pent-4-en-2-ol (4S,2'R,4'R,6'S)-4-[6'-ethoxycarbonylmethyl-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl]-2,2-dimethyloxazolidine-3-carboxylic acid tert-butyl ester (4S,1'R,3'R)-4-[3'-hydroxy-1'-(triethylsilanyloxy)-hex-5'-enyl]-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester ((2S,4R,6R)-6-{(R)-1-[2-(4-Methoxy-benzyloxy)-acetylamino]-2-oxo-ethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-acetic acid ethyl ester (2'S,4'R,6'R)-[6'-{2-(4-methoxybenzyloxymethyl)-oxazol-4-yl}-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl]-acetic acid ethyl ester (2'R,4'R,6'R)-3''-{6'-[2-(4-methoxybenzyloxymethyl)-oxazol-4-yl]-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl}-propane-1'',2''-diol (4S,1'R,3'S)-2,2-dimethyl-4-[5'-oxo-1'-(triethylsilanyloxy)-3'-(triisopropylsilanyloxy)-pentyl]-oxazolidine-3-carboxylic acid tert-butyl ester (2'R,4'R,6'R)-4-(6'-allyl-4'-(triisopropylsilanyloxy)-tetrahydropyran-2'-yl)-2-(4-methoxybenzyloxymethyl)-oxazole

下游产品

[4-((2R,4R,6R)-6-{(2R,6R)-6-[2-(tert-Butyl-dimethyl-silanyloxy)-ethyl]-4-methylene-tetrahydro-pyran-2-ylmethyl}-4-triisopropylsilanyloxy-tetrahydro-pyran-2-yl)-oxazol-2-yl]-methanol