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(2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol

(2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol

CAS号：71565-21-4

英文名：(2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol

分子式：C8H16O3

分子量：160.211

合成路线

(R)-2-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-propionic acid (R)-3-phenyl-2-(toluene-4-sulfonylamino)-propyl ester

(R)-2-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-propionic acid (R)-3-phenyl-2-(toluene-4-sulfonylamino)-propyl ester

(2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol

(2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol

(1'S,4R)-(-)-2,2-Dimethyl-4-(1-methyl-(Z)-2-hexenyl)-1,3-dioxolan

(1'S,4R)-(-)-2,2-Dimethyl-4-(1-methyl-(Z)-2-hexenyl)-1,3-dioxolan

(2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol

(2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol

上游原料

(1'S,4R)-(-)-2,2-Dimethyl-4-(1-methyl-(Z)-2-hexenyl)-1,3-dioxolan (R)-2-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-propionic acid (R)-3-phenyl-2-(toluene-4-sulfonylamino)-propyl ester

下游产品

(2R,3R,4S)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methyl-pentane-1,3-diol carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-8-hydroxy-9-hydroxymethyl-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-nonadeca-2,10,12,16,18-pentaenyl ester carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-7-{5-[8-ethyl-10-(6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-2,6-dimethyl-deca-1,3,7,9-tetraenyl]-2,2-dimethyl-[1,3]dioxan-4-yl}-3,5-dimethyl-oct-2-enyl ester (1S)-1-{(1R,2R,3R)-2-{[tert-butyl(dimethyl)silyl]oxy}-5-[(3,4-dimethoxybenzyl)oxy]-1,3-dimethylpentyl}pent-3-ynyl 2,4-dimethoxy-6-{(2R,3S)-3-methyl-2-[(triisopropylsilyl)oxy]hept-5-ynyl}benzoate (3R,4R,5R)-4-{[tert-butyl(dimethyl)silyl]oxy}-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-3-methylhexan-1-ol (4S,5R,6R,7R)-6-{[tert-butyl(dimethyl)silyl]oxy}-9-[(3,4-dimethoxybenzyl)oxy]-5,7-dimethyl-non-1-yn-4-ol carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-8-hydroxy-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester (3R,4S,5R,6R)-8-((3S,4R,5S,6S)-4,6-Dimethyl-2,8-dioxa-bicyclo[3.2.1]oct-3-yl)-1-methoxymethoxy-4,6-dimethyl-octane-3,5-diol (2S,3R,4R,5R)-5,6-Dihydroxy-3-(4-methoxy-benzyloxy)-2,4-dimethyl-hexanal (2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenoic acid (2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-3,5,7,11,15-pentamethyl-19-((2S,3S)-3-methyl-6-oxo-3,6-dihydro-2H-pyran-2-yl)-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenal tert-Butyl-[(4Z,6E)-(R)-5-ethyl-7-((2S,3S)-6-isopropoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3-methyl-hepta-4,6-dienyloxy]-diphenyl-silane carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-19-(6-methoxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester (2E,10E,12E,16Z,18E)-(5S,6R,7S,9S,15R)-6-(tert-Butyl-dimethyl-silanyloxy)-17-ethyl-1-hydroxy-19-((2S,3S)-6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaen-8-one (3R,4S,5S,6S)-4,6-Dimethyl-2,8-dioxa-bicyclo[3.2.1]octane-3-carbaldehyde carbonic acid allyl ester 6-(tert-butyl-dimethyl-silanyloxy)-17-ethyl-19-(6-hydroxy-3-methyl-3,6-dihydro-2H-pyran-2-yl)-3,5,7,11,15-pentamethyl-8-oxo-9-triisopropylsilanyloxymethyl-nonadeca-2,10,12,16,18-pentaenyl ester